全文获取类型
收费全文 | 5495篇 |
免费 | 742篇 |
国内免费 | 614篇 |
专业分类
化学 | 1227篇 |
晶体学 | 32篇 |
力学 | 180篇 |
综合类 | 72篇 |
数学 | 752篇 |
物理学 | 1522篇 |
综合类 | 3066篇 |
出版年
2024年 | 22篇 |
2023年 | 67篇 |
2022年 | 146篇 |
2021年 | 153篇 |
2020年 | 144篇 |
2019年 | 157篇 |
2018年 | 145篇 |
2017年 | 215篇 |
2016年 | 218篇 |
2015年 | 221篇 |
2014年 | 356篇 |
2013年 | 320篇 |
2012年 | 354篇 |
2011年 | 378篇 |
2010年 | 305篇 |
2009年 | 351篇 |
2008年 | 359篇 |
2007年 | 438篇 |
2006年 | 364篇 |
2005年 | 320篇 |
2004年 | 274篇 |
2003年 | 229篇 |
2002年 | 188篇 |
2001年 | 185篇 |
2000年 | 135篇 |
1999年 | 126篇 |
1998年 | 114篇 |
1997年 | 88篇 |
1996年 | 94篇 |
1995年 | 66篇 |
1994年 | 46篇 |
1993年 | 48篇 |
1992年 | 45篇 |
1991年 | 37篇 |
1990年 | 38篇 |
1989年 | 26篇 |
1988年 | 30篇 |
1987年 | 15篇 |
1986年 | 7篇 |
1985年 | 5篇 |
1984年 | 12篇 |
1983年 | 2篇 |
1982年 | 3篇 |
1981年 | 4篇 |
1955年 | 1篇 |
排序方式: 共有6851条查询结果,搜索用时 0 毫秒
51.
The electrical properties of polycrystalline lithium chloroboracite, Li4B7O12Cl, prepared by the sol-gel method were investigated in connection with their structure. Li4B7O12Cl pellets were prepared with different amounts of hydrochloric acid or ammonium chloride. The kind and amount of the chlorine source affected the formation of by-products (Li2B4O7, LiCl, a glass phase) and the morphology of the Li4B7O12Cl pellets. Thus their conductivity, which is dominated by grain boundary response owing to the high porosity of the materials, was also affected. The formation of Li2B4O7 as a by-product led to a higher activation energy and lower conductivity. In those pellets in which Li2B4O7 did form, an increase of the amount of glass phase led to higher conductivities. 相似文献
52.
Impedance biosensors are a class of electrical biosensors that show promise for point-of-care and other applications due to low cost, ease of miniaturization, and label-free operation. Unlabeled DNA and protein targets can be detected by monitoring changes in surface impedance when a target molecule binds to an immobilized probe. The affinity capture step leads to challenges shared by all label-free affinity biosensors; these challenges are discussed along with others unique to impedance readout. Various possible mechanisms for impedance change upon target binding are discussed. We critically summarize accomplishments of past label-free impedance biosensors and identify areas for future research. 相似文献
53.
Alexander S. Bondarenko Genady A. Ragoisha 《Journal of Solid State Electrochemistry》2005,9(12):845-849
Potentiodynamic electrochemical impedance spectroscopy provides extraction of potential-dependent space charge layer capacitance
from potentiodynamic impedance spectra of non-stationary semiconductor–electrolyte interface. The new technique has been applied
for acquisition of Mott-Schottky plots of cathodically treated TiO2 anodic films. Cathodic treatment in 1 M H2SO4 increases donor density and flat band potential of TiO2. Freshly doped films show hysteresis in the space charge layer capacitance in cyclic potential scans. The subsequent cycling
eliminates the hysteresis but preserves the greater part of the doping effect.
Presented at the 4th Baltic Conference on Electrochemistry, Greifswald, 13–16 March 2005 相似文献
54.
55.
BaCe1—xRExO3—0.5x的溶胶—凝胶法合成及离子导电性 总被引:3,自引:0,他引:3
用溶胶-凝胶法合成了系列钙钛矿结构的BaCe1-xRExO3-0.5x(RE=La,Nd,Sm,Eu,Gd,Dy,Ho,Er和Y)复合氧化物,通过XRD和热分析对样品结构及生成过程进行了研究.测定了不同温度下样品的交流阻抗谱,讨论了稀土离子掺杂对BaCeO3电性质的影响.溶胶-凝胶法比固相反应法合成温度降低了600~800℃,稀土掺杂使BaCeO3离子导电率提高了10~40倍. 相似文献
56.
Electrochemical behavior of poly-o-phenylenediamine (PoPhD) films in lithium perchlorate and perchloric acid solutions of different pH and constant ionic strength is studied using cyclic voltammetry, low-amplitude chronoamperometry, chronopotentiometry, and faradaic-impedance spectroscopy. The experimental results point to the diffusion–migration kinetics of charge transfer processes in redox-active PoPhD films and show that two such processes occur during oxidation–reduction of PoPhD. The processes are separated most fully at low concentrations of hydronium ions. Effect of the electrode potential and electrolyte composition on these processes is examined. Different methods yield similar results and permit their more reliable interpretation. 相似文献
57.
The perfect matching vector and forcing and the Kekulé-vector of cata-benzenoids are defined. Two theorems are given which
set the sufficient and necessary conditions for HKZ-vector (Harary et al. J Math Chem 6:295, 1991) and Kekulé-vector in cata-benzenoids.
Additional two theorems are obtained which give sharp bounds for the modules of HKZ- and Kekulé vectors.
Dedicated to Professor Tadeusz Marek Krygowski on the happy occasion of his 70th birthday. 相似文献
58.
The Randić index of an organic molecule whose molecular graph is G is the sum of the weights (d(u)d(v))−1/2 of all edges uv of G, where d(u) and d(v) are the degrees of the vertices u and v in G. We give a sharp lower bound on the Randić index of conjugated trees (trees with a perfect matching) in terms of the number
of vertices. A sharp lower bound on the Randić index of trees with a given size of matching is also given
Mei Lu: Partially supported by NNSFC (No. 60172005)
Lian-zhu Zhang: Partially supported by NNSFC (No. 10271105)
Feng Tian: Partially supported by NNSFC (No. 10431020) 相似文献
59.
Joachim Franzke Maria-Antoaneta Bratescu Damir Veza Kay Niemax 《Mikrochimica acta》1994,113(3-6):349-355
Laser impedance spectroscopy in a miniature neon RF-discharge operating at 0.27 bar was performed. The dominant role of the metastable atoms to the size and the sign of the RF-signal was investigated. Excellent linearity of the RF-signal but poor detection sensitivity of excited metastable neon atoms were found at low laser powers. 相似文献
60.
交流示波极谱法中if~E曲线的研究(Ⅱ):if~E曲线的理论公式 总被引:4,自引:0,他引:4
提出利用i_f~E曲线代替常用的dE/dt~E曲线的新的交流示波极谱法,并研究了该法的基本理论,推导出i_f~E曲线的理论公式。 相似文献