Naphthalimide‐phthalimide derivative based photoinitiating systems for polymerization reactions under blue lights

Naphthalimide‐phthalimide derivatives (NDPDs) have been synthesized and combined with an iodonium salt, N‐vinylcarbazole, amine or 2,4,6‐tris(trichloromethyl)‐1,3,5‐triazine to produce reactive species (i.e., radicals and cations). These generated reactive species are capable of initiating the cationic polymerization of epoxides and/or the radical polymerization of acrylates upon exposure to very soft polychromatic visible lights or blue lights. Compared with the well‐known camphorquinone based systems used as references, the novel NDPD based combinations employed here demonstrate clearly higher efficiencies for the cationic polymerization of epoxides under air as well as the radical polymerization of acrylates. Remarkably, one of the NDPDs (i.e., NDPD2) based systems is characterized by an outstanding reactivity. The structure/reactivity/efficiency relationships of the investigated NDPDs were studied by fluorescence, cyclic voltammetry, laser flash photolysis, electron spin resonance spin trapping, and steady state photolysis techniques. The key parameters for their reactivity are provided. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2015 , 53, 665–674     

基于交通信号灯信息的混合动力汽车节能预测控制方法

针对传统混合动力汽车控制方法不考虑已知道路交通信号灯信息对车辆能量管理影响的问题,提出了基于交通信号灯信息的混合动力汽车节能预测控制智能优化策略。通过建立混合动力汽车系统的简化模型,并采用连续广义最小残量方法求解模型预测控制问题。运用MATLAB/Simulink进行仿真,仿真结果验证了交通信号灯信息模型的有效性,以及所设计的模型预测控制算法大幅度提高混合动力汽车的燃油经济性的能力和实时控制性能。研究结果表明所提出的控制策略可以实现车辆行驶轨迹的优化控制,显著提高了车辆的燃油经济性,并满足系统的实时最优控制要求。     

Directing-Group-Free C7-Alkylations of N-Alkylindoles Mediated by Cationic Zirconium Complexes: Role of Brønsted Acid for Catalytic Manifold

Highly position selective alkylations of N-alkylindoles at C7-positions have been enabled by cationic zirconium complexes. The strategy provides a straightforward access to install alkyl groups at C7-positions of indoles without a complex directing group. Mechanistic studies provided support for the importance of Brønsted acids in the catalytic manifold.     

基于DIS数字信息化系统对透光物质透光性能的研究

采用DIS数字信息化系统,对不同浓度的蓝墨水溶液在激光光源照射下的透射平均照度及照度分布图像进行实验研究,得到了平均照度值随溶液浓度变化的规律。对不同颜色塑料膜片对白炽灯光源透过照度值及照度分布图像进行实验研究得到及其相关之规律。     

关于三网合一技术

介绍了我国现阶段并存的三网(电信网、有线电视网和计算机互联网)的特点与现状，分析了三网在融合过程中需要解决的一些不可避免的问题，以及三网合一的技术基础和促进三网合一的有利因素，提出了三网合一是现代通信和计算机网络发展的必然趋势，以及在三网融合的过程中还将有一个相互渗透交叉、相互竞争、共存发展过程的观点。     

各向同性介质与单轴晶体界面上e光波法线的折射

根据光的电矢量满足的边条件，对各向同性介质与单轴晶体界面上e光波法线的折射进行了具体的讨论，得到了确定e光波法线在单轴晶体中传播方向的公式，并对几种特殊情况进行了具体讨论。指出了由所得结果可以确定e光光线的行进方向。     

Analysis on X-Ray Laser Generation with EM-Wave Wiggler

The possibility of realizing SASE Free Election Laser in x-ray waveband with EM-wave wiggler is studied in this paper. SASE effect including saturation length, saturation power and nonlinear process is explored through a 3-D simulation code. A utilization of seed light from laser plasma x-ray is also analyzed, which demonstrates the feature of shortening the interaction length for saturation. The results show that sizeable output power of x-ray laser would be generated with a middle energy electron beam.     

Scattering of Laser Light from Mixed Micelles

Dynamic and static scattering of light was employed to investigate mixed micelles of two homologous anionic surfactants-sodium octyl sulfate and sodium hexadecyl sulfate, above the phase boundary temperature and critical micelle concentrations (cmc). The results indicate that the mixed micelles change from prolate to sphcrical as the molar ratio SOS/SHS increases from 1 to 8. Below 1 or above 8, the formation of micelles is due to one surfactant dissolving the other.     

燃料添加剂对柴油机烟粒燃烧的影响

考察了燃料添加剂对降低柴油机烟粒燃点温度的效应。含金属添加剂的柴油机烟粒被收集在金属纤维过滤器上,把原状烟粒样品移入实验室反应器,用模拟柴油机排气进行燃烧试验。实验结果表明,当烟粒中含有Pd或Cu时,烟粒的燃点温度可降至430℃左右(普通柴油机烟粒的燃点温度约600℃);Pd的添加还可大大降低烟粒一次燃烧产物中CO的分率。文中还对金属(催化剂)/烟粒接触程度和添加剂溶液中可燃性部分对烟粒燃烧的影响作了讨论。