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51.
52.
对苯胺、乙醇气相N-乙基化反应催化剂的制备及其活性进行了评述,特别是对近十年来的发展作出了较详细而深入的论述,指出研制这类反应催化剂的重要性和今后的发展方向。 相似文献
53.
<正>《大学物理》1985第l期上发表了胡先生有关"Terrell转动"的文章。作者的结论是:"综上所述,"......v>ccos时,能同时看到后表面,侧面和反转了的前表面,一,在v=c时,相当于静止立方体转动了尤一e的角度,并且看起来似乎是透明的." 相似文献
54.
A novel mixed sol method was developed for the preparation of supported catalysts. Analyses by means of XRD and BET show that a 40%AgBiVMoO/γ-Al2O3 catalyst prepared by this method possessed high specific surface area and high dispersion of the active phase. As a result, high acrylic acid selectivity of 8.5% was obtained when the catalyst was used in the reaction of propane partial oxidation to acrylic acid in a fixed-bed reactor. 相似文献
55.
The first MCM-41-supported bidentate phosphine palladium(0) complex has been prepared. This complex is a highly efficient catalyst for Sonogashira reaction and can be reused at least 10 times without any decrease in activity. 相似文献
56.
We have studied the kinetics of the process of epoxidation of 1-octene by tert-butyl hydroperoxide in the presence of molybdenum boride MoB2. We have studied the effect of the concentrations of starting materials and reaction products on the process. We suggest a kinetic scheme and we calculate the kinetic parameters of the process. 相似文献
57.
Hatsuhiko Hattori 《Tetrahedron letters》2005,46(35):5871-5875
Organozinc and a Pd catalyst promoted formation of dienes from allylic esters possessing a leaving group such as acyloxy and alkoxy groups next to the allyl moiety. The reaction proceeded with high regio- and stereoselectivity when applied to secondary allylic substrates. 相似文献
58.
An increasing number of biologically active compounds in the pharma and agro-chemical sector contain carbon fluorine bonds. One of the most common methods to introduce fluorine into intermediates is the well-investigated halogen-exchange reaction, in which chloro- and bromoaromatics activated towards nucleophilic substitution, react with a fluoride source to yield the corresponding fluoroarenes. In general, the reaction is supported by phase-transfer catalysts. The use of a new class of very active phase-transfer catalysts gives the possibility of substituting even halogens with weak activation giving a convenient access to interesting compounds that are not available so far and opening up new synthetic routes in Halex chemistry. Our new classes of catalysts, CNC+ (1a), PNC+ (2a) and several different approaches presented by other groups are described and experimental results discussed. 相似文献
59.
G. K. Vlasov E. I. Chizhikova D. N. Vylegzhanin 《International Journal of Infrared and Millimeter Waves》1994,15(1):121-135
The theory of new type detectors based on the quenching of secondary emission in direct-gap semiconductors (lines of Raman light scattering due to interaction between free and bound excitons in the crystal, and also bands of edge radiation) caused by IR or submillimeter radiation is proposed. The results obtained are confirmed by the experiment performed for CdS crystal excited by ultraviolet radiation of mercury lamp, at liquid helium temperature. 相似文献
60.
对负载型钌配合物的组成进行了原位红外表征,并讨论了其催化氧化性能 相似文献