全文获取类型
收费全文 | 248240篇 |
免费 | 10620篇 |
国内免费 | 13260篇 |
专业分类
化学 | 44017篇 |
晶体学 | 645篇 |
力学 | 9557篇 |
综合类 | 1676篇 |
数学 | 37351篇 |
物理学 | 36206篇 |
综合类 | 142668篇 |
出版年
2024年 | 361篇 |
2023年 | 1512篇 |
2022年 | 2828篇 |
2021年 | 3186篇 |
2020年 | 3395篇 |
2019年 | 3568篇 |
2018年 | 3301篇 |
2017年 | 3746篇 |
2016年 | 4361篇 |
2015年 | 5388篇 |
2014年 | 10210篇 |
2013年 | 11688篇 |
2012年 | 12031篇 |
2011年 | 14244篇 |
2010年 | 11719篇 |
2009年 | 14007篇 |
2008年 | 15337篇 |
2007年 | 18402篇 |
2006年 | 16391篇 |
2005年 | 14583篇 |
2004年 | 12374篇 |
2003年 | 11873篇 |
2002年 | 10831篇 |
2001年 | 8819篇 |
2000年 | 7810篇 |
1999年 | 6574篇 |
1998年 | 5602篇 |
1997年 | 4706篇 |
1996年 | 4300篇 |
1995年 | 3862篇 |
1994年 | 3680篇 |
1993年 | 3092篇 |
1992年 | 2950篇 |
1991年 | 2521篇 |
1990年 | 2216篇 |
1989年 | 2089篇 |
1988年 | 1746篇 |
1987年 | 1186篇 |
1986年 | 869篇 |
1985年 | 692篇 |
1984年 | 618篇 |
1983年 | 312篇 |
1982年 | 473篇 |
1981年 | 521篇 |
1980年 | 384篇 |
1979年 | 381篇 |
1978年 | 307篇 |
1977年 | 292篇 |
1976年 | 213篇 |
1973年 | 152篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
61.
陈艳艳 《科技情报开发与经济》2015,(5):48-50
在高校图书馆传统功能定位下,音乐元素的融入受到了极大的限制。音乐及阅读心理治疗等新功能的设置,则将音乐元素更广、更深地融入到高校图书馆的工作中,可更好地为高校广大师生的学习生活提供服务。从高校图书馆传统功能定位下音乐元素的融入和高校图书馆新功能定位下音乐元素的融入两个方面,提出了高校图书馆不同功能定位下对音乐元素运用的思考。 相似文献
62.
Synthesis of diisocyanides with phenolic groups and their polymerization to helically chiral poly(quinoxaline‐2,3‐diyl)s
下载免费PDF全文
![点击此处可从《Journal of polymer science. Part A, Polymer chemistry》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Johannes Scholz Michael Reggelin 《Journal of polymer science. Part A, Polymer chemistry》2015,53(11):1320-1329
The development of synthetic routes which lead to five new diisocyanide monomers with one or two phenolic groups is described. Their polymerization behavior is studied with Pd‐ and Ni‐based initiators, as well as under microwave irradiation. The polymerizability is mainly dominated by steric effects as is concluded from experiments using different protecting groups. Chiroptical properties of these new polymers are studied by CD‐spectroscopy. After deprotection, helically chiral poly(quinoxalin‐2,3‐diyl)s are obtained which display a Brønsted function attached to a stereolabile biaryl axis whose configuration should be influenced by the chiral polymer backbone. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2015 , 53, 1320–1329 相似文献
63.
万仁莉 《科技情报开发与经济》2015,(2):6-8
介绍了智慧图书馆的理论研究现状及构建路径,分析了智慧图书馆人才队伍建设中存在的问题,对智慧图书馆员的培养目标及培养策略进行了探讨。 相似文献
64.
João Marcos G. Barbosa Milenna K. Fernandes Rodrigues Lurian C. David Taynara C. e Silva Danielly A. Fortuna Lima Naiara Z. Pereira Emmanuel B. D'Alessandro Anselmo E. de Oliveira Paulo H. Jorge da Cunha Maria Clorinda S. Fioravanti Nelson R. Antoniosi Filho 《Biomedical chromatography : BMC》2020,34(11):e4935
An innovative volatolomic approach employs the detection of biomarkers present in cerumen (earwax) to identify cattle intoxication by Stryphnodendron rotundifolium Mart., Fabaceae (popularly known as barbatimão). S. rotundifolium is a poisonous plant with the toxic compound undefined and widely distributed throughout the Brazilian territory. Cerumen samples from cattle of two local Brazilian breeds (‘Curraleiro Pé-Duro’ and ‘Pantaneiro’) were collected during an experimental intoxication protocol and analyzed using headspace (HS)/GC–MS followed by multivariate analysis (genetic algorithm for a partial least squares, cluster analysis, and classification and regression trees). A total of 106 volatile organic metabolites were identified in the cerumen samples of bovines. The intoxication by S. rotundifolium influenced the cerumen volatolomic profile of the bovines throughout the intoxication protocol. In this way, it was possible to detect biomarkers for cattle intoxication. Among the biomarkers, 2-octyldecanol and 9-tetradecen-1-ol were able to discriminate all samples between intoxicated and nonintoxicated bovines. The cattle intoxication diagnosis by S. rotundifolium was accomplished by applying the cerumen analysis using HS/GC–MS, in an easy, accurate, and noninvasive way. Thus, the proposed bioanalytical chromatography protocol is a useful tool in veterinary applications to determine this kind of intoxication. 相似文献
65.
Valentin A. Semenov Dmitry O. Samultsev Leonid B. Krivdin 《Magnetic resonance in chemistry : MRC》2020,58(6):532-539
The density functional theory calculation of 1H and 13C NMR chemical shifts in a series of ten 10 classically known Strychnos alkaloids with a strychnine skeleton was performed at the PBE0/pcSseg-2//pcseg-2 level. It was found that calculated 1H and 13C NMR chemical shifts provided a markedly good correlation with experiment characterized by a mean absolute error of 0.08 ppm in the range of 7 ppm for protons and 1.67 ppm in the range of 150 ppm for carbons, so that a mean absolute percentage error was as small as ~1% in both cases. 相似文献
66.
Two highly ordered isonicotinamide (INA)‐functionalized mesoporous MCM‐41 materials supporting indium and thallium (MCM‐41‐INA‐In and MCM‐41‐INA‐Tl) have been developed using a covalent grafting method. A surface functionalization method has been applied to prepare Cl‐modified mesoporous MCM‐41 material. Condensation of this Cl‐functionalized MCM‐41 with INA leads to the formation of MCM‐41‐INA. The reaction of MCM‐41‐INA with In(NO3)3 or Tl(NO3)3 leads to the formation of MCM‐41‐INA‐In and MCM‐41‐INA‐Tl catalysts. The resulting materials were characterized using various techniques. These MCM‐41‐INA‐In and MCM‐41‐INA‐Tl catalysts show excellent catalytic performance in the selective oxidation of sulfides and thiols to their corresponding sulfoxides and disulfides. Finally, it is found that the anchored indium and thallium do not leach out from the surface of the mesoporous catalysts during reaction and the catalysts can be reused for seven repeat reaction runs without considerable loss of catalytic performance. 相似文献
67.
68.
通过采用机器学习算法,提出了高温作用后砂岩物理力学性质变化的阈值温度的确定方法。基于Python语言,利用K-Means、SVM算法,实现了对样本数据的分类和聚类,确定了阈值温度区间,验证了二分类法的合理性和准确性.结果表明,砂岩样本的阈值温度区间为400~600 ℃,阈值温度上下砂岩的物理力学性质存在显著差异,体现为阈值温度区间以下的岩样物理力学性质较为分散,而阈值温度区间以上的岩样物理力学性质较为集中. 相似文献
69.
刘春平 《科技导报(北京)》2019,37(9):38-44
19世纪末20世纪初在中华大地上兴起学会热潮,尤其是“五四”新文化运动以来,现代意义上的科技社团在中国已经走过了百年历程,构成世界科技社团发展史上波澜壮阔的画卷之一。在纪念“五四”运动100周年之际,回顾科技社团百年来发展历程,研究分析科技社团在中国科学文化启蒙、科学技术发展和经济社会建设中的重要作用,对于探寻新时代中国科技社团发展道路,具有重要的理论和现实意义。 相似文献
70.
李静云 《科技情报开发与经济》2015,(5):79-80,97
介绍了MOOC的基本概念及其发展情况,探讨了MOOC时代高校图书馆的角色定位,分析了MOOC时代高校图书馆的独特优势,指出高校图书馆只有与MOOC融合发展,才能适应信息化社会的需要。 相似文献