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101.
Shi-jun Zheng Qun Xu Shao-kui Cao 《高分子科学》2007,(2):171-179
The novel shish-kebab-type liquid crystalline cross-conjugated (p-phenylene)s-poly(p-phenylenevinylene)s hybrid was synthesized through Gilch polymerization. Their structures and properties were characterized by NMR, GPC, DSC, X-ray diffraction and polarizing optical microscope (POM). ^1H-NMR investigation of the polymers indicates that the shish-kebab-structure has a strong ability to suppress the structural defects in the polymers. The polymers are enantiotropic liquid crystals. The melting point (Tm) of the polymers decreases when the length of the alkoxy tails of the mesogenic units increases. The mesophase was identified by X-ray diffraction method. They showed not only a smectic LC phase, but also a strong green fluorescence in chloroform. The maximum absorption band of the "kebabs" of the two, 5-bis(4'- alkoxyphenyl)benzene at 280 nm did not appear in absorption spectra of the polymers. The same phenomena were also observed in the fluorescence spectra. These results imply that the polymers have formed a cross-conjugated uniform structure and achieved an extended n-conjugation polymer. 相似文献
102.
103.
一维双极粘滞量子流体力学模型解的存在性 总被引:1,自引:0,他引:1
研究了一类一维稳态双极半导体方程的粘滞量子流体力学模型.该模型包含关于粒子浓度和电流密度的连续方程以及电势Poisson方程的耦合方程组,其中含有三阶量子修正项和二阶粘滞项.该问题在有界区间(0,1)中讨论,并通过边界条件的假设将原方程组变形为常见的形式,得到原问题的等价问题.用截断方法将等价问题正则化,并得到正则化问题解的先验估计.利用Leray-Schauder不动点定理证明正则化问题解的存在性,最后通过L∞估计证明正则化问题的解即为原问题的解,从而证明了原双极粘滞量子流体力学模型存在稳态解. 相似文献
104.
We prove the existence of a weak solution for a generalized quantum MHD equation in a 2-dimensional periodic box for large initial data. The existence of a global weak solution is established through a three-level approximation,energy estimates, and weak convergence for the adiabatic exponent γ 1. 相似文献
105.
In this work we employ the state-of-the-art pseudopotential method, within a generalized gradient approximation to the density functional theory, combined with a recently developed method for the calculation of HREELS spectra to study a series of different proposed models for carbon incorporation on the silicon (0 0 1) surface. A fully discussion on the geometry, energetics and specially the comparison between experimental and theoretical STM images and electron energy loss spectra indicate that the Si(1 0 0)-c(4 × 4) is probably induced by Si-C surface dimers, in agreement with recent experimental findings. 相似文献
106.
Camille Thevenot Brice Vincent Sabu Thomas Didier Rouxel 《International Journal of Polymer Analysis and Characterization》2017,22(7):649-658
The purpose of this paper is to understand the mechanisms occurring during the ultrasonication of the copolymer poly(vinylidenedifluoride-trifluoroethylene). In these experimental conditions, the polymer adopts a core–shell structure and its hydrodynamic diameter is measured by dynamic light scattering. The results show that, without covalent bonds breakage, the hydrodynamic diameter decreases with ultrasonication time and a smaller size population appears. This evolution is reversible in a matter of days. A new two-step mechanism is proposed to describe this phenomenon: first the erosion of a core–shell structure and second the contraction of the core. Beyond shedding a new light on the phenomena occurring during the sonication of polymers used in nanocomposites elaboration, this work also strongly questions the traditional techniques used to study the degradation of polymers, which use the hydrodynamic diameter measurement to determine the molecular weight. 相似文献
107.
中学课堂提问不公平问题浅议 总被引:1,自引:0,他引:1
宋娟 《萍乡高等专科学校学报》2010,27(4):90-92
课堂教学是实施教育的主要阵地,从某种意义上讲,课堂教学的公平性会直接影响着教育公平性及其实现程度。在中学阶段,课堂提问不公平的原因是多方面的,主要有学生课堂上的不配合、班级规模过大、升学任务繁重和中学课程评价体制不完善、个别老师的素质偏低等原因造成的。因此,为了实现课堂提问的公平性,必须提升教师的整体素质、和谐处理师生之间的关系、合理理解并改革现行的教学评价体制等。 相似文献
108.
S. E. Mangioni H. S. Wio 《The European Physical Journal B - Condensed Matter and Complex Systems》2008,61(1):67-73
We analyze the effect of a colored non Gaussian noise on a model of
a random walker moving along a ratchet potential. Such a model was
motivated by the transport properties of motor proteins, like
kinesin and myosin. Previous studies have been realized assuming
white noises. However, for real situations, in general we could
expect that those noises be correlated and non Gaussian. Among other
aspects, in addition to a maximum in the current as the noise
intensity is varied, we have also found another optimal value of the
current when departing from Gaussian behavior. We show the relevant
effects that arise when departing from Gaussian behavior,
particularly related to current's enhancement, and discuss its
relevance for both biological and technological situations. 相似文献
109.
F. Slanina 《The European Physical Journal B - Condensed Matter and Complex Systems》2008,61(2):225-240
Far-from-equilibrium models of interacting particles in one dimension
are used as a basis for modelling the stock-market
fluctuations. Particle types and their positions are interpreted as
buy and sel orders placed on a price axis in the order book. We
revisit some modifications of well-known models, starting with the
Bak-Paczuski-Shubik model. We look at the four decades old Stigler
model and investigate its variants. One of them is the simplified
version of the Genoa artificial market. The list of studied models is
completed by the models of Maslov and Daniels et al. Generically, in
all cases we
compare the return distribution, absolute return autocorrelation and
the value of the Hurst exponent. It turns out that none of the models
reproduces satisfactorily all the empirical data, but the most promising
candidates for further development are the Genoa artificial market and
the Maslov model with moderate order evaporation. 相似文献
110.
Josephson oscillation of a superfluid Fermi gas 总被引:1,自引:0,他引:1
S. K. Adhikari 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2008,47(3):413-419
Using the complete numerical solution of a time-dependent
three-dimensional mean-field model we
study the Josephson oscillation of a superfluid Fermi gas (SFG) at zero temperature formed in a combined axially-symmetric
harmonic plus one-dimensional periodic optical-lattice (OL) potentials after displacing the harmonic trap along the axial
OL
axis. We study the dependence of Josephson frequency on the strength of the OL potential. The Josephson frequency decreases
with increasing strength as found in the experiment of Cataliotti et al. [Science 293, 843 (2001)] for a Bose-Einstein condensate and of the experiment of Pezzè et al. [Phys. Rev. Lett. 93, 120401 (2004)] for an ideal Fermi gas. We demonstrate a
breakdown of Josephson oscillation in the SFG for a large displacement
of the harmonic trap. These features of Josephson oscillation of a SFG can be tested experimentally. 相似文献