Thiol–norbornene materials: Approaches to develop high Tg thiol–ene polymers

The ability to prepare high T_g low shrinkage thiol–ene materials is attractive for applications such as coatings and dental restoratives. However, thiol and nonacrylated vinyl materials typically consist of a flexible backbone, limiting the utility of these polymers. Hence, it is of importance to synthesize and investigate thiol and vinyl materials of varying backbone chemistry and stiffness. Here, we investigate the effect of backbone chemistry and functionality of norbornene resins on polymerization kinetics and glass transition temperature (T_g) for several thiol–norbornene materials. Results indicate that T_gs as high as 94 °C are achievable in thiol–norbornene resins of appropriately controlled chemistry. Furthermore, both the backbone chemistry and the norbornene moiety are important factors in the development of high T_g materials. In particular, as much as a 70 °C increase in T_g was observed in a norbornene–thiol specimen when compared with a sample prepared using allyl ether monomer of analogous backbone chemistry. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 5686–5696, 2007     

A Galois Connection

The connection presented in this paper mirror-links two metamathematical structures, the finitary closure operators, and the compact consistency properties, in such a way that a specification of one structure induces a provably equivalent specification of the other. Mathematics Subject Classification (2000): Primary 06A15, Secondary 28E10 03B22     

棉纤维与精梳纱之间性能关系的探讨

为了确定棉纤维性能对精梳纱性能的影响，分别从梳棉前的纤维中和同一纺纱工艺流程的粗纱中选同样９种不同的纤维作为试样进行实验。根据实验数据．得到了纤维性能与纱线性能之间关系的回归方程式，为从纤维直接预测纱线性能提供了一条快速、简捷的方法和途径。     

佛山市城市公共交通发展策略

通过对佛山市公共交通客流和公共交通设施现状的调查，掌握了居民出行规律和客运交通特征指标．采用定性和定量相结合的方法，综合评价了公共交通现状的水平．在分析佛山市未来社会经济、城市发展基本特征的基础上，根据客流分布特点、发展态势及客流交通的生成变化特征，采用经验加模型系统方法，科学地预测发展需求．结合佛山市的实际，分析了公共交通的优劣势，确定了优先发展公共交通的方针与目标．对公共交通政策进行了研究，并提出确保实施公共交通目标的对策和措施     

一类有不动点性的Banach空间

本文研究弱一致Opial条件的性质；弱一致Opial条件与弱一致Opial条件的对偶性；证明当对偶空间有弱一致Opial条件时该Banach空间具有不动点性．     

都匀阶地土的承载特性研究

分析了阶地的形成与土层序列阶地土的判属以及持力层和承载。     

试析新中国户籍制度形成的历史背景

新中国户籍制度的形成，既有其深刻的历史渊源，更是中华人民共和国成立后重工业优先发展战略和计划经济体制的必然产物。     

论城市社区体育的大众化

城市社区体育大众化有着深刻的内涵和重要的意义,但也面临着认识偏差、投入不足、人才短缺、中青年居民参与度低等问题,针对这些问题本文提出了提高认识、资金投入、整合现有资源、加紧培养人才、培育体育社团、扶持体育产业等对策.     

农村土地产权制度与土地综合生产能力的经济学分析

现存农村土地制度存在的主要问题是:土地的产权关系不明晰,土地使用权的不稳定,降低了农民对土地的利用效率;农民进行土地改良的投资十分有限,大大降低了土地综合生产能力.本文从产权经济学的角度分析农村土地产权制度与土地综合生产能力的关系.     

一些高Tc超导体的弹性性质

 本文用超声相比较方法测定了高T_c超导体La_1.85Sr_0.15CuO₄，La₂CuO₄和YBa₂Cu₃O₇的纵波和横波声速，进而导出了它们的纵向模量、切变模量、杨氏模量、泊松比、德拜温度及定体比热。在La_1.85Sr_0.15CuO₄样品上，还进行了压力实验，发现所有弹性模量都是随压强增加而增加。定体比热c_V和泊松比σ在高压下则略有下降。德拜温度是随压强增加而增加的。