B-Splines with Arbitrary Connection Matrices

We consider a space of Chebyshev splines whose left and right derivatives satisfy linear constraints that are given by arbitrary nonsingular connection matrices. We show that for almost all knot sequences such spline spaces have basis functions whose support is equal to the support of the ordinary B-splines with the same knots. Consequently, there are knot insertion and evaluation algorithms analogous to de Boors algorithm for ordinary splines.     

The Volume of Hyperbolic Alternating Link Complements

If a hyperbolic link has a prime alternating diagram D, thenwe show that the link complement's volume can be estimated directlyfrom D. We define a very elementary invariant of the diagramD, its twist number t(D), and show that the volume lies betweenv₃(t(D) – 2)/2 and v₃(10t(D) – 10), where v₃ isthe volume of a regular hyperbolic ideal 3-simplex. As a consequence,the set of all hyperbolic alternating and augmented alternatinglink complements is a closed subset of the space of all completefinite-volume hyperbolic 3-manifolds, in the geometric topology.2000 Mathematics Subject Classification 57M25, 57N10.     

A geometric formula for Haefliger knots

Haefliger has shown that a smooth embedding of the (4k−1)-sphere in the 6k-sphere can be knotted in the smooth sense. In this paper, we give a formula with which we can detect the isotopy class of such a Haefliger knot. The formula is expressed in terms of the geometric characteristics of an extension, analogous to a Seifert surface, of the given embedding. In particular, the Hopf invariant associated to the extension plays a crucial role. This leads us to a new characterisation of Haefliger knots.     

The Neighborhood Union of Essential Sets and Hamiltonicity of Graphs

Let G be a graph. An independent set Y in G is called an essential independent set (or essential set for simplicity) if there is {y1,y2} (?) Y such that dist (y1,y2) = 2. In this paper, we use the technique of the vertex insertion on l-connected (l = k or k + 1, k≥ 2) graphs to provide a unified proof for G to be hamiltonian, or hamiltonian-connected. The sufficient conditions are expressed     

All frame-spun knots are slice

Frame-spun knots are constructed by spinning a knot of lower dimension about a framed submanifold of . We show that all frame-spun knots are slice (null-cobordant).

     

无K1,r图中的哈密顿圈（英文）

本文借助对图的本质独立集和图的部分平方图的独立集的研究，对于K1,r图中哈密顿圈的存在性给出了八个充分条件。我们将利用T－插点技术对这八个充分条件给出统一的证明，本文的结果从本质上改进了C－Q.Zhang于1988年利用次形条件给出的k-连通无爪图是哈密顿图的次型充分条件，同时。G.Chen和R.H.Schelp在1995年利用次型条件给出的关于k-连通无K1，4图是哈密顿图的充分条件也被我们的结果改进并推广到无K1,r图。     

A theory of concordance for non-spherical 3-knots

Consider a closed connected oriented 3-manifold embedded in the -sphere, which is called a -knot in this paper. For two such knots, we say that their Seifert forms are spin concordant, if they are algebraically concordant with respect to a diffeomorphism between the 3-manifolds which preserves their spin structures. Then we show that two simple fibered 3-knots are geometrically concordant if and only if they have spin concordant Seifert forms, provided that they have torsion free first homology groups. Some related results are also obtained.

     

Reaction mechanism and rate constants of the CH+CH4 reaction: a theoretical study

Ab initio and density functional calculations have been performed to elucidate the mechanism of CH radical insertion into methane. The results show that the reaction can be viewed to occur via two stages. On the first stage, the CH radical approaches methane without large structural changes to acquire proper positioning for the subsequent stage, where H-migration occurs from CH₄ to CH, along with a C–C bond formation. Where the first stage ends and the second begins, a tight transition state was located using the B3LYP/6-311G(d,p) and MP4(SDQ)/6-311++G(d,p) methods. Using a rigid rotor – harmonic oscillator approach within transition state theory, we show that at the MP5/6-311++G(d,p)//MP4(SDQ)/6-311++G(d,p) level the calculated rate constants are in a reasonably good agreement with experiment in a broad temperature range of 145–581 K. Even at low temperatures, the insertion reaction bottleneck is found about the location of the tight transition state, rather than at long separations between the CH and CH₄ reactants. In addition, high level CCSD(T)-F12/CBS calculations of the remainder of the C₂H₅ potential energy surface predict the CH+CH₄ reaction to proceed via the initial insertion step to the ethyl radical which then can emit a hydrogen atom to form highly exothermic C₂H₄+H products.     

Influences of flexible defect on the interplay of supercoiling and knotting of circular DNA

Knots are discovered in biophysical systems, such as DNA and proteins. Knotted portions in knotted DNA are significantly bent and their corresponding bending angles are comparable with or larger than the sharp bending angle resulting in flexible defects. The role of flexible defects in the interplay of supercoiling and knotting of circular DNA were predicted by a Monte Carlo simulation. In knotted DNA with a particular knot type, a flexible defect noticeably enhances the supercoiling of the knotted DNA and the decreasing excitation energy makes the knotted portion more compact. A reduction in twist rigidity and unwinding of flexible defects are incorporated into the numerical simulations, so that interplay of supercoiling and knotting of circular DNA is studied under torsional conditions. Increasing unwinding not only results in a wider linking number distribution, but also leads to a drift of the distribution to lower values. A flexible defect has obvious effects on knotting probability. The summation of equilibrium distribution probability for nontrivial knotted DNA with different contour length does not change with excitation energy monotonically and has a maximum at an intermediate value of excitation energy around 5 kBT. In the phase space of knot length and gyration radius of knotted DNA, knot length does not anticorrelate with its gyration radius, which is attributed to the flexible defect in the knotted portion, which leads to the release of bending energy and inhibited the competition between entropy and bending energy.     

Knot solitons in AFZ model

This paper studies the topological properties of knotted solitons in the (3+1)-dimensional Aratyn--Ferreira--Zimerman (AFZ) model. Topologically, these solitons are characterized by the Hopf invariant I, which is an integral class in the homotopy group π₃(S³)=Z. By making use of the decomposition of U(1) gauge potential theory and Duan's topological current theory, it is shown that the invariant is just the total sum of all the self-linking and linking numbers of the knot family while only linking numbers are considered in other papers. Furthermore, it is pointed out that this invariant is preserved in the branch processes (splitting, merging and intersection) of these knot vortex lines.