Generalized cyclic cohomology associated with deformed commutators

The generalized cyclic cohomology is introduced which is associated with -deformed commutators . Some formulas related to the trace of the product of -deformed commutators are established. The Chern character of odd dimension associated with -deformed commutators is studied.

     

铬（Ⅲ）—尼克酸配合物合成方法的改进及其与酸反应特性的研究

为了避免Ｃｒ（ＯＨ）３引起的污染,本文用改进的方法合成了配合物Ｃｒ（ｎｉｃ）２（Ｈ２Ｏ）３ＯＨ,这里ｎｉｃ表示尼克酸根。通过红外光谱、热分析对其结构进行了表征。结果表明,尼克酸以羧基氧与铬（Ⅲ）配位。对该配合物与酸的反应特性和可能的机理进行了研究讨论。     

质心层次特征的无约束手写体数字识别

光学字符识别（ＯＣＲ）是模式识别最为成功的应用之一．目前,ＯＣＲ的研究重点是无约束手写体字符识别．采用了基于字符质心的层次特征对无约束手写体数字进行分类识别．基于字符质心的不均匀分块方法,在一定程度上可以克服无约束手写体数字字形千变万化所引起的不稳定性．层次特征将字符在空间的二维分布转化为一维,特征抽取过程简单,易于实现．将该算法应用于无约束手写体数字的信函分拣系统,单字的平均识别率达９７％以上．     

HYDC数据压缩器

描述了采用代换式压缩法,设计一个高效率的数据压缩器ＨＹＤＣ的过程,并给出一个在实际应用中的例子。     

期刊编辑基本素质浅论

期刊编辑人员的政治、文化业务水平与人格构成其基本素质的三大要素。政治素质产生出期刊的文化导向性;文化业务水平制约着刊物的内在质量,决定期刊内容与形式能否表里统一;人格因素具有保证性,它可使期刊不断为社会文化洪流注入具有生命活力的股股清泉,以高尚的精神塑造人,把最好的东西奉献给人     

“黑麦草-水稻”草田轮作系统的根际效应 Ⅱ.冬种黑麦草对土壤物理化学性状的影响

研究了冬种黑麦草对土壤物理化学性状的影响．结果表明,冬种黑麦草使土壤容质量下降９．４％,而对照区仅下降４．０％;冬种黑麦草使土壤有机质质量分数提高了６６％,而对照区降低了１４％;冬种黑麦草使土壤的全Ｎ,全Ｐ和有效Ｎ,有效Ｐ的质量分数分别提高了２６％,３２％,６７％和３３％,而对照区下降了１３％,４％,２０％和１３％;冬种黑麦草使土壤的全Ｋ和有效Ｋ质量分数提高了１４％和７８％,对照区也提高了１０％和１０％;种草区虽然土壤养分的增加与施肥有关,但有效Ｎ和Ｋ的增加显然还受到根际效应的影响,其证据是：在种草区,尽管土壤中的Ｎ通过收获黑麦草产生了较大的净输出（２８．０ｇ／ｍ２）,但土壤Ｎ含量仍然有不寻常的增加,说明可能存在着不明Ｎ源．２种养分有效含量的增幅比全量的增幅更大．从收获的黑麦草中发现土壤有Ｎ的净输出,可能是由于冬种黑麦草有不明来源的Ｎ素积累．     

Modification of HPTLC-plates by in situ chemical bonding with non-polar and polar organosilanes

A method has been developed for the preparation of modified silica plates for high performance thin-layer chromatography (HPTLC). Some typical organosilanes were thus allowed to react in situ with the silica of Merck HPTLC-plates. This method was found to be highly reproducible, simple and cheap. Non-polar plates were prepared and compared with commercial plates from Merck, Whatman and Macherey-Nagel. Modification with cyanodecyltrichlorosilane resulted in plates that showed good coverage, efficiency and low residual silica activity. Silica modified with a multifunctional silane has different properties in different organic solvents. It will appear to be non-polar in a polar solvent and vice versa. New advantageous separation systems are thus made feasible by the presence of cyano groups on the plate. The utility of modified thin-layer plates is demonstrated by the separation of some homologues of p-hydroxybenzoic acid esters and of some polycyclic aromatic hydrocarbons.     

Full Non-rigid Group of Sponge and Pina

The non-rigid molecule group theory (NRG) in which the dynamical symmetry operations are defined as physical operations is a new field in chemistry. Smeyers and Villa computed the r-NRG of the triple equivalent methyl rotation in pyramidal trimethylamine with inversion and proved that the r-NRG of this molecule is a group of order 648, containing a subgroup of order 324 without inversions (see J. Math. Chem. 28(4) (2000) 377–388). In this work, a computational method is described, by means of which it is possible to calculate the symmetry group of molecules. We study the full non-rigid group (f-NRG) of Sponge and Pina molecules with C ₂ and C _i point groups, respectively. It proved that these are groups of order 162 and 13122 with 54 and 3240 conjugacy classes, respectively. The character tables of these groups are also computed.     

Electron transfer from dibenzo[b,f]-1-azapentalene dianion: Attempted synthesis of dibenzo[b,f]-1-azapentalene

When dibenzo[b,f]-1-azapentalene dianion (3) was allowed to react with either iron (III) chloride or ethylene bromide, a one-electron transfer from3 took place readily to give the radical anion11. Further electron transfer from11 did not occur presumably due to the antiaromatic character of dibenzo[b,f]-1-azapentalene (1) that would have resulted. The radical anion11 underwent further transformation by hydrogen abstraction from the solvent to give 5,10-dihydroindeno[1,2-b]indole (2) and by dimerization to themeso and (R,S) isomers of 5,5,10,10-tetrahydro-10,10-biindeno[1,2-b]indole (4 a and4 b) respectively.

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Elektronentransfer von Dibenzo[b,f]-1-azapentalen-Dianion: Ein Versuch zur Synthese von Dibenzo[b,f]-1-azapentalen

Zusammenfassung Die Reaktion von Dibenzo[b,f]-1-azapentalen-Dianion (3) mit Eisen (III) oder Ethylenbromid ergab einen Ein-Elektronentransfer zum Radikalanion11. Ein weiterer Elektronentransfer fand nicht statt, vermutlich wegen des antiaromatischen Charakters von Dibenzo[b,f]-1-azapentalen (1), das dabei entstehen müßte. Das Radikalanion11 ergab unter Wasserstoffentzug aus dem Lösungsmittel 5,10-Dihydroindeno[1,2-b]indol (2), das weiter zummeso- bzw. (R,S)-5,5,10,10-tetrahydro-10,10-biindeno[1,2-b]indol (4 a bzw.4 b) dimerisierte.

     

CuO超细粉体的形貌与红外特性研究

CuO作为一种多功能精细无机材料，在印染、陶瓷、玻璃及医药等领域的应用已有数十年的历史，作为催化剂的主要活性成分，近年来在氧化、加氢、C１化学合成、NOx还原、CO及碳氢化合物燃烧、精细化工等多种催化反应中也得到了广泛的应用。可以推测，当CuO材料的粒度达到纳米级时，将使它的功能更加独特，应用更为广泛。因此CuO纳米材料的制备方法、聚集状态、与其他组分或载体的作用状况及催化活性等成为当前功能材料发展的研究热点之一犤１～８犦。我们在前文中报道了直接热解Cu２（OH）２CO３所得CuO粒径小、分布均匀、比表面积大，…