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11.
本文从椭偏光合矢量旋转角速度Ω的表达式出发,对只有沿椭圆长、短轴方向的椭偏光合矢量间的相位差才为的难点给出了证明 相似文献
12.
Khaled A. Aamer Gregory N. Tew 《Journal of polymer science. Part A, Polymer chemistry》2007,45(6):1109-1121
Supramolecular block‐random copolymers containing [Ir(terpy)2]3+ in the side chain were synthesized via postfunctionalization of a P(S‐b‐ACterpy) block copolymer. Absorbance and emission spectra compared to a model compound show that the polymer backbone has a minor effect on the polymer absorbance but produces a larger shift for the phosphorescence signals to higher wavelength. Dynamic light scattering of the metal complex containing copolymer studied in various solvents showed monomodal aggregation with decreasing aggregate size as the solvent dielectric constant increased. The copolymer precursor P(S‐b‐ACterpy) shows multimodal aggregation in different solvents with the major population consisting of single chains. This difference in behavior between the two polymers is attributed to the electrolytic nature of the complex and the amphiphilicity induced by the charged metal complex. Supramolecular copolymers like these will continue to have interesting self‐organizational properties and may find applications in multicomponent systems for photoinduced charge separation processes. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 1109–1121, 2007 相似文献
13.
舒惠霞 《陕西理工学院学报(自然科学版)》2003,19(1):48-48
针对光栅衍射实验中出现的操作问题,简述了仪器调节不满足计算公式成立的条件时,引起的测量误差,并给出了正确的做法。 相似文献
14.
杜维中 《科技情报开发与经济》2004,14(3):245-246
摄象过程中,画面质量由设备因素及人的因素所决定,在拍摄过程中,为了摄取优质、逼真的视频图象,必须掌握布光、用光的技巧和艺术,光的明暗对比度的调整和确定是摄象机使用过程中的重点与难点。 相似文献
15.
Chongyu Mei Junqiao Ding Bing Yao Yanxiang Cheng Zhiyuan Xie Yanhou Geng Lixiang Wang 《Journal of polymer science. Part A, Polymer chemistry》2007,45(9):1746-1757
Two orange phosphorescent iridium complex monomers, 9‐hexyl‐9‐(iridium (III)bis(2‐(4′‐fluorophenyl)‐4‐phenylquinoline‐N,C2′)(tetradecanedionate‐11,13))‐2,7‐dibromofluorene (Br‐PIr) and 9‐hexyl‐9‐(iridium(III)bis(2‐(4′‐fluorophenyl)‐4‐methylquinoline‐N,C2′)(tetradecanedionate‐11,13))‐2,7‐dibromofluorene (Br‐MIr), were successfully synthesized. The Suzuki polycondensation of 2,7‐bis(trimethylene boronate)‐9,9‐dioctylfluorene with 2,7‐dibromo‐9,9‐dioctylfluorene and Br‐PIr or Br‐MIr afforded two series of copolymers, PIrPFs and MIrPFs, in good yields, in which the concentrations of the phosphorescent moieties were kept small (0.5–3 mol % feed ratio) to realize incomplete energy transfer. The photoluminescence (PL) of the copolymers showed blue‐ and orange‐emission peaks. A white‐light‐emitting diode with a configuration of indium tin oxide/poly(3,4‐ethylenedioxythiophene):poly(styrenesulfonate)/PIr05PF (0.5 mol % feed ratio of Br‐PIr)/Ca/Al exhibited a luminous efficiency of 4.49 cd/A and a power efficiency of 2.35 lm/W at 6.0 V with Commission Internationale de L'Eclairage (CIE) coordinates of (0.46, 0.33). The CIE coordinates were improved to (0.34, 0.33) when copolymer MIr10PF (1.0 mol % feed ratio of Br‐MIr) was employed as the white‐emissive layer. The strong orange emission in the electroluminescence spectra in comparison with PL for these kinds of polymers was attributed to the additional contribution of charge trapping in the phosphorescent dopants. © 2007 Wiley Periodicals, Inc. JPolym Sci Part A: Polym Chem 45: 1746–1757, 2007 相似文献
16.
CAI Guang-Yu LlU Zhong-Min SHI Ren-Min HE Chang-Qing YANG Li-Xin SUN Cheng-LinDalian Institute of Chemical Physics Acadernia Sinica Dalian Iiaorting 《天然气化学杂志》1995,(2)
A new route named as SDTO method for the synthesis of lightolefins from syngas has been proposed.That is to convert syngas todimethylether and then to convert dimethylether to light olefins.The catalystsfor the two conversion reactions have been developed.For the first reaction,the catulySt was synthesized by the combination of methanol synthesis catalystwith γ-Al_2O_3or zeolites which possesses both metallic and acidic functions.Thecatalyst for the second reaction was modified SAPO-34 molecular sieve.Thevariables of the reactions have also been investigated.The results from theserial connection of the two conversion steps without any separation show thatthe yield of C_2~-C_4~- olefins Could be>100g/(m~3 syngas). 相似文献
17.
采用联合光照方法,使处于性休止期的雪鸡恢复性机能活动。雄性可产出形态正常的精子;雌性输卵管发育并能产卵,由此揭示:采用联合先照技术,有助于改变雪鸡季节性繁衍后代的习性。 相似文献
18.
Zhitian Liu Lei Wang Junwu Chen Feng Wang Xiaoying Ouyang Yong Cao 《Journal of polymer science. Part A, Polymer chemistry》2007,45(5):756-767
2,5‐Bis(2‐bromofluorene‐7‐yl)silole was prepared by a modified one‐pot synthesis with a reverse addition procedure, from which novel silole‐containing polyfluorenes with binary random and alternating structures (silole contents between 4.5 and 25% and high Mw up to 509 kDa were successfully synthesized. The well‐defined repeating unit of the alternating copolymer comprises a terfluorene and a silole ring. Optoelectronic properties including UV absorption, electrochemistry, photoluminescence (PL), and electroluminescence (EL) of the copolymers were examined. The different excitation energy transfers from fluorene to silole of the copolymers in solution and in the solid state were compared. The films of the copolymers showed silole‐dominant green emissions with high absolute PL quantum yields up to 83%. EL devices of the copolymers with a configuration of ITO/PEDOT/copolymer/Ba/Al displayed exclusive silole emissions peaked at around 543 nm and the highest EL efficiency was achieved with the alternating copolymer. Using the alternating copolymer and poly(9,9‐dioctylfluorene) as the blend‐type emissive layer, a maximum external quantum efficiency of 1.99% (four times to that of the neat film) was realized, which was a high efficiency so far reported for silole‐containing polymers. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 756–767, 2007 相似文献
19.
对老式油压材料试验机进行技术改造的方案是利用原试验机结构框架和加载系统。改进落后的测试系统使其达到现代科技水平。本文论述了进行改造的项目、工作原理、实施方法。方案一经买施.对拥有大量老式油压材料试验机的我国.其社会效益和经济效益都将是十分可观的。 相似文献
20.
刘合英 《河南师范大学学报(自然科学版)》1994,22(2):108-110
本文通过用计算机对杨氏模量测量的程序设计,说明微机不仅可以迅速完成数据处理工作,还可以判断实验结果,从而更好地探索实验规律。 相似文献