Electrochemical characterization of composite membranes based on crown-ethers intercalated into montmorillonite

Oxyethylene macrocyclic compounds (crown-ethers) act as ligands of intracrystalline cations of certain layered silicates as montmorillonites. Stable intercalation materials are formed which are used to prepare organic-inorganic membranes by encapsulating these intercalation compounds with a poly-butadiene thin coating. Electrochemical Impedance Spectroscopy (EIS) is used to study the resulting composite membranes in contact with aqueous electrolytes. From the impedance plots, the ionic resistance of the membranes is obtained. The thickness of the polybutadiene coating is an important factor determining the ability of ions to pass across the membrane. Marked differences in the ionic resistance are observed as a function of the nature of the interlayer macrocyclic compound. For non-intercalated montmorillonite membranes, the ionic resistance is strongly reduced, whereas for some crown-ether intercalated materials such as 18-crown-6 and dibenzo 24-crown-8, iono-selective membranes are obtained. Concerning the nature of the electrolyte, cations exhibiting greater hydration energies show higher difficulties to pass through the membrane and, consequently, the ionic resistance increases.     

特定最大功率传输问题探讨

本文通过理论计算给出几种特定情况下的功率传输问题。     

小波多尺度分解及其在SAR图象目标检测中的应用

合成孔径雷达图象的目标检测是最重要的任务之一.目前用于目标检测的现有方法速度较慢、准确率较低、精度较差.作者提出小波分解的方法用于目标检测.同尺度目标检测采用二维离散二进小波分解方法,提高检测速度.不同尺度的目标检测采用多尺度二维离散小波分解方法,提高检测准确率.图象匹配采用灰度归一化的灰度相关匹配方法,提高匹配精度.实验证明,采用该法进行目标检测能获得较好的效果.     

APPLICATION OF MECHANICAL IMPEDANCE IN VIBRATION ANALYSIS

In the network of a mechanical system,force F and velocity V are related by mechanicalimpedance Z as:Z=F/V.In this paper,we are going to discuss two cases:①Z=0,which gives the frequency equation of the system.We shall use this equation tosolve some practical examples;②Z=∞,which can serve as the design criterion of dynamic dampers.     

异种钢焊接接头过渡层影响因素的研究

本文根据回归正交优化法原理,用电孤焊试验研究了异种钢焊接接头过渡层的影响因素。通过实测与计算,获得过渡层为零时,最佳匹配的焊接规范参数,为消除过渡层的有害影响探讨了新的途径。     

高校研究生论文答辩系统的设计

介绍了高校研究生论文答辩系统的核心算法,并给出了一种处理冲突的方法——专家相关回溯法。     

Robust Output Tracking Control of an Uncertain Linear System via a Modified Optimal Linear-Quadratic Method

This study investigates the robust output tracking problem for a class of uncertain linear systems. The uncertainties are assumed to be time invariant and to satisfy the matching conditions. According to the selected nominal parameters, an optimal solution with a prescribed degree of stability is determined. Then, an auxiliary input via the use of an adapting factor, connected to the nominal optimal control, is introduced to guarantee the robustness and prescribed degree of stability for the output tracking control of the uncertain linear systems. This method is very simple and effective and can reject bounded uncertainties imposed on the states. A maglev vehicle model example is given to show its effectiveness.     

Structure–electrical property study of anisotropic polyaniline films

The relationships of the structure and electrical properties of anisotropic HCl‐doped polyaniline (PANI) films cast from N,N′‐dimethylpropylene urea (DMPU) solutions and stretched to different draw ratios were studied. The anisotropic structure of the stretched PANI films was examined by X‐ray diffraction, near‐infrared wave‐guide coupling, and polarized infrared measurements. The PANI emeraldine base (EB) films cast from DMPU solutions had a single‐phase noncrystalline structure, and stretching of the films did not cause crystallization to occur. The transition moment angles of two weakly absorbing infrared bands were determined, and the Hermans' orientation functions for the PANI EB films were calculated. The PANI films were then doped with HCl, and the electrical properties were determined by impedance spectroscopy. With a specially designed test fixture, the in‐plane and through‐plane impedance was obtained. The conductivity along the stretch direction increased with orientation. The in‐plane conductivity was significantly higher than the through‐plane conductivity. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 823–841, 2003     

聚合物分散液晶光栅的衍射特性的研究

报道了一种由聚合物分散液晶膜与具有周期性条状电极结构板结合的新型光栅器件，借助于聚合物分散液晶膜的电光特性，这种栅对入射光的散射或衍射取决于对其施加的电压，即它是电场可调的，实验结果显示出当驱动电压超过器件器件阈值电压时，衍射光的强度和衍射斑的可见级次被电场调制，而且它能入射光的线性偏振态变为椭圆偏振态。