Chemical bonding in representative astrophysically relevant neutral,cation, and anion HCnH chains

Most existing studies assign a polyynic and cumulenic character of chemical bonding in carbon-based chains relying on values of the bond lengths. Building on our recent work, in this paper we add further evidence on the limitations of such an analysis and demonstrate the significant insight gained via natural bond analysis. Presently reported results include atomic charges, natural bond order and valence indices obtained from ab initio computations for representative members of the astrophysically relevant neutral and charged HC_2k/2k+1H chain family. They unravel a series of counter-intuitive aspects and/or help naive intuition in properly understanding microscopic processes, e.g., electron removal from or electron attachment to a neutral chain. Demonstrating that the Wiberg indices adequately quantify the chemical bonding structure of the HC_2k/2k+1H chains—while the often heavily advertised Mayer indices do not—represents an important message conveyed by the present study.     

Long correlations and Levy models applied to the study of memory effects in high frequency (tick) data

This work is devoted to the study of long correlations, memory effects and other statistical properties of high frequency (tick) data. We use a sample of 25 stocks for this purpose.We verify that the behavior of the return is compatible with that of continuous time Levy processes. We also study the presence of memory effects and long-range correlations in the values of the return.     

用BP神经网络法预测反相液相色谱保留值

运用逐步回归法筛选BP人工神经网络的输入元素改进BP网络的结构，并用于疏水分配常数及氢键作用能预测反相液相色谱保留值，结果表明，逐步回归法与人工神经网络相结合，能优化网络，大大提高网络收敛速度在很大程度上克服了通常BP网络过所合的缺点，较通常BP神经网络及回归法在处理构效关系方面有更强的信息处理能力和预测能力。     

铁路货运总收入与运营指标关系的研究

在分析研究铁路运营指标与全路货运收入的关系的基础上 ,利用因素影响分析理论 ,得出了铁路运营指标对全路货运收入影响的分析计算方法 ,并给出了计算实例 .该方法的计算结果可用于分析运输组织工作中的成绩与不足 ,从而有利于改善运输组织与管理 ,以提高铁路运输业的经济效益     

Capillary gas chromatography-mass spectrometry of all 93 acyclic octenes and their identification in fluid catalytic cracked gasoline

The Kováts retention indices of all 93 acyclic octenes on polydimethylsiloxane and squalane as stationary phases as well as their mass spectra were measured. The means of gas chromatography-mass spectrometry (GC-MS) were used for confirmation of GC identification as well as for mass spectrometric deconvolution of the majority of gas chromatographic unseparated isomeric octene peaks. The distinction between corresponding E and Z acyclic octenes, that is either difficult or even impossible by means of GC-MS, was obtained on the basis of larger temperature coefficients of retention indices for Z isomeric octenes than for corresponding E isomers. The retention data expressed as homomorphy factors were correlated with the degree of branching, position of double bond, and position of alkyl group with respect to the double bond of acyclic octenes, and the structure-retention relationships were formulated. The 81 acyclic octenes were identified in FCC gasoline.     

竞技体育社会评价指标体系构建研究

为实现竞技体育的可持续发展,有必要对竞技体育进行社会评价、根据“资源配置--运行--效益”模式,科学构建竞技体育社会评价的指标体系,有利于竞技体育的良性运行,有利于奥运战略的完成和竞技体育的可持续发展、     

烯烃气相色谱保留指数的预测

通过对部分烯烃在不同固定相不同柱温下的1031个样本集的气相色谱保留指数值(RI)与其部分参数关系的研究,发现RI与拓扑指数(mQ)、双键原子杂化状态指数(DHSI)、支链对双键的极化效应指数(PBD)、固定液极性值(CP)及柱温(T)的关系可表示为:^RI=-58.138 57.7460Q-8.2591Q 0.120T 0.807CP 36.460PBD 7.919DHSI(R=0.9989)继以留一法(Leave-one-out,LOO)进行交互检验,相关系数RCV=0.9977,说明所建模型具有良好的稳定性和预测能力,较好地揭示了烯烃类化合物气相色谱保留指数RI随固定相极性、柱温的改变而变化的规律.     

Enrichment of Zinc and Iron Micronutrients in Lentil (Lens culinaris Medik.) through Biofortification

Biofortification of pulse crops with Zn and Fe is a viable approach to combat their widespread deficiencies in humans. Lentil (Lens culinaris Medik.) is a widely consumed edible crop possessing a high level of Zn and Fe micronutrients. Thus, the present study was conducted to examine the influence of foliar application of Zn and Fe on productivity, concentration, uptake and the economics of lentil cultivation (LL 931). For this, different treatment combinations of ZnSO₄·7H₂O (0.5%) and FeSO₄·7H₂O (0.5%), along with the recommended dose of fertilizer (RDF), were applied to the lentil. The results of study reported that the combined foliar application of ZnSO₄·7H₂O (0.5%) + FeSO₄·7H₂O (0.5%) at pre-flowering (S1) and pod formation (S2) stages was most effective in enhancing grain and straw yield, Zn and Fe concentration, and uptake. However, the outcome of this treatment was statistically on par with the results obtained under the treatment ZnSO₄·7H₂O (0.5%) + FeSO₄·7H₂O (0.5%) at S1 stage. A single spray of ZnSO₄·7H₂O (0.5%) + FeSO₄·7H₂O (0.5%) at S1 stage enhanced the grain and straw yield up to 39.6% and 51.8%, respectively. Similarly, Zn and Fe concentrations showed enhancement in grain (10.9% and 20.4%, respectively) and straw (27.5% and 27.6% respectively) of the lentil. The increase in Zn and Fe uptake by grain was 54.8% and 68.0%, respectively, whereas uptake by straw was 93.6% and 93.7%, respectively. Also the benefit:cost was the highest (1.96) with application of ZnSO₄·7H₂O (0.5%) + FeSO₄·7H₂O (0.5%) at S1 stage. Conclusively, the combined use of ZnSO₄·7H₂O (0.5%) + FeSO₄·7H₂O (0.5%) at S1 stage can contribute significantly towards yield, Zn and Fe concentration, as well as uptake and the economic returns of lentil to remediate the Zn and Fe deficiency.     

工程机械效益评价指标模型

为了研究和确定工程机械效益评价指标,评析了机器的最大牵引力、最大牵引功率和单位机重功率等指标,确定了技术经济综合效益评价指标作为评价机器技术经济水平的优化指标。根据自行式工程机械生产率计算特点,推导、建立了由机器的主要结构性能参数、使用条件及行走机构与地面间的牵引附着特性等因素确定的装载机生产率计算数学模型。计算结果表明,该模型能够更加客观、合理地反映机器的技术经济品质。