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121.
Vicenç Branchadell Roser Pleixats Claude Commandeur Max Malacria 《Journal of organometallic chemistry》2003,687(2):337-345
Regioselectivity of the Tsuji-Trost reaction on allyl acetates and carbonates substituted with silyl groups at the olefinic moiety has been analyzed. Silicon atom in the central carbon atom increases the stability of the intermediate π-allylpalladium cation with respect to the isomeric π-allylpalladium cation featuring the silicon in a terminal carbon atom. 相似文献
122.
氯代5-氟脲嘧啶卟啉的红外光谱特性的研究 总被引:6,自引:0,他引:6
本文对新合成的对位及间位两类氯代苯基 5 氟脲嘧啶卟啉的红外光谱吸收峰进行了归属和总结 ,讨论了其红外吸收频率随取代基位置变化的规律。指出了苯环上的取代基为电负性强的基团时 ,由于场效应的存在 ,使被测化合物的羰基伸缩振动吸收峰的相对强度发生改变。同时 ,表明了嘧啶环上N原子发生了取代 ,形成单、双取代 5 氟脲嘧啶卟啉化合物的红外光谱特性。 相似文献
123.
Marta Gimnez-Pedrs Ali Aghmiz Carmen Claver Anna M. Masdeu-Bult Denis Sinou 《Journal of molecular catalysis. A, Chemical》2003,200(1-2):157-163
High linear alkenes (1-octene and 1-decene) have been hydroformylated using water-soluble rhodium complexes associated with sulfonated diphosphines in the presence of ionic surfactants or methanol. In all cases, the hydroformylation activities were higher than in experiments without additives. The selectivity in aldehydes was higher when we used cetyltrimethylammonium hydrogensulfate (CTAHSO4) as the surfactant or methanol as the co-solvent. 相似文献
124.
125.
The impact of habitat fragmentation and isolation on the genetic diversity of populations has attracted much attention in studies of meta-population and conservation biology. In this work, using the randomly amplified polymorphic DNA (RAPD) technique, we studied the genetic diversity of central, peripheral and peninsular populations of ratlike hamster, which were collected in five locations of the North China Plain and its surrounding areas, in 1999. The study revealed that, ⅰ) the genetic diversity of central population of Raoyang County>the sub-central populations of Gu'an County and Taikang County>the peripheral population of Shunyi District>the peninsular population of Mentougou District; ⅱ) the genetic diversities of the five populations were positively correlated to the nearest distances to the peripheral line of population distribution; ⅲ) there were significant differences of gene frequencies of some RAPD fragments among the five populations. More RAPD fragments disappeared in peripheral populations than in central or sub-central populations. The frequencies of two RAPD fragments were correlated to the latitude. This study clearly indicated that the variation of the genetic diversities of the five populations was caused by edge effect and frag- mentation through the enhanced inbreeding and genetic drift, and thus supported the view that habitat fragmentation and related edge effect reduce the population genetic diversity. 相似文献
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128.
G. K. Shenoy 《Hyperfine Interactions》2006,170(1-3):5-13
Stanley L. Ruby (1924–2004) made major contributions to Mössbauer spectroscopy and was the first to suggest the feasibility of observing the Mössbauer effect using synchrotron radiation. In this article we recall his scientific legacy that have inspired his scientific colleagues. 相似文献
129.
Due to the Meissner effect, a permanent magnet is levitated, when released above a high temperature superconductor. When there is an inhomogeneous temperature field around the magnet, the magnet might start to oscillate with increasing amplitude until it remains in a continuous rotation. A mathematical model for the described effect is presented which couples heat transfer and electromagnetic forces with the equation of motion, yielding to a multiphysics task. In a detailed analysis it is found, that the torque which drives the rotation of the magnet, is explicitly given in terms of Bessel functions and the Fourier coefficients of order zero and one of the temperature field of the surrounding air. 相似文献
130.
在研究大量实验曲线的基础上,指出势阱所有能级均有一定的宽度,电子或空穴在各能级中出现的概率符合正态分布,从理论上分析了I类超晶格和双势垒单势阱的发光光谱与吸收光谱·解释了GaAs/Ga1-xAlxAs多量子阱和超晶格吸收光谱吸收边及量子阱变窄时各吸收峰的“蓝移现象”及GaAs/Ga1-xAlxAs双势垒单量子阱样品的电流—电压特性曲线及电导—电压特性曲线的特征和出现的“负阻效应”· 相似文献