平头pH电极-流动注射联用技术快速滴定食醋中醋酸的方法研究

采用一种具有平头结构的pH电极作为流动注射分析(FIA)的检测器,构建了流动注射自动化酸度滴定系统.优化了样品进样量、流速、载液浓度和反应管长度等参数.用NaOH溶液作为载液,在4.639×10-4～0.212 mol·L-1范围内醋酸浓度的对数与FIA峰的峰面积成正比,该方法的相对标准偏差(RSD)小于0.5%.采用...     

Trace analysis of pesticides in paddy field water by direct injection using liquid chromatography-quadrupole-linear ion trap-mass spectrometry

A multiresidue method was developed for the quantification and confirmation of 70 pesticides in paddy field water. After its filtration, water was injected directly in a liquid chromatograph coupled to a hybrid triple quadrupole-linear ion trap-mass spectrometer (QqLIT). The list of target analytes included organophosphates, phenylureas, sulfonylureas, carbamates, conazoles, imidazolinones and others compounds widely used in different countries where rice is cropped. Detection and quantification limits achieved were in the range from 0.4 to 80 ng L(-1) and from 2 to 150 ng L(-1), respectively. Correlation coefficients for the calibration curves in the range 0.1-50 μg L(-1) were higher than 0.99 except for diazinon (0.1-25 μg L(-1)). Only 9 pesticides presented more than 20% of signal suppression/enhancement, no matrix effect was observed in the studied conditions for the rest of the target pesticides. The method developed was used to investigate the occurrence of pesticides in 59 water samples collected in paddy fields located in Spain and Uruguay. The study shows the presence of bensulfuron methyl, tricyclazole, carbendazim, imidacloprid, tebuconazole and quinclorac in a concentration range from 0.08 to 7.20 μg L(-1).     

Using multiple short-end injections to develop fast electrophoretic separations--applications in iodide analysis

The aim of this study was to develop a fast CE separation method by using multiple short-end injections in a capillary coated with quaternary ammonium chitosan (HACC), in order to determine the iodide content of pharmaceutical formulations. The BGE was composed of 20 mM tris(hydroxymethyl)aminomethane and 11 mM hydrochloric acid, at pH 8. The internal standard used was thiocyanate. Separations were performed in a fused silica capillary (32 cm total length, 8.5 cm effective length and 50 μm i.d.) coated with HACC and direct UV detection at 220 nm. EOF was modified by flushing the capillary with polymeric solution, resulting in a semi-permanent coating of controlled and stable EOF. The EOF was anodic at pH 8. Different strategies, using single and multiple injection short-end configurations, were studied to develop a CE method that resulted in a maximum number of iodide samples analyzed per hour: one plug and flush (Sflush) 35 samples/h, one plug without flush (SWflush) 76 samples/h, four plugs and flush (Mflush) 61 samples/h, and four plugs without flush (MWflush) 80 samples/h. Using the multiple injection configuration, it was possible to inject up to four plugs using spacer electrolytes with good separation efficiency and selectivity. The voltage application time needed to separate the eight peaks (iodide and thiocyanate) with MWflush was only 12s. The method was validated and samples were analyzed using MWflush. Good linearity (R(2)>0.999); a limit of detection 0.4 mg L(-1); intermediate precision better than 3.8% (peak area) and recovery in the range of 99-102% were obtained.     

Diffusion of magnetic nanoparticles in a multi-site injection process within a biological tissue during magnetic fluid hyperthermia using lattice Boltzmann method

In this study the lattice Boltzmann model (LBM) has been used to simulate diffusion of magnetic nanoparticles (MNPs) injected at multiple sites inside a biological tissue during magnetic fluid hyperthermia (MFH). To validate the numerical results, diffusion in infinite one and two dimensional domains have been compared with the analytical solutions. Agreement were excellent. Also diffusion of a water based nanofluid containing magnetite MNPs (ferrofluid) for mono and multi-site injection in the tissue has been studied. Moreover, the effects of ferrofluid injection volume as well as infusion flow rate of ferrofluid on the distribution of MNPs have been investigated.     

Rolling/sliding of a particle on a flat wall in a linear shear flow at finite Re

Recently Lee and Balachandar proposed analytically-based expressions for drag and lift coefficients for a spherical particle moving on a flat wall in a linear shear flow at finite Reynolds number. In order to evaluate the accuracy of these expressions, we have conducted direct numerical simulations of a rolling particle for shear Reynolds number up to 100. We assume that the particle rolls on a horizontal flat wall with a small gap separating the particle from the wall (L = 0.505) and thus avoiding the logarithmic singularity. The influence of the shear Reynolds number and the translational velocity of the particle on the hydrodynamic forces of the particle was investigated under both transient and the final drag-free and torque-free steady state. It is observed that the quasi-steady drag and lift expressions of Lee and Balachandar provide good approximation for the terminal state of the particle motion ranging from perfect sliding to perfect rolling. With regards to transient particle motion in a wall-bounded shear flow it is observed that the above validated quasi-steady drag and lift forces must be supplemented with appropriate wall-corrected added-mass and history forces in order to accurately predict the time-dependent approach to the terminal steady state. Quantitative comparison with the actual particle motion computed in the numerical simulations shows that the theoretical models quite effective in predicting rolling/sliding motion of a particle in a wall-bounded shear flow at moderate Re.     

An experimental study of fuel injection strategies in CAI gasoline engine

Combustion of gasoline in a direct injection controlled auto-ignition (CAI) single-cylinder research engine was studied. CAI operation was achieved with the use of the negative valve overlap (NVO) technique and internal exhaust gas re-circulation (EGR). Experiments were performed at single injection and split injection, where some amount of fuel was injected close to top dead centre (TDC) during NVO interval, and the second injection was applied with variable timing. Additionally, combustion at variable fuel-rail pressure was examined.Investigation showed that at fuel injection into recompressed exhaust fuel reforming took place. This process was identified via an analysis of the exhaust-fuel mixture composition after NVO interval. It was found that at single fuel injection in NVO phase, its advance determined the heat release rate and auto-ignition timing, and had a strong influence on NO_X emission. However, a delay of single injection to intake stroke resulted in deterioration of cycle-to-cycle variability. Application of split injection showed benefits of this strategy versus single injection. Examinations of different fuel mass split ratios and variable second injection timing resulted in further optimisation of mixture formation. At equal share of the fuel mass injected in the first injection during NVO and in the second injection at the beginning of compression, the lowest emission level and cyclic variability improvement were observed.     

Stabilization of flow boiling in a micro tube with air injection

Air injection as a stabilization method is evaluated for flow boiling in a micro tube. Pyrex glass tube coated by ITO film is employed as a test tube for flow visualization with water as a working fluid. Air bubble and liquid slug lengths are controlled by changing air and liquid mass velocities. Wall temperatures and inlet/outlet pressures show very large fluctuations during flow boiling without air injection. Severe reverse flow is also observed from flow visualization. On the other hand, wall temperature and inlet/outlet pressures as well as visualized flow patterns become very stable with air injection. In addition, much higher heat transfer coefficients are obtained for air injected cases. It is observed from the flow visualization that the flow becomes much stable and shows regular patterns.     

漫谈统计学的应用与发展(4)

本文分两部分:第一部分通过20多个实际案例说明统计学在各个领域的广泛应用,希望使更多的人对统计学有更全面、更深切的了解;第二部分简要介绍统计学在国内外的发展概况,并通过其发展进程的介绍,进一步阐明统计学的意义与价值。同时列举更多的论据说明近代统计学是当今最重要的科学技术之一。     

双卷流燃烧系统的双燃料发动机燃烧排放特性

为解决因生物柴油粘度过大,以及低温燃烧导致的燃油雾化、燃烧性能和排放恶化等问题,利用AMESim软件和AVL_FIRE软件对发动机燃烧室进行双卷流（DS）改造,对喷油提前角、喷孔直径进行优化匹配。结果表明:双卷流（DS）燃烧室燃油分布更加均匀,在运行范围内燃烧速率和功率比浅盆型燃烧室具有更大的优势;同时在加快燃油扩散速率和提高空气利用率方面具有显著的作用;在提高发动机动力性和经济性方面具有明显的优势。采用DS燃烧室、喷油提前角20.6°、喷孔直径0.28 mm组合结构形式的柴油机,其NO排放比原机降低81.83%,指示功率比原机降低7.73%。研究结果可为船用柴油机双燃料低温燃烧性能优化提供一定的指导依据。