Herein macromolecular recognition by cyclodextrins (CDs) is summarized. Recognition of macromolecules by CDs is classified as main‐chain recognition or side‐chain recognition. We found that CDs form inclusion complexes with various polymers with high selectivity. Polyrotaxanes in which many CDs are entrapped in a polymer chain were prepared. Tubular polymers were prepared from the polyrotaxanes. CDs were found to recognize side‐chains of polymers selectively. CD host polymers were found to form gels with guest polymers in water. These gels showed self‐healing properties. When azobenzene was used as a guest, the gel showed sol‐gel transition by photoirradiation. When ferrocene was used, redox‐responsive gels were obtained. Macroscopic self‐assembly through molecular recognition has been discovered. Photoswitchable gel association and dissociation have been observed. 相似文献
We review briefly the problems that are driving the search for a quantum computer. These include, primarily, methods for encryption and decryption based on Shor’s algorithm for factoring large integers and the use of Pell’s equation for encryption. We also outline some of the approaches that have been suggested for implementing a quantum computer and then focus on Josephson-junction systems as qubits. We have been investigating the current-biased Josephson junction for this application, a suggestion we made about 2 years ago. We have studied macroscopic quantum tunneling and energy level spectroscopy, using microwaves, in single junctions and recently we have begun measurements of the two-quantum bit (qubit) system, i.e. two capacitively coupled junctions. Theoretical studies of energy levels and their dynamic evolution are also in progress. In the present report we discuss the basics of single Josephson junctions and compare their potential as qubits with the potentials of other systems. We also discuss our future plans to obtain greater isolation of the junctions from sources of decoherence and to develop realistic qubits. An important first step must be to exhibit quantum entanglement and measure coherence times. Then it must be shown that the states of the qubits can be initialized, that gate operations can be performed, and that the results can be read out. 相似文献
ABSTRACTRecently, there has been a surge of interest in mesogens exhibiting the twist-bend nematic (NTB) phase that is shown to be chiral even though formed by effectively achiral molecules. Although it now seems to be clear that the NTB phase in the bulk is formed by degenerate domains having opposite handedness, the presence of a supramolecular heliconical structure proposed in the Dozov model has been contradicted by the Hoffmann et al. model in which the heliconical arrangement is replaced by a polar nematic phase. The evidence in support of this is that the quadrupolar splitting tensor measured in various experiments is uniaxial and not biaxial as expected for the twist-bend nematic structure. In this debate, among other evidence, the molecular translational diffusion, and its magnitude with respect to that in the nematic phase above the NTB phase, has also been invoked to eliminate or to confirm one model or the other. We attempt to resolve this issue by reporting the first measurements of the translational self-diffusion coefficients in the nematic and twist-bend nematic phases formed 1″,7″-bis-4-(4′-cyanobiphenyl-4′-yl) heptane (CB7CB). Such measurements certainly appear to resolve the differences between the two models in favour of that for the classic twist-bend nematic phase. 相似文献
A novel pH‐switchable macroscopic assembly is reported using alginate‐based hydrogels functionalized with host (α‐cyclodextrin, αCD) and guest (diethylenetriamine, DETA) moieties. Since the interaction of αCD and DETA is pH sensitive, the host hydrogel and guest hydrogel could adhere together when the pH is 11.5 and separate when the pH is 7.0. Furthermore, this pH‐controlled adhesion and dissociation shows a good reversibility. The host and guest polymers have good biocompatibility; therefore, this pH‐sensitive macroscopic assembly shows great potential in biotechnological and biomedical applications.
