Observation of latent tracks formed by heavy ion irradiation in poly(methyl methacrylate)

The irradiation effect in poly(methyl methacrylate) changed from main‐chain scission to crosslinking, depending on the stopping powers of the Au and Xe ions irradiated with high stopping powers. The latent ion tracks, including an end of the ion range in the polymer, were observed clearly by field emission and atomic force microscopies. Additionally, it was also observed that a crosslinked structure (formed by nuclear stopping) existed across an end of the ion range calculated by a Transport of Ion in Matters code, and it was different from that formed by electronic stopping. The nuclear stopping of the heavy ions can play an important role around the end of the ion range in the polymer. © 2001 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys 39: 757–762, 2001     

Studies on epoxy resins cured by cationic latent thermal catalysts: The effect of the catalysts on the thermal,rheological, and mechanical properties

To investigate the effect of catalysts on the thermal, rheological, and mechanical properties of an epoxy system, a resin based on diglycidyl ether of bisphenol‐A (DGEBA) was cured by two cationic latent thermal catalysts, N‐benzylpyrazinium hexafluoroantimonate (BPH) and N‐benzylquinoxalinium hexafluoroantimonate (BQH). Differential scanning calorimetry was used for the thermal characterization of the epoxy systems. Near‐infrared spectroscopy was employed to examine the cure reaction between the DGEBA and the latent thermal catalysts used. The rheological properties of the blend systems were investigated under an isothermal condition with a rheometer. To characterize the mechanical properties of the systems, flexure, fracture toughness (K_IC), and impact tests were performed. The phase morphology was studied with scanning electron microscopy of the fractured surfaces of mechanical test samples. The conversion and cure activation energy of the DGEBA/BQH system were higher than those of the DGEBA/BPH system. The crosslinking activation energy showed a result similar to that obtained from the cure kinetics of the blend systems. The flexure strength, K_IC, and impact properties of the DGEBA/BQH system were also superior to those of the DGEBA/BPH system. This was a result of the substituted benzene group of the BQH catalyst, which increased the crosslink density and structural stability of the epoxy system studied. © 2000 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 39: 187–195, 2001     

基于潜在类别条件Logit模型的机舱座位选择行为

为向旅客推送精细化座位推荐服务,通过潜在类别条件logit模型探究了旅客座位偏好及座位效用差异。首先运用解释结构模型筛选出影响旅客选座的关键因素;其次对旅客及其选择偏好进行RP-SP调查,运用潜在类别条件Logit模型划分旅客类别,进一步探究不同因素对旅客类别的影响程度;最后构建不同类别旅客机舱座位效用函数,根据效用最大化原则判断旅客选择行为。结果表明,旅客在机舱座位选择行为上存在异质性,旅客被划分为三个类别：class1占比38.8%,倾向于选择第一排或紧急通道排的过道位置;class2占比39.8%,倾向于选择靠窗座位;class3占比21.4%,倾向于过道位置。研究将为航空公司进行座位管理及制定座位附加服务费提供理论及决策支持。     

图书馆员能力的开发与利用

将图书馆工作岗位分为基础岗位和技术岗位,根据岗位的要求,提出了对图书馆员的文化素质和业务能力的要求,并提出了激活图书馆员潜能力的措施和激活能力以后的管理对策。     

“502”胶显现汗潜手印后Basic Red 29染色的应用研究

研究一种新型的荧光染料碱性红29用于"502"胶显现手印后染色的方法。通过荧光分光光度计测定了该染料的激发光谱和发射光谱;并对其应用条件进行了考察,包括最佳配方、观察条件、不同客体手印显现效果、陈旧手印的处理方法等方面。结果表明,浓度为0.1 g/L的碱性红乙醇溶液,在530~550 nm范围内激发,在橙色滤光镜下观察能产生橙黄色的荧光,很好地增强了与客体背景的反差,提高了手印的显现率,由于其荧光效率高、安全无毒、吸附性好等优点,在公安实际工作中有很好的应用前景。     

Preparation,characterization, and performance study of beeswax/expanded graphite composite as thermal storage material

In this study, beeswax as a new energy storage material and its composite with expanded graphite were prepared and characterized for their surface and thermal properties. Surface characterization showed no chemical interaction between beeswax and expanded graphite. The thermal conductivity of the composite was improved with 117% enhancement. The thermal performance of beeswax and its composite as a heat storage material was studied in a rectangular shell-and-tube thermal storage unit. The melting point of the composite remained almost same as that of beeswax; however, the melting time was reduced considerably, from 540 to 360 min with inlet water at 80°C and a 2-lpm flow rate.     

一种基于上下文信息的乳腺肿块ROI检测方法

传统的ROI(region of interest)检测方法忽略了图像中的上下文信息,为了解决这个问题,本文利用概率潜在语义分析(probability latent semantic analysis,PLSA)来对图像中的每块区域周围的图像特征进行分析,并利用其作为上下文特征来辅助ROI的检测。实验表明,该方法与直接进行分类相比,能够取得更好的分类效果。     

基于分形的多孔介质复合相变材料的储热特性

本文利用膨胀石墨和纳米颗粒来强化相变储热系统的传热性能。在膨胀石墨基体中填充含纳米颗粒的相变材料,用焓-孔隙度法模拟材料的相变过程。针对不规则的膨胀石墨孔隙结构,用三维W-M分形函数修正膨胀石墨孔隙率波动,以研究不同的孔隙率和有效导热系数比对固态显热蓄热阶段相变材料熔融速率的影响。在液态显热蓄热阶段时探讨膨胀石墨孔隙率以及纳米颗粒体积分数对相变储热系统中对流传热的影响。研究结果表明,分形分布的孔隙结构能有效地抑制纳米颗粒的自由运动从而降低了纳米颗粒的局部团聚的可能性,所以利用三维W-M分形函数修正的膨胀石墨比采用平均孔隙率能更好地模拟相变材料的熔融速率。在固态显热蓄热阶段,膨胀石墨孔隙率为0.8的相变材料熔融速率比孔隙率为0.85和0.9显著增加,另外,膨胀石墨与纳米颗粒-相变材料的有效导热系数比为100的熔融速率也明显比有效导热系数比为80和60的快。当相变材料处于液态显热蓄热阶段时,其在膨胀石墨孔隙中产生对流,对流传热速率随着膨胀石墨的孔隙率增大而增大,纳米颗粒体积分数的增加也会提高对流传热速率。     

Melting temperature and enthalpy variations of phase change materials (PCMs): a differential scanning calorimetry (DSC) analysis

Differential scanning calorimetry (DSC) analysis is a standard thermal analysis technique used to determine the phase transition temperature, enthalpy, heat of fusion, specific heat and activation energy of phase change materials (PCMs). To determine the appropriate heating rate and sample mass, various DSC measurements were carried out using two kinds of PCMs, namely N-octadecane paraffin and calcium chloride hexahydrate. The variations in phase transition temperature, enthalpy, heat of fusion, specific heat and activation energy were observed within applicable heating rates and sample masses. It was found that the phase transition temperature range increased with increasing heating rate and sample mass; while the heat of fusion varied without any established pattern. The specific heat decreased with the increase of heating rate and sample mass. For accuracy purpose, it is recommended that for PCMs with high thermal conductivity (e.g. hydrated salt) the focus will be on heating rate rather than sample mass.     

钐钆共掺杂荧光配合物的合成及在潜手印显现中的应用

以2-噻吩甲酰三氟丙酮(TTA)为第一配体,邻菲罗啉(o-Phen)为第二配体,利用共沉淀法合成一系列钐钆共掺杂荧光配合物,并优化了该系列荧光配合物的合成条件(反应温度、体系pH、稀土离子相对含量).将最优条件合成的Sm0.5 Gd0.5 TTA3(o-Phen)荧光配合物粉末用于常见光滑非渗透性客体表面潜在手印的显现...