在混凝土模拟孔隙液中癸二酸二异辛酯的缓蚀特性研究

采用动电位极化曲线和电化学阻抗谱研究了癸二酸二异辛酯在模拟混凝土孔隙液中对钢筋的保护作用.癸二酸二异辛酯的加入导致混凝土钢筋的腐蚀电位正移,对钢筋的阳极电化学过程有抑制作用.其缓蚀效果随癸二酸二异辛酯浓度增加而增加,当癸二酸二异辛酯的浓度为2%时,对含有400mg/LCl-的混凝土模拟液中钢筋电极的缓蚀效率为78.5%.氯离子含量是影响钢筋腐蚀性能和癸二酸二异辛酯阻锈剂作用的重要因素.癸二酸二异辛酯能够在钢筋表面形成沉淀性保护膜.     

阿魏酸与血清蛋白相互作用研究

应用紫外-可见吸收光谱及荧光光谱法研究了阿魏酸与牛血清蛋白(BSA)在1∶1甲醇水体系中的相互作用.结果表明阿魏酸与BSA发生反应生成新的复合物,荧光猝灭机制为静态猝灭;根据能量转移原理求得阿魏酸与BSA间的结合距离为4.41nm.进一步考察金属离子对此结合反应的影响,结果表明金属离子存在时,BSA荧光猝灭程度加大.     

Structure and corrosion resistance of Al–Cu–Fe alloys

The microstructure and electrochemical properties of Al–Cu–Fe alloys with the atomic compositions of Al_(65)Cu_(20)Fe_(15),Al_(78)Cu_7Fe_(15)and Al_(80)Cu_5Fe_(14)Si_1have been studied.The alloys were produced by induction melting of pure elements with copper mold casting.The microstructure of the alloys was analyzed by X-ray diffraction and high-resolution transmission electron microscopy.The formation of quasicrystalline phases in the Al–Cu–Fe alloys was confirmed.The presence of intermetallic phases was observed in the alloys after crystallization in a form of ingots and plates.The electrochemical measurements were conducted in 3.5%NaCl solution.The electronic structure of the alloys was determined by X-ray photoelectron spectroscopy.The post corrosion surface of the samples was checked using a scanning electron microscope equipped with the energydispersive X-ray detector.It was observed that the Al_(65)Cu_(20)Fe_(15)alloy had the highest corrosion resistance.The improved corrosion resistance parameters were noted for the plate samples rather than those in the as-cast state.And the hardness of the Al_(65)Cu_(20)Fe_(15)alloy was significantly higher than the other alloy samples.     

应用FLRDS技术测量多模光纤的弯曲损耗

光纤环形腔衰荡光谱技术是一种新颖的吸收光谱技术,具有灵敏度高,信噪比强等优点.利用这种技术可以实现环形腔内光损耗的测量.对多模光纤的弯曲损耗进行了定量测量和分析.     

基于红外光谱的稠油界面检测方法研究

稠油界面检测对于稠油的开采利用具有重要意义,然而现有的检测技术效率差,准确率低。建立了稠油和水的热传递模型,主要是热传导和热对流模型,同时也提出了固体壁面的热传递模型,主要是热辐射模型,进行了稠油粘度与温度的实验测定,提出了黏温关系模型。设计了以红外光谱为探测元的界面检测实验,采用了铜和玻璃两种热传导介质,与实验测温结果与传导对流模型一致,证明了所提模型的正确性。     

分子磁体{NBu4[MnFe(ox)3]}n的磁分裂穆斯堡尔谱

用穆斯堡尔谱学方法研究了{NBu4[MnFe(ox)3]}n配合物中磁性离子之间的磁相互作用,当温度低于30 K时,观察到磁分裂谱,磁分裂谱的出现说明配合物中有磁有序发生,谱线的超精细参数说明铁的电子态为高自旋Fe3 ,穆谱结果也说明样品中有自旋倾斜现象发生。     

Influence of acid leaching and calcination on iron removal of coal kaolin

Calcination and acid leaching of coal kaolin were studied to determine an effective and economical preparation method of calcined kaolin. Thermogravimetric-differential thermal analysis (TG-DTA) and X-ray diffraction (XRD) demonstrated that 900℃ was the suitable temperature for the calcination. Leaching tests showed that hydrochloric acid was more effective for iron dissolution from raw coal kaolin (RCK), whereas oxalic acid was more effective on iron dissolution from calcined coal kaolin (CCK). The iron dissolution from CCK was 28.78wt%, which is far less effective than the 54.86wt% of RCK under their respective optimal conditions. Through analysis by using M?ssbauer spectroscopy, it is detected that nearly all of the structural ferrous ions in RCK were removed by hydrochloric acid. However, iron sites in CCK changed slightly by oxalic acid leaching because nearly all ferrous ions were transformed into ferric species after firing at 900℃. It can be concluded that it is difficult to remove the structural ferric ions and ferric oxides evolved from the structural ferrous ions. Thus, iron removal by acids should be conducted prior to calcination.     

回转支承自适应负载的运动控制方法

建立回转支承运动系统的动力学模型,以传统阻抗控制为基础,分析由于动力学模型不确定造成的误差,用神经网络补偿这一误差,建立基于力矩型神经网络阻抗控制结构,并对控制系统进行仿真分析。结果表明:力矩型神经网络阻抗控制器具有良好的自适应性及鲁棒性,能实现回转支承系统的驱动力和位置的双重高精度控制,从而降低功率损耗,有效减少损伤的发生机率和减缓损伤发展速度,延长使用寿命。     

近红外光谱法定量分析亚麻油中的主要组分

用厚度为 1cm的玻璃比色皿作为吸收池 ,测定了亚麻油的近红外光谱 ,利用 70 0 0～ 6 0 0 0cm-1范围内的透波率 ,建立了主成分回归分析模型和BP人工神经网络模型 ,用二模型预测了亚麻油中油酸、亚油酸和亚麻酸的含量 ,预测结果的平均相对误差均在 2 %以内 ,并BP人工神经网络模型预测的效果较好。该法可用于亚麻油中主要组分的实时成分分析。     

基于动力相互作用因子的饱和土中群管桩的纵向振动研究

利用动力Winkler弹簧-阻尼器,模拟桩周饱和土和桩芯饱和土与管桩的动力相互作用.在忽略饱和土径向位移和环向位移的情况下,将桩周饱和土视为由无穷多带一圆孔的薄土层组成,而桩芯饱和土视为由无穷多有界的圆形薄土层组成,运用数学物理手段求得了动力Winkler弹簧-阻尼器模型的刚度系数和阻尼系数.运用初始参数法和传递矩阵法,求得了饱和土中主动管桩和被动管桩的纵向位移,得到了饱和土中管桩-管桩纵向动力相互作用因子.基于管桩-管桩纵向动力相互作用因子和群桩叠加原理,得到了饱和土中群管桩的纵向动力阻抗.数值分析表明:桩间距越大,群管桩纵向动力阻抗随频率变化曲线波动越厉害;管桩内半径和管桩长径比越大,管桩纵向动力阻抗随频率变化曲线幅值越大,而桩土模量比越大则越小;桩间距对群管桩动刚度的影响最大,其次是管桩长径比,最小的是桩土模量比.