全文获取类型
收费全文 | 36974篇 |
免费 | 2784篇 |
国内免费 | 2080篇 |
专业分类
化学 | 6155篇 |
晶体学 | 36篇 |
力学 | 1648篇 |
综合类 | 244篇 |
数学 | 13250篇 |
物理学 | 6856篇 |
综合类 | 13649篇 |
出版年
2024年 | 74篇 |
2023年 | 253篇 |
2022年 | 474篇 |
2021年 | 625篇 |
2020年 | 691篇 |
2019年 | 747篇 |
2018年 | 603篇 |
2017年 | 790篇 |
2016年 | 1071篇 |
2015年 | 942篇 |
2014年 | 1610篇 |
2013年 | 2270篇 |
2012年 | 1790篇 |
2011年 | 1860篇 |
2010年 | 1639篇 |
2009年 | 2028篇 |
2008年 | 2192篇 |
2007年 | 2506篇 |
2006年 | 2189篇 |
2005年 | 1774篇 |
2004年 | 1591篇 |
2003年 | 1548篇 |
2002年 | 1452篇 |
2001年 | 1293篇 |
2000年 | 1209篇 |
1999年 | 1126篇 |
1998年 | 1005篇 |
1997年 | 805篇 |
1996年 | 780篇 |
1995年 | 662篇 |
1994年 | 582篇 |
1993年 | 551篇 |
1992年 | 529篇 |
1991年 | 373篇 |
1990年 | 340篇 |
1989年 | 336篇 |
1988年 | 318篇 |
1987年 | 226篇 |
1986年 | 171篇 |
1985年 | 164篇 |
1984年 | 129篇 |
1983年 | 40篇 |
1982年 | 84篇 |
1981年 | 65篇 |
1980年 | 65篇 |
1979年 | 60篇 |
1978年 | 44篇 |
1977年 | 48篇 |
1976年 | 36篇 |
1955年 | 16篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
91.
A fully automated sequential injection spectrophotometric method for the determination of phenylephrine hydrochloride in pharmaceutical preparations is reported. The method is based on the condensation reaction of the analyte with 4-aminoantipyrine in the presence of potassium ferricyanide. The absorbance of the condensation product was monitored at 503 nm. A linear relationship between the relative peak height and concentration was obtained in the range 0.5-17.5 mg l−1. The detection limit (as 3σ value) was 0.09 mg l−1 and repeatability was 0.8 and 0.6% at 2.5 and 5 mg l−1, respectively. Results obtained by this method agreed very well with those obtained by the AOAC official method. 相似文献
92.
J. Šesták D. Sedmidubsky G. Moiseev 《Journal of Thermal Analysis and Calorimetry》1997,48(5):1105-1122
Thermochemical and thermodynamical properties of HTSC phases are reviewed for the Y-Ba-Cu-O system and also presented for the newly calculated Bi-Sr-Cu-O system stressing out stoichiometric and phenomenological viewpoints. Simulated data are listed for (H
298
o
-H
o
o
, phase transformation temperatures, standard entropies, standard enthalpies of formation, heat capacities in crystalline phase, etc. Pseudobinary phase diagrams are treated showing the effect of oxygen partial pressure particularly illustrated on the (Sr, Bi, Ba)-Cu-O system.The work was carried out under the project No. A 2010532 supported by the Grant Agency of Academy of Sciences of the Czech Republic and the grant No. 104/97/0589 financed by the Grant Agency of the Czech Republic. 相似文献
93.
Dielectric properties of plasma polymerized PVCa and composite PVCa:Au films had been analyzed in the frequency range from 10 to 105 Hz. In order to explain experimental data obtained the modification of Maxwell-Garnett and Bruggeman self-consistent models for the case of three-component composite has been done. The theoretical analysis performed allows to determine peculiarities of dielectric behavior of a three-component system, as well as to disclose the procedure of evaluation of third-component parameters. Results of this analysis are in agreement with experimental ones. 相似文献
94.
Tomislav P. Živković 《Journal of mathematical chemistry》2002,32(1):39-71
Interaction of quantum system S
a
described by the generalised × eigenvalue equation A|
s
=E
s
S
a
|
s
(s=1,...,) with quantum system S
b
described by the generalised n×n eigenvalue equation B|
i
=
i
S
b
|
i
(i=1,...,n) is considered. With the system S
a
is associated -dimensional space X
a
and with the system S
b
is associated an n-dimensional space X
n
b
that is orthogonal to X
a
. Combined system S is described by the generalised (+n)×(+n) eigenvalue equation [A+B+V]|
k
=
k
[S
a
+S
b
+P]|
k
(k=1,...,n+) where operators V and P represent interaction between those two systems. All operators are Hermitian, while operators S
a
,S
b
and S=S
a
+S
b
+P are, in addition, positive definite. It is shown that each eigenvalue
k
i
of the combined system is the eigenvalue of the × eigenvalue equation
. Operator
in this equation is expressed in terms of the eigenvalues
i
of the system S
b
and in terms of matrix elements
s
|V|
i
and
s
|P|
i
where vectors |
s
form a base in X
a
. Eigenstate |
k
a
of this equation is the projection of the eigenstate |
k
of the combined system on the space X
a
. Projection |
k
b
of |
k
on the space X
n
b
is given by |
k
b
=(
k
S
b
–B)–1(V–
k
P})|
k
a
where (
k
S
b
–B)–1 is inverse of (
k
S
b
–B) in X
n
b
. Hence, if the solution to the system S
b
is known, one can obtain all eigenvalues
k
i
} and all the corresponding eigenstates |
k
of the combined system as a solution of the above × eigenvalue equation that refers to the system S
a
alone. Slightly more complicated expressions are obtained for the eigenvalues
k
i
} and the corresponding eigenstates, provided such eigenvalues and eigenstates exist. 相似文献
95.
A new series of π-conjugated oligomers based on various combinations of thiophene and EDOT units and double bonds has been synthesized by Wittig-Horner reactions from phosphonate anions carrying EDOT or bis-EDOT units. Optical and electrochemical results evidence the crucial role of the EDOT moiety for modulating the electronic properties of the oligomers. The insertion of bis-EDOT unit in the middle of the molecule leads to a self-rigidification of the conjugated system due to non covalent S?O intramolecular interactions. The strong electron donor effect of the EDOT units explains the determining role of the relative position of the EDOT units on the localization and stabilization of the positive charges in the radical cation or dication states. 相似文献
96.
Arrhenius parameters values, in non-isothermal kinetic vaporisation processes for a series of compounds with related structures,
have been calculated. This was made using a method of calculation that allows to find the most probable vaporisation mechanisms.
According to this method DTG curves were compared with some theoretical ones reported in literature, whose shape results to
be only a function of the mechanisms. In this way the choice of the mathematical functions which can be inserted in the kinetic
equations, was influenced by the shape of the DTG plots and other thermal analysis signals thus allowing to choose the most
probable mechanisms.
The kinetic parameters derived from these mechanisms were compared, using statistical analysis, with those obtained from another
method of calculation based on ‘a priori’ vaporisation mechanism chosen for the investigated liquid–gas transition.
The standard deviations of the slope and of the intercept, together with the standard deviation and the square correlation
coefficient (r
2) of the linear regression equations related to the mechanisms of the two methods were calculated. Student t-test, Fisher F-test, confidence intervals (c.i.) and residuals valueswere also given.
Statistical analysis shows that the mechanisms obtained with the former method (diffusive and geometrical models) and the
related Arrhenius parameters result to be more significant (in terms of probability) than the corresponding quantities of
the latter for which a first-order model was chosen.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
97.
The third law of thermodynamics, in the sense that the entropy per unit volume goes to zero as the temperature goes to zero, is investigated within the framework of statistical mechanics for quantum and classical lattice models. We present two main results: (i) For all models the question of whether the third law is satisfied can be decided completely in terms of ground-state degeneracies alone, provided these are computed for all possible boundary conditions. In principle, there is no need to investigate possible entropy contributions from low-lying excited states, (ii) The third law is shown to hold for ferromagnetic models by an analysis of the ground states.Dedicated to Pierre Résibois. Work supported in part by NSF grant PHY-7825390 A01. 相似文献
98.
一类带有扰动的不确定切换系统的鲁棒镇定 总被引:2,自引:0,他引:2
研究了一类带有非线性扰动的不确定切换系统的鲁棒镇定问题.利用完备性条件,得到了不确定切换系统渐近稳定的一个充分条件.基于LMI方法,设计出鲁棒状态反馈控制器及相应的切换策略,使得闭环系统在其平衡点处是渐近稳定的. 相似文献
99.
证明了一种N阶线性跟踪一微分器的收敛性。由于该线性跟踪一微分器的结构参数和跟踪性能对噪声和对象有一定的敏感度和依赖性,采用自适应遗传算法对三阶线性跟踪一微分器的结构参数进行了优化,以期获得较好的参数匹配,提高跟踪预测的精度和速度。将优化后的三阶线性跟踪一微分器用于电力系统参考相角预测研究中,仿真结果证明,优化后的三阶线性跟踪一微分器具有较好的跟踪性能和预测精度,满足电力系统相角预测的要求。 相似文献
100.
采用状态空间法,对多自由度非经典线性动力系统的振动进行了分析,提出了系统位移主变量和速度主变量概念,给出了系统状态向量与位移主变量和速度主变量之间的关系.算例表明,引入位移主变量和速度主变量后,可使非经典线性动力系统的振动问题得到更清晰的描述. 相似文献