4—甲基—6—羟基—2—吡啶酮衍生物的互变异构研究

合成和精制了五个４－甲基－６－羟基－２－吡啶酮衍生物，用核磁共振波谱和 红外光谱研究了它们在氘代二甲基亚砜溶液中的烯醇式、双酮式互变异构平 衡。热力学参数的计算表明，从烯醇式到双酮式构型的转变是一个吸热过程。 当氮原子上带有体积较大的取代基时，在相同的条件下，化合物更容易以双 酮式构型存在。     

机器人阵列式触觉传感器的仿真

阐述了机器人二维和三维触觉传感器仿真的模型、计算机内部表示、一般方法和简化方法（扫描－搜索－填充法）．简化方法利用了物体的区域连贯性，吸收了数控插补的思想，效率较高。仿真生成的触觉图像可用于校验各种触觉图像处理及判断算法的正确性、可靠性和效率。     

Thiol–ene coupling reaction of fatty acid monomers

The reactivities and reaction rates of the thiol–ene coupling reaction of 2‐ethyl‐(hydroxymethyl)‐1,3‐propanediol trimercapto acetate and 2‐ethyl‐(hydroxymethyl)‐1,3‐propanediol trimercapto propionate with two common unsaturated fatty acid methyl esters (methyl oleate and methyl linoleate) were evaluated. The reactions were monitored with real‐time IR and ¹H NMR, which both showed that the mercapto acetate was more reactive than the mercapto propionate. Both thiols were more prone to add to the monounsaturated methyl oleate than to methyl linoleate, which contained two unconjugated double bonds. According to bond energy calculations, the thiol hydrogen of mercapto acetate was somewhat more difficult to abstract than the hydrogen of mercapto propionate. Consequently, the formed S? C bond in the acetate case was stronger than in the propionate case, and so the equilibrium was more shifted toward the addition products. The real‐time IR measurements also showed that the cis unsaturation in methyl oleate isomerized much more quickly than that in methyl linoleate, and this also had an impact on the overall addition rate of the thiols because a trans unsaturation was more reactive than a cis unsaturation. The higher isomerization rates in the oleate systems, compared with those of the linoleate systems, was suggested to be due to a more restricted rotation along the C? C bond of the reacted unsaturation in linoleate. This study showed the importance of trans unsaturations in obtaining reasonable reaction rates in thiol–ene reactions with fatty acid derivatives. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 6346–6352, 2004     

一种新型微机械热导压力敏感器及其数值模拟

本文研究了一种新型微机械ＣＭＯＳ热导压力敏感器。其压力测量范围是０．００１－１００ Ｔｏｒｒ。整个量程范围内，多晶硅热敏电阻相对变化（即灵敏度）优於３０％。为使敏感器结构性能优化，我们首次开发了一软件包对器件热电性能进行数值模拟。三维模拟问题被简化为两个２－Ｄ模拟，并将由稳态能量平衡得到的方程组离散化用非线性Ｇａｕｓｓ－Ｓｅｉｄｅｌ算法迭代求解。器件敏度的模拟结果和实验值相吻合。文中还对温度分布进     

近红外区N－H和O－H振动吸收谱带在定性定量分析中的应用

本研究介绍了如何应用近红外光谱对Ｎ─Ｈ、Ｏ─Ｈ等官能团进行定量分析，以及如何应用近红外光谱法研究金属氧化物的表面羟基与其催化活性的关系。     

包络半群与拓扑动力学中的接近关系

运用包络半群的理论，对接近关系中一个重要定理给出了一个简单证明．作为这一定理的应用，我们得到接近关系可乘性的一个结果．并且对另一种接近关系，也得到一个结果．这两个定理减弱了Ｃｌａｙ在这一领域中两个定理的条件．     

Interaction of multi-raman-processes in miniature optically pumped NH3 fir laser

The principle of Raman gain superposition was introduced to the theory of multi-Raman- processes interaction. Spectral characteristics of Raman lines from miniature NH₃-optically pumped FiR lasers were studied and measured.supported by the National Nature Science Foundation of P.R.C. and the Special Research Foundation of Doctorate Stations of P.R.C.     

Infrared spectroscopy studies of the cyclic anhydride as the intermediate for the ester crosslinking of cotton cellulose by polycarboxylic acids. I. Identification of the cyclic anhydride intermediate

The mechanism of esterification of cotton cellulose by a polycarboxylic acid was investigated using Fourier transform infrared spectroscopy (FT-IR). The infrared spectroscopic data indicate that a polycarboxylic acid esterifies with cotton cellulose through the formation of an acid anhydride intermediate. A five-member cyclic anhydride intermediate was identified in the cotton fabric treated with poly(maleic acid). The five-member cyclic anhydride is a reactive intermediate and readily esterifies when reaction sites are available. We also found that those polycarboxylic acids, which form five-member cyclic anhydride intermediates, crosslink cotton cellulose more effectively than those polycarboxylic acids which form six-member cyclic anhydride intermediates. © 1993 John Wiley & Sons, Inc.     

多信息输出位移传感器

本文提出一种用于空间自由曲面测量的多信息输出位移传感器.该传感器结构简单,传感器的输出量与被测量成线性关系,不但能给出位移信息、倾斜角度,还能给出测量光的强弱信息.