城市供暖热力站自控系统调试流程

阐述了城市供暖中实现热力站温度、压力自动控制的必要性,介绍了太原市热力公司热力站自动控制系统的调试流程,提出了各个工作步骤中需要注意的一些事项。     

紧邻地铁站的超大深基坑逆作法变形规律研究

某超大深基坑紧邻城市2条地铁线交汇处的换乘站,周围环境复杂,基坑施工难度大,因此基坑支护结构施工顺利及对相邻地铁站的变形控制成为工程成败的关键。文章结合基坑工程2种施工方案,利用有限元软件MIDAS GTS建立三维有限元模型,研究了基坑盖挖逆作法施工对地表沉降、支护结构和相邻地铁站的变形和受力影响,得出影响逆作法施工的相关因素,并提出相关解决措施与建议。采用盖挖逆作法施工能够较好地控制基坑支护结构的变形,同时减小对地表和地铁站的影响。综合考虑基坑施工对围护结构、地表和地铁换乘站的影响,首层土体暗挖法要优于明挖法,但是暗挖法对围护结构强度和刚度要求高,特别是楼板临时洞口处。所得相关结论和建议可供设计和施工参考。     

On the formation of smaller p‐block endohedral fullerenes: Bonding analysis in the E@C20 (E = Si,Ge, Sn,Pb) series from relativistic DFT calculations

Experimentally characterized endohedral metallofullerenes are of current interest in expanding the range of viable fullerenic structures and their applications. Smaller metallofullerenes, such as M@C₂₈, show that several d‐ and f‐block elements can be efficiently confined in relatively small carbon cages. This article explores the potential capabilities of the smallest fullerene cage, that is, C₂₀, to encapsulate p‐block elements from group 14, that is, E = Si, Ge, Sn, and Pb. Our interest relates to the bonding features and optical properties related to E@C₂₀. The results indicate both s‐ and p‐type concentric bonds, in contrast to the well explored endohedral structures encapsulating f‐block elements. Our results suggest the E@C₂₀ series to be a new family of viable endohedral fullerenes. In addition spectroscopic properties related to electron affinity, optical, and vibrational were modeled to gain further information useful for characterization. Characteristic optical patterns were studied predicting a distinctive first peak located between 400 and 250 nm, which is red‐shifted going to the heavier encapsulated Group 14 atoms. Electron affinity properties expose different patterns useful to differentiate the hollow C₂₀ fullerene to the proposed p‐block endohedral counterparts. © 2017 Wiley Periodicals, Inc.     

Water‐soluble metalated and non‐metalated A2B‐ and A3‐corrole/amino acid conjugates: syntheses,characterization and properties

In this study, novel water‐soluble corrole amino acid conjugates were synthesized and characterized. The coupling reaction of A₂B‐ and A₃‐corroles with glycine ethyl ester and taurine under strong basic conditions proved to be successful and yielded di‐ and trifunctionalized corrole amino acid conjugates in good yields. The subsequent metalation of the corrole/amino acid conjugates broadens the scope for applications considerably. As examples, we herein show the catalytic activity of the Mn(III) A₃‐corrole towards O₂ evolution. First we employed tert‐butyl hydroperoxide (t‐BuOOH) as oxidant to obtain the Mn(V)oxo species and tetrabutyl ammonium hydroxide (TBAH) as hydroxide donor agent. Furthermore, the binding properties of the non‐metalated and the Mn(III) A₃‐corrole/amino sulfonic acid conjugates and transport of proteins were investigated and the conjugates exhibited binding to human serum albumin (HSA). Finally, a novel Ga(III) A₃‐corrole/amino sulfonic acid derivative was synthesized and we briefly describe the photophysical properties of this compound. Copyright © 2013 John Wiley & Sons, Ltd.     

Peroxide Coordination of Tellurium in Aqueous Solutions

Tellurium–peroxo complexes in aqueous solutions have never been reported. In this work, ammonium peroxotellurates (NH₄)₄Te₂(μ‐OO)₂(μ‐O)O₄(OH)₂ ( 1 ) and (NH₄)₅Te₂(μ‐OO)₂(μ‐O)O₅(OH)?1.28 H₂O?0.72 H₂O₂ ( 2 ) were isolated from 5 % hydrogen peroxide aqueous solutions of ammonium tellurate and characterized by single‐crystal and powder X‐ray diffraction analysis, by Raman spectroscopy and thermal analysis. The crystal structure of 1 comprises ammonium cations and a symmetric binuclear peroxotellurate anion [Te₂(μ‐OO)₂(μ‐O)O₄(OH)₂]^4?. The structure of 2 consists of an unsymmetrical [Te₂(μ‐OO)₂(μ‐O)O₅(OH)]^5? anion, ammonium cations, hydrogen peroxide, and water. Peroxotellurate anions in both 1 and 2 contain a binuclear Te₂(μ‐OO)₂(μ‐O) fragment with one μ‐oxo‐ and two μ‐peroxo bridging groups. ¹²⁵Te NMR spectroscopic analysis shows that the peroxo bridged bitellurate anions are the dominant species in solution, with 3–40 %wt H₂O₂ and for pH values above 9. DFT calculations of the peroxotellurate anion confirm its higher thermodynamic stability compared with those of the oxotellurate analogues. This is the first direct evidence for tellurium–peroxide coordination in any aqueous system and the first report of inorganic tellurium–peroxo complexes. General features common to all reported p‐block element peroxides could be discerned by the characterization of aqueous and crystalline peroxotellurates.     

织金火车站铁路客运服务分析

自2013年1月26日织金站办理铁路旅客运输业务以来,织金站旅客运输量逐渐增加,特别是周末和节假日期间客流量的大幅度增加与运能不足、车站设施设备短缺之间的矛盾日益突出.对织金站客运服务系统做了详细的分析,提出织金火车站的运能、客运工作人员及相关客运设施设计等方面存在的问题,并且从列车的行车组织及完善设备设施等方面提出了相应的改善措施.     

高压大容量STATCOM主电路的工程选用分析

为了设计出具有高性价比的高压大容量STATCOM装置,从工程设计角度对现有的各种结构的STATCOM主电路进行分析,指出：随着各类工程现场对装置性能要求的不断提高和新的高压大容量功率开关管研制成功,部分STATCOM主电路结构受到限制,甚至遭到淘汰.目前应用和技术上较为先进成熟的两种结构是链式（Cascade）结构和MMC结构.两种结构的稳定性、性价比、损耗节能和技术成熟度等比较分析表明,对于高压大容量STATCOM,链式结构最为适用,应成为设计的首选.MMC结构作为一种先进的结构在模块化程度和器件利用率上具有优势,是未来发展的一个重要方向.     

梅梁湖泵站主水泵大修技术探讨

通过对无锡市梅梁湖泵站主水泵进行大修,系统总结了大修的准备、检查、安装工作,并对存在的问题提出了相关的建议。     

多级提水高扬程泵站高压变频节能的计算与分析

针时平定县供水管理局娘子关各站机电水泵在直接启动时站与站之间存在流量不匹配问题而造成扬程损失,提出了改进措施,重点对多级提水高扬程泵站的高压变频节能进行了计算与分析.     

25Hz微电子交流计数站内电码化调试存在问题分析

分析了微电子交流计数站内电码化在车出清区段后不能自动复原的问题,探讨了解决问题的方案,并提出了在受端发码时受端发码电源的调试范围。