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101.
电化学超级电容器电极材料的研究进展   总被引:9,自引:0,他引:9  
苗小丽  邓正华 《合成化学》2002,10(2):106-109,119
回顾了电化学超级电容器电极材料的研究进展,并对不同电极材料的储能原理和性能特点进行了简要的阐述。参考文献29篇。  相似文献   
102.
Some new coordination polymers of Mn(II), Co(II), Ni(II), Cu(II), Zn(II) and Cd(II), obtained from the interaction of metal acetate with dipotassium salt of N,N’-di(carboxyethylidene)terephthalaldehydediimine (K2SB) are described. The products, which have been characterized by elemental analyses, magnetic measurements, thermogravimetric analyses, electronic and infrared spectral studies, have composition, [M(SB)(H2O)2]n. These colored coordination polymers are non-hygroscopic and quite stable at room temperature. On the basis of analytical data and IR studies, a 1:1 metal to ligand stoichiometry has been suggested to these coordination polymers. The IR studies have also revealed that ligands are coordinated to metal ion through carboxy oxygen and azomethine nitrogen. All the studies suggested tetradentate nature of the ligand with octahedral symmetry of the coordination polymers. All the coordination polymers are insoluble in acetone, ethanol, chloroform, methanol, benzene, DMF and DMSO. The thermal decomposition of the coordination polymers is studied and indicates that not only the coordinated water is lost but also that the decomposition of the ligand from the coordination polymers is necessary to interpret the successive mass loss.  相似文献   
103.
Conventional criteria and indices of aromaticity, including electronic, geometric, energetic and magnetic aspects have been applied to examine the aromaticity of five typical transition metal heterocyclic complexes, i.e. six-membered osmabezene 1 and iridabenzene 2, five-membered cobaltacyclopentadiene 3 and iridacyclopentadiene 4, and four-membered tungstacyclobutadiene 5. The results show that the cyclic, planar, conjugated and Hückel 4n+2 rule’s criteria in the transition-metal-containing heterocycles of the five complexes studied are all met. Five quantitative aromaticity indices, including Bird aromatic index (In), homodesmotic reaction aromatic stabilization energy (HASE), absolute hardness (η), diamagnetic susceptibility exaltation (Λ) and NMR chemical shift (δH), qualitatively lead to a consistent and affirmative conclusion that all of them are aromatic. However, they fail to draw a common conclusion for their relative magnitudes of aromaticity, which proves once again the multidimensional character of aromaticity.  相似文献   
104.
A new fluorescent compound based on calix[4] arene skeleton was synthesized.Its complexation ability with transition metal ions,such as Fe^3 ,Co^2 ,Ni^2 ,Cu^2 ,Zn^2 and Ag^ ,Was investigated by UV-vis and fluorescent spectra.  相似文献   
105.
杨勇  李骏 《电化学》1996,2(4):363-371
贮氢合金材料电化学与表面性能的研究进展①杨勇李骏林祖赓(厦门大学化学系,固体表面物理化学国家重点实验室,厦门361005)八十年代后期以来,人们对地球的环境保护提出了更高的要求,而便携式电器(如移动电话,摄像机与笔记本电脑等)对电池的需求也大量增加...  相似文献   
106.
通过使用“可磨式”人工热电偶进行的不同条件下的磨削温度测量试验研究了钢坯磨削工件表层温度,结果表明钢坯被磨削表层温度分布与热强呈三角形分布时的理论分析结果相同,表层峰值温度随磨削压力及磨削功率增大而提高,且随工件进给速度提高而略有降低,峰值温度还随磨削角度减小而提高,90°磨削的峰值温度比0°磨削要低250℃左右,砂轮种类也对峰值温度有重要影响,使用锆刚玉砂轮时磨削温度低于棕刚玉砂轮,试验结果表明高效钢坯磨削的磨削区温度远比普通磨削为高,可达1200℃左右,还从不同方面探讨了磨削高温对钢坯磨削的影响,认为尽管磨削高温有若干不利影响,但对高效钢坯磨削却是重要条件,上述讨论,从一个方面揭示了钢坯磨削机理,并验证了关于钢坯磨削温度的理论分析结果。  相似文献   
107.
甲烷部分氧化制合成气 Ⅰ.甲烷在过渡金属上的活化   总被引:1,自引:0,他引:1  
文中用同位素交换(D_2─CH_4)反应来测量四种过渡金属负载型催化剂对甲烷的活化能力,并与Svensson等从头算的计算结果作了比较,表明最有效活化甲烷分子的C─H键的金属是铑(Rh).文中还测定了在甲烷部分氧化制合成气反应中,四个不同催化剂的催化活性与选择性,并与它们对甲烷的活化能力进行对比,可以看出甲烷部分氧化反应中,反应活性高的催化剂有效地活化甲烷,断裂C─H键,而且氘代甲烷产物分布以形成CD_4产物为主要成份.  相似文献   
108.
Thermal decomposition of transition metal malonates, MCH2C2O4?xH2O and transition metal succinates, M(CH2)2C2O4?xH2O (M=Mn, Fe, Co, Ni, Cu, Zn) has been studied employing TG, DTG, DTA, XRD, SEM, IR and Mössbauer spectroscopic techniques. After dehydration, the anhydrous metal malonates and succinates decompose directly to their respective metal oxides in the temperature ranges 310–400 and 400–525°C, respectively. The oxides obtained have been found to be nanosized. The thermal stability of succinates have been found to be higher than that of the respective malonates.  相似文献   
109.
Designing an Immobilized Metal ion Affinity (IMA) chromatographic process on large scale demands a thorough understanding to be developed regarding the adsorption behaviour of proteins on metal loaded IMA (IMA-M(II)) gels and the characteristic adsorption parameters to be evaluated. This research investigation illustrates the significance of these aspects for the proposed fractionation of chicken egg-white proteins on these gels. Consequently, a systematic investigation of the adsorption characteristics of three chicken egg-white proteins viz., ovalbumin, conalbumin and lysozyme on Cu(II) and Ni(II) loaded IMA gels, iminodiacetate (IDA) and tris(2-aminoethyl)amine (TREN), has been undertaken. These gels differ in their selectivity towards the proteins of interest under the identical sets of experimental conditions. While TREN-Ni(II) was selective only for lysozyme, IDA-Cu(II), IDA-Ni(II) and TREN-Cu(II) showed varying affinities for all the three proteins. The equilibrium and kinetic data were analysed using various theoretical models and adsorption parameters were quantified. On the basis of these investigations, various strategies have been proposed for the efficient large-scale fractionation of chicken egg-white proteins on these gels.  相似文献   
110.
Polyoxometalates(POMs0) containing Keggin moieties exhibit a wide variety of compositions and have considerable structrral versatility as well as important magnetic, optical,and catalytic proper-ties[1-6].  相似文献   
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