各向异性磁介质中载流矩形线圈空间磁场

在给出的各向异性的毕奥－萨伐尔定律的基础上，求出载流矩形线圈在各向异性磁介质中的空间磁场，为研究磁各向异性的磁场提供了实例。     

GdCo5和Gd^3＋离子的磁晶各向异性

本文采用点电荷模型，考虑过渡族离子和稀土离子对晶场势的贡献。以自旋轨道耦合与晶场势为微扰哈密顿量，计算了ＧｄＣｏ５中Ｇｄ＾３＋的基态分裂和磁晶各向异性常数，所得结论解释了ＧｄＣｏ５的磁晶各向异性。     

3DNSRMMCs网络骨架结构几何特征分析

用β-Si3N4颗粒浆料浸渍有机前驱体多孔聚合物材料，通过加热烧蚀掉聚合物，制备出三维空间连续网络结构预制块体。其几何特征遵循Euler定律、Aboav-Weaire定律和Levis准则等拓扑规律，在复制过程中，孔穴结构产生扭曲、变形，使其结构在空间三维方向上出现各向异性，各向异性率因扭曲变形程度不同而不同。通过实验数据测量和拓扑规律计算，定性和定量地描述了作为金属基复合材料增强相网络结构的几何特征，为获取复合材料优良性能奠定了基础。     

IF深冲钢织构及其对塑性各向异性的影响

经不同热轧终止温度生产的两种含 Ti- Nb超低碳 IF深冲钢薄板呈现不同的塑性各向异性 .利用取向分布函数 ( ODF)定量分析了它们的织构 ,并对它们相异的塑性行为与织构及 ODF级数展开四阶系数的关系进行了探讨 .结果发现 ,沿板面〈1 0 0〉的取向分布是影响薄板塑性各向异性的主要原因 ,四阶织构系数 C124及 C13 4 值的大小与正负将决定制耳效应的特征 .     

Enhanced magnetic anisotropy of nickel nanosheet prepared in Na-4 mica

Nanosheets of nickel with thickness equal to 0.6 nm have been grown within the interlayer spaces of Na-4 mica. The sheets are made up of percolative clusters of nanodisks. Magnetization characteristics indicate a superparamagnetic behavior with a blocking temperature of 428 K. The magnetic anisotropy constant as extracted from the coercivity data has been found to be higher than that of bulk nickel by two orders of magnitude. This is ascribed to a large aspect ratio of the nickel nanophase. The Bloch exponent is also found to be considerably different from that of bulk nickel because of a size effect. The Bloch equation is still found to be valid for the two dimensional structures.     

Influence of cell and LC parameters on the dynamics of STN liquid crystal displays

The dynamics of super-twisted nematic (STN) liquid crystal displays have rarely been studied. In this article, the dynamic response of STN is analysed in detail. The evolution of director configuration with time was obtained by solving Ericksen–Leslie hydrodynamic equations. The time varying midlayer tilt angle is presented as a measure of dynamic response. The influence on STN dynamics of cell parameters including pretilt angle, twist angle, cell thickness, and of material parameters including d/p, K ₂₂, K ₃₃, were studied.     

Heterometallic Coii-Lii carboxylate complexes with N-heterocyclic carbene,triphenylphosphine and pyridine: a comparative study of magnetic properties

Heterometallic Coii-Lii compounds with N-heterocyclic carbene 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene (IMes), tri phenylphosphine (Ph3P) and pyridine (py), [Co2Li2(Piv)6(IMes)2] (Piv is the anion of pivalic acid), [Co2Li2(Piv)6(Ph3P)2] and [Co2Li2(Fur)6(py)2] (Fur is the anion of 2-furoic acid), respectively, have been prepared and structurally characterized by X-ray crystallography. Easy-plane magnetic anisotropy in Coii complexes with pseudo-tetrahedral cores CoO3X (X = C, P and N) was revealed by measuring the magnetic properties together with quantum-chemical calculations using the SA-CASSCF/NEVPT2 approach. The field-induced slow magnetic relaxation of the complexes was mainly attributed to the Raman and direct processes.     

Twist-bend nematics,liquid crystal dimers,structure–property relations

ABSTRACT

One of the current challenges in liquid crystal science is to understand the molecular factors leading to the formation of the intriguing twist-bend nematic phase (N_TB) and determine its properties. During our earlier hunt for the N_TB phase created on cooling directly from the isotropic phase and not the nematic phase, we had prepared 30 symmetric liquid crystal dimers. These had odd spacers and methylene links to the two mesogenic groups; desirable but clearly not essential features for the formation of the N_TB. Here, we report the phases that the dimers exhibit and their transition temperatures as functions of both the lengths of the spacer and the terminal chains. In addition we describe the transitional entropies, their optical textures, the X-ray scattering patterns and the ²H NMR spectra employed in characterising the phases. All of which may lead to important properties of the twist-bend nematic phase.     

Cyano terminated tolane compounds for polymer dispersed liquid crystal application: relationship between cyano terminated tolane based molecular structures and electro-optical properties

ABSTRACT

The structures of the liquid crystal (LC) molecules have a key role in impacting the electro-optical performance of a polymer dispersed liquid crystal (PDLC) film. In this paper, the relationship between the LC molecular structures and the electro-optical properties of PDLC films is investigated based on an unexplored cyano-terminated tolane compounds (CTTCs) doped E8 LCs/UV polymers system. Due to the high polarity of CTTCs, LCs doped with the cyano-terminated tolane (CTT) molecules exhibit high birefringence and large positive dielectric anisotropy. On the whole, PDLC films doped with the CTT molecules exhibit a lower driving voltage than that doped with the pure E8. More excitingly, PDLC films based on CTT molecules with larger length-to-width ratio and longer conjugated system show higher contrast ratio (CR) and faster response time. Eventually, the mechanism of the effects of CTT-based molecular structures and the relationship between the electro-optical performance of PDLC films and CTT molecules are illustrated. This work paves a new way for optimising the electro-optical properties of PDLC films.