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51.
Ha H. Nguyen James H. McAliley David A. Bruce 《Journal of polymer science. Part A, Polymer chemistry》2012,50(10):2019-2028
Two novel water‐soluble meta‐poly(phenylene ethynylene) (mPPE) copolymers were synthesized and characterized, each contained ester and amine functional groups attached to exohelix positions on the phenylene rings and one contained methoxy endohelix functional groups. Secondary structure formation was investigated for these materials in aqueous solutions using ultraviolet and fluorescence spectroscopy. Additionally, the folding behaviors are reported for the mPPEs and their protected amine precursors in other protic and aprotic solvents. Results indicate that both mPPEs are able to form stable helical structures in water, while only the nonmethoxylated polymer exhibited a helical structure in acetonitrile and several alcohols. © 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2012 相似文献
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Six meta‐substituted salicylaldehyde compounds have been prepared in 68–90% yields by the Suzuki–Miyaura coupling reaction using 3‐bromo‐5‐t‐butylsalicylaldehyde (1a) and arylboronic acids (2a–f) as reactants. Among the obtained products, 3‐(4‐fluorophenyl)‐5‐t‐butylsalicylaldehyde (3b), 3‐(4‐methylphenyl)‐5‐t‐butylsalicylaldehyde (3d), 3‐(1‐naphthyl)‐5‐t‐butylsalicylaldehyde (3e), and 3‐(2‐naphthyl)‐5‐t‐butylsalicylaldehyde (3f) have not been reported so far. A series of new Schiff base ligands (L1–L10) were obtained in 51–89% yields from these salicylaldehyde derivatives. 相似文献
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为了提高专业搜索引擎的查询精度,提出了一种基于PageRank算法的改进搜索结果融合算法.首先,通过对元搜索引擎技术的分析,将rtf算法和PageRank算法进行融合,提出了基于PageRank算法的改进算法.该算法可以实现基于同义词、近义词的查询,将这种改进的算法在煤地质学专业搜索引擎上进行使用,实验结果表明,采用该... 相似文献
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Simas Sakirzanovas Artūras Katelnikovas Helga Bettentrup 《Journal of luminescence》2011,131(7):1525-1529
Luminescence and reflection spectra as well as luminescence kinetics of the 1 mol% Sm3+-doped crystalline lanthanum magnesium meta borate (LaMgB5O10) and gadolinium magnesium meta borate (GdMgB5O10) were analyzed. Materials were synthesized by conventional solid state route and showed bright orange-red emission under UV excitation. Emission spectra contain sharp and well resolved Sm3+4G5/2→6HJ transitions indicating a strong crystal-field effect. In case of gadolinium compound energy transfer between Gd3+ and Sm3+ was detected. The luminescent kinetics of the Sm3+ in analyzed powders is characterized by single exponential decay and experimental values vary in the range 2.2-2.4 ms. 相似文献
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域适应(Domain Adaptation,DA)学习旨在利用标签丰富的源域来帮助标签稀缺的目标域学习。DA方法通常假设源域数据已正确标记,然而现实中通常很难收集到大量带有干净标签的源实例,带有噪声源标签的噪声DA学习可能会降低目标学习性能。为此,本文提出基于自适应标签噪声校正的鲁棒DA学习方法(Robust DA Method through Adaptive Noise Correction,RoDAC)。RoDAC包含两个学习阶段,即自适应噪声标签检测(Adaptive Noise Label Detection,ANLD)和自适应噪声标签校正(Adaptive Noise Label Correction,ANLC)。在ANLD中,使用自适应噪声检测器识别带有噪声标签的源实例,并进一步在ANLC中自适应地校正噪声标签,将其重新投入域适应学习中。与基准数据集进行比较,结果表明RoDAC方法在源域标签存在噪声的域适应场景中取得了显著的性能提升。该学习策略可集成至许多现有的DA方法中,以提升其在噪声标签场景下的学习性能。 相似文献
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A new synthetic approach to the synthesis of some epimeric C‐4‐hydroxy‐benzo[c]pyrans is described. A key step in their formation is stereoisomerisation of a nonconjugated ortho alkenylphenylketone and ‐ester using palladium bisacetonitrile [bisacetonitriledichloropalladium(II)] to give the corresponding conjugated E stereoisomers which cyclize on treatment with meta‐chloroperbenzoic acid (m‐CPBA) to afford the target compounds. 相似文献
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This paper deals with how to determine which features should be included in the software to be developed. Metaheuristic techniques have been applied to this problem and can help software developers when they face contradictory goals. We show how the knowledge and experience of human experts can be enriched by these techniques, with the idea of obtaining a better requirements selection than that produced by expert judgment alone. This objective is achieved by embedding metaheuristics techniques into a requirements management tool that takes advantage of them during the execution of the development stages of any software development project. © 2015 Wiley Periodicals, Inc. Complexity 21: 250–262, 2016 相似文献
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产品质量元数据的隐秘性 总被引:1,自引:0,他引:1
揭示了现实中质量元数据具有一定隐秘性的属性,分析了质量元数据隐秘性对顾客和企业的不同作用和不同意愿,引入都柏林核心资源集合的概念,定义了质量元数据由6要素构成的方法,并分别规范了6要素构成的应用样例,针对质量元数据的隐秘性提出了面向流程的质量元数据应用方法和数据流程,将质量元数据划分为故障元数据、制造元数据和功能元数据三大类,在尊重隐秘性的前提下,规划了质量元数据的共享原则和数据传递流程. 相似文献