复合材料失效判据有效性验证方法研究

为系统地验证复合材料失效判据计算精度和有效性范围,给出了4种材料体系、6种铺层形式的层合板在单轴、双轴载荷下的失效试验数据,用以评估复合材料失效判据在单向层合板失效包线、多向层合板初始失效包线、多向层合板最终失效包线、层合板变形及层合板的破坏特性等五个方面的预测能力。并根据验证方法和有效性评估策略对失效判据计算精度进行量化考核,给出了失效判据在五个层面上的计算精度。     

Energy transport in boundary driven quantum spin systems: One-way street phenomenon in models with long range interactions

We address the investigation of non trivial properties of the energy current in boundary driven XXZ quantum spin models. In specific, we focus on the occurrence of the one-way street phenomenon in asymmetrical chains, a phenomenon stronger than rectification, which establishes the existence of a unique way for the energy current in the absence of external magnetic field, that is, the magnitude and direction of the energy flow does not change as we invert the baths at the boundaries. For general target polarizations at the boundaries, we show that such a phenomenon holds in the presence of long range interactions, ingredient which increases the flow and the rectification in chains of classical oscillators, and so, of interest in the study of manipulation and control of the energy flow.     

一款2 G/s采样率20 GHz带宽主从式跟踪保持电路设计研究

设计了一款全差分、20 GHz带宽主从式跟踪保持芯片(MS-THA)。该芯片采样率为2 G/s,工作带宽大于20 GHz,采用0.13μm SiGe BiCMOS工艺实现。该芯片采用传统的开关发射极跟随器(SEF)作为跟踪保持核心电路,Cherryhooper电路作为输入缓冲和输出缓冲的带宽增强核心电路,并利用交叉反馈电容抑制馈通。为了验证上述电路的有效性,设计了一个单级THA电路,测试结果为MS-THA电路提供了足够的支持。在单电源+3.3 V供电、输入直流电平为0 V,2 G/s采样率以及-3 dBm输入信号功率条件下,获得的单端输出无杂散动态范围小于-23.5 dB,总功耗约为300 mW。     

Teflon Magnetic Stirring Capsules (TMSC) as a Practical and Reusable Delivery System for Sensitive Reagents and Catalysts

The development of a user-friendly reusable laboratory equipment for the delivery of sensitive reagents and catalysts is described. The tightness of these Teflon Magnetic Stirring Capsules (TMSC) is ensured by the magnetic force and release of the reagent inside the solution is triggered by adjusting the stirring rate so that the centrifuge force exceeds the magnetic force. They can be loaded with several chemicals at the same time and do operate across a broad range of temperatures. The inertness of Teflon facilitates reaction purification.     

多糖凝胶的孔径和化学结构对单壁碳纳米管流动性和选择性分离的影响

基于凝胶柱色谱分离技术研究了单分散的单壁碳纳米管(SWCNTs)在不同化学结构多孔多糖凝胶中的流动特性以及对金属型(m-)/半导体型(s-)SWCNTs分离的影响.通过比较SWCNTs在一系列不同孔径的葡聚糖Sephacryl凝胶中的流动行为,发现减小孔径尺寸能够增强s-SWCNTs与凝胶之间的吸附作用力,使大直径的m-SWCNTs快速地流过凝胶颗粒,而选择性地保留了小直径的s-SWCNTs.进一步发现多糖凝胶化学结构比孔径尺寸在SWCNTs的m/s分离中起着更重要的作用.当基于葡聚糖结构的Sephacryl凝胶中的氨基结构被琼脂糖结构所取代时,如Superdex 200和Sepharose 2B凝胶会增强它们与SWCNTs之间的作用力,使SWCNTs的保留时间延长,降低了s-SWCNTs的选择性和纯度.此外,即使拥有与Sephacryl S100类似的孔径范围,当Sephacryl凝胶中的氨基被疏水环氧丙烷基团取代时,葡聚糖凝胶Sephadex G100与SWCNTs的作用力很弱,导致所有SWCNTs快速流动,无法实现SWCNTs的m/s分离.因而,我们认为凝胶孔径和化学结构共同影响并调控了SWCNTs的m/s分离的选择性、纯度以及分离效率.     

Li3V2（PO4）3/C正极材料在不同电压区间的电化学行为及容量衰减原因

采用溶胶-凝胶法制备锂离子电池正极材料Li3V2(PO4)3/C.通过恒电流充放电测试、循环伏安(CV)、电化学阻抗谱(EIS)等方法,研究了Li3V2(PO4)3/C在不同电压区间的电化学行为(3.0-4.5 V和3.0-4.8 V).结果表明,3.0-4.8 V电压区间的循环性能和倍率性能均不及3.0-4.5 V电压区间的.3.0-4.5 V区间0.1C (1C=150 mA?g-1)倍率首次放电比容量为127.0 mAh?g-1,循环50次后容量保持率为99.5%,而3.0-4.8 V区间的分别为168.2 mAh?g-1和78.5%.经过高倍率测试后再回到0.1C倍率充放电,3.0-4.5 V和3.0-4.8 V的放电比容量分别为初始0.1C倍率的99.0%和80.7%.经过3.0-4.8 V电压区间测试后,少部分第三个锂离子能够在低于4.5 V的电压脱出,使3.0-4.5 V电压区间的放电比容量提升了7.4%. CV结果表明3.0-4.8 V区间的容量损失主要表现为第一个锂离子的不可逆损失.极片的X射线衍射(XRD)和X射线光电子能谱(XPS)分析测试结果表明经过3.0-4.8 V测试后, Li3V2(PO4)3的结构发生了轻微的改变.电感耦合等离子体(ICP)测试结果表明循环后的电解液中含有少量的V.结构变形和V溶解可能是Li3V2(PO4)3在3.0-4.8 V区间容量衰减的主要原因.     

Two Cd（ll） Metal-organic Frameworks （MOFs） Derived from a Triazine-based Flexible Polycarboxylate Ligand： Syntheses, Crystal Structures and Luminescence

Two new metal-organic frameworks, {[Cd2CI（HL）（H20）2＂0.5H20]}n （1） and {[Cd2L（H20）2]＇H20}n （2）, have been hydrothermally synthesized with designed ligand H4L （HaL = 1,3,5-triazine-2-iminodiacetic acid-4,6-biglycine） under the same condition except for different pH values. Single-crystal X-ray determination shows that they are 3-D frameworks. Complex 1 crystallizes in monoclinic, space group P21/n. Complex 2 crystallizes in triclinic, space group Pi. The photoluminescence properties of those two complexes have been investigated in solid state. Complexes 2 exhibited remarkable blue luminescence emissions with high quantum yield of 40.3% On the other hand, complexes 1 featured weak quantum yields of 13.7%.     

有机液体化学试剂馏程测定注意事项

对有机液体化学试剂馏程测定过程中应注意的一些问题如加热源选择、蒸馏速度控制、温度计选择、蒸馏收率以及同一样品不同特性测量结果的相关性分析等进行了分析，为正确测定馏程提供经验和依据。     

仪器定量分析中几个问题的探讨

详细介绍了分析方法的评价指标,包括检出限、测定限、灵敏度、精密度、准确度、动态范围和线性范围、抗干扰能力等,单因素优化方法与加标回收实验评定测定结果准确度的可靠性,并就分析工作中遇到的一些实际问题进行了讨论.     

Influence of the anion on the coordination mode of an unsymmetrical N-heterocyclic ligand in Cd(II) complexes: From discrete molecule to one- and two-dimensional structures

Five new 0D–2D Cd(II) complexes, [Cd₂(Hbimt)₂I₄] (1), [Cd(bimt)(Hbimt)Br]_n (2), [Cd(Hbimt)Cl₂(H₂O)]_n (3), {[Cd(Hbimt)(SO₄)(H₂O)₂]·1.5H₂O}_n (4) and [Cd(Hbimt)(SCN)₂]_n (5) (Hbimt = 2-((benzoimidazol-yl)methyl)-1H-tetrazole) have been synthesized by the reactions of Hbimt with suitable cadmium salts. Employment of different anions can influence the coordination modes of the Hbimt ligand, and accordingly result in different structures ranging from 0D to infinite 1D and 2D networks. Complex 1 displays a dimeric structure in which two Cd(II) ions are bridged through two iodine atoms. Complex 2 was caused by deprotonation of the Hbimt ligand, resulting in a 1D helical chain. While in complexes 3 and 4, Hbimt acts as a bidentate bridging ligand which joins two Cd(II) ions, leading to 1D stair-like chains. Complex 5 exhibits a 2D network structure with infinite 1D [Cd₂(SCN)₂]_n chains. The distinct structures of 1, 2, 3, 4 and 5 reveal that the anions and the versatile coordination modes of the ligand play an important role in the structures of the complexes. In addition, the luminescent properties of complexes 1–5 have been investigated in the solid state at room temperature.