全文获取类型
收费全文 | 20972篇 |
免费 | 2349篇 |
国内免费 | 3650篇 |
专业分类
化学 | 15241篇 |
晶体学 | 154篇 |
力学 | 746篇 |
综合类 | 139篇 |
数学 | 1037篇 |
物理学 | 2887篇 |
综合类 | 6767篇 |
出版年
2024年 | 102篇 |
2023年 | 316篇 |
2022年 | 712篇 |
2021年 | 940篇 |
2020年 | 1311篇 |
2019年 | 931篇 |
2018年 | 725篇 |
2017年 | 738篇 |
2016年 | 911篇 |
2015年 | 899篇 |
2014年 | 1166篇 |
2013年 | 1571篇 |
2012年 | 1352篇 |
2011年 | 1204篇 |
2010年 | 897篇 |
2009年 | 1066篇 |
2008年 | 1038篇 |
2007年 | 1193篇 |
2006年 | 1158篇 |
2005年 | 1034篇 |
2004年 | 994篇 |
2003年 | 934篇 |
2002年 | 911篇 |
2001年 | 618篇 |
2000年 | 584篇 |
1999年 | 437篇 |
1998年 | 405篇 |
1997年 | 361篇 |
1996年 | 349篇 |
1995年 | 348篇 |
1994年 | 307篇 |
1993年 | 261篇 |
1992年 | 242篇 |
1991年 | 154篇 |
1990年 | 139篇 |
1989年 | 124篇 |
1988年 | 132篇 |
1987年 | 106篇 |
1986年 | 62篇 |
1985年 | 58篇 |
1984年 | 34篇 |
1983年 | 16篇 |
1982年 | 33篇 |
1981年 | 22篇 |
1980年 | 21篇 |
1979年 | 17篇 |
1978年 | 6篇 |
1977年 | 5篇 |
1976年 | 8篇 |
1973年 | 5篇 |
排序方式: 共有10000条查询结果,搜索用时 562 毫秒
21.
利用降价法研究了多孔介质中一维核废料污染问题,此模型由一非线性抛物-椭圆耦合偏微分方程组的初边值问题来描述,对此问题给出了一个关于时间和空间均具有二阶精度的差分格式,并进行了理论分析。 相似文献
22.
L. T. Ashchepkov 《Computational Mathematics and Mathematical Physics》2006,46(7):1168-1175
A general nonlinear programming problem with interval functions is considered. Two reductions of this problem to the deterministic nonlinear programming problem are proposed, and illustrative examples are discussed. 相似文献
23.
A convective flow CO laser composed of polytetrafluoroethylene discharge tubes, nickel–chromium steel components, a cupric heat exchanger and other components is described. Operating in liquid nitrogen condition, output power of 60 W has been obtained from a non-selective cavity. 相似文献
24.
M.Hasegawa 《复旦学报(自然科学版)》2007,(5)
1 Results In the coordination system by using complexation with organic ligand, the ff emission of lanthanide(Ⅲ) (Ln(Ⅲ)) is induced the excitation energy transfer form the organic chromophore under the light-irradiation. However, there are not so much number of reports to discuss the energy relaxation mechanism in such complexes with Ln(Ⅲ). Recently, we succeeded firstly to estimate the rate constant of the energy transfer between the ligand and Ln(Ⅲ) in Pr(Ⅲ)-phenanthroline analogs[1]. Here, we will di... 相似文献
25.
Results of two urgent and practically important directions of research on the indirect oxidation of organic compounds by highly reactive intermediates generated electrochemically from oxygen (HO2
–, HO2
·, HO·) are considered and orderly arranged. The studies in question are the indirect synthesis and mineralization of organic toxicants in waste water. 相似文献
26.
Ya. I. Kurys’ N. S. Netyaga V. G. Koshechko V. D. Pokhodenko 《Theoretical and Experimental Chemistry》2007,43(5):334-342
A guest-host nanocomposite based on electroconducting polyaniline doped with 12-phosphotungstic acid and V2O5 as well as its bifunctional analog containing not more than 5 mass% nanosized platinum were obtained. A study was carried
out on the structure of these nanocomposites, their redox characteristics, and electrocatalytic activity in the reduction
of oxygen. These nanocomposites were found to display catalytic properties in the electrochemical reduction of oxygen, while
the presence of even a slight amount of nanosized platinum in the bifunctional composite leads to a significant increase in
its electrocatalytic activity.
__________
Translated from Teoreticheskaya i éksperimental’naya Khimiya, Vol. 43, No. 5, pp. 307–314, September–October, 2007. 相似文献
27.
采用扫描电镜表征了氯化聚氯乙烯静电纺丝纳米纤维膜的微观结构特征,并进行了去除地下水中铜、铅、镉等重金属阳离子的过滤试验,包括直接过滤、加土壤过滤、加硅藻土过滤和胶束强化过滤。结果表明,最佳的过滤工艺是胶束强化过滤,其最佳试验条件是10层膜过滤和5mmol/L的SDBS浓度,对铜、铅、镉的去除率分别超过73%,82%和91%。 相似文献
28.
Ching Sum Hui Lillian Sze Man Lam Chun Yin Wai Kin Chan Aleksandra B. Djurii 《Journal of polymer science. Part A, Polymer chemistry》2003,41(11):1708-1715
Polyurethanes incorporated with rhenium diimine complexes were synthesized. The polymers exhibited interesting morphologies and solution properties. Results from gel permeation chromatography suggested the formation of polymer aggregates in solutions. The polymers could act as probes for metal ions. The addition of metal ions to polymer solutions led to significant changes in the electronic absorption properties of the polymer solutions. This was attributed to the interactions between the polyether moieties and metal ions. The metal complexes could also act as efficient photosensitizers. After doping with charge‐transport viologens, the photoconductivity of the polymers was greatly enhanced. The experimental quantum efficiency was simulated with Onsager's theory. The thermalization distances and the primary yields were typically 12–14 Å and 10?3, respectively. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 1708–1715, 2003 相似文献
29.
Grishin D. F. Semyonycheva L. L. Telegina E. V. Smirnov A. S. Nevodchikov V. I. 《Russian Chemical Bulletin》2003,52(2):505-507
Organometallic compounds Cp2TiCl2, (EtC5H4)2NbCl2, and (PriC5H4)2WCl2 were assessed as additives that control polymer chain growth in the polymerization of methyl methacrylate. In the presence of compounds mentioned in amounts comparable with that of the initiator, a uniform process with no gel-effect occured and respective linear increase in the molecular weight of the polymer up to high degrees of the monomer conversion was observed. 相似文献
30.
本文对在过渡金属铁、镍电极表面制备得到的γ-氨丙基三甲氧基硅烷(γ-APS)膜进行了研究。实验中对硅烷膜用X-射线光电子能谱(XPS)、现场表面增强拉曼散射光谱(SERS)和原子力显微镜(AFM)进行了表征。X-射线光电子能谱(XPS)的结果发现存在两个N1s峰,表明γ-APS膜中的氨基有两种存在方式:自由氨基和质子化氨基。实验中还发现现场表面增强拉曼散射光谱(SERS)是研究金属/γ-APS体系中界面层结构非常有效的手段,SERS结果表明硅醇羟基和氨基发生了竞争吸附,且γ-APS分子在外加电位等条件的影响下吸附状态会发生一定变化。原子力显微镜(AFM)的表征结果在微观上显示电极表面的γ-APS膜上形成了一种较规则的微孔结构,这种结构可能与基底的性质有关。 相似文献