Thermal properties of rare earth dodecaborides

We have measured heat capacity and thermal expansion of rare earth dodecaborides REB₁₂ (RE=Y, Tb-Tm, Lu). YB₁₂ and LuB₁₂ are diamagnetics whereas the other dodecaborides are ordered antiferromagnetically. The amplitude of the heat capacity discontinuity at the Néel temperature and the shape of the heat capacity variation in the critical region for all these antiferromagnetics are characteristics for amplitude-modulated magnetic structures. In the ordered state TbB₁₂ reveals two first-order phase transitions, most likely due to magnetic structure changes. The heat capacity of ErB₁₂ just below the Néel point shows an anomaly of unclear origin. From the Schottky contribution to the heat capacity we have determined crystal field parameters. They are completely different than that is estimated from Point Charge Model.     

Silica-supported Copper（Ⅱ） Catalyzed Coupling of Arylboronic Acids with Imidazoles

Immobilized copper（Ⅱ） in organic-inorganic hybrid materials catalyzed Ar-N coupling of arylboronic acids with imidazoles has been developed. Arylboronic acids reacted with imidazoles smoothly in the presence of a 3-（2-aminoethylamino）propyl functionalized silica gel immobilized copper（Ⅱ） catalyst （10 mol%） in methanol without any additives and bases. The reactions generated the corresponding cross-coupling products in good yields. Furthermore, silica-supported copper can be recovered and recycled by a simple filtration procedure and used for five consecutive trials without decreases in activity.     

共混合聚(醚-酯)多嵌段共聚物的表面表征及其血液相容性研究

本文通过X-射线光电子能谱(XPS)、表面接触角、表面ξ电位和血液相容性实验,研究了聚(醚-酯)多嵌段共聚物及其共混物的表面组成和性质与血液相容性的关系。实验结果表明,疏水性的PET-PTMO多嵌段共聚物的血液相容性很差,并且与表相中软段的富集量无关;当亲水性的PET-PEO多嵌段共聚物与疏水性的PET-PTMO多嵌段共聚物共混后,发现存在着一个最佳的共混比例,此时材料表面的血小板粘附量大大降低。对于共混物,表相△[C—O)/[C—O]和表面ξ电位可以较好地与血小板粘附量相关联。以上结果清楚地表明,材料表面的亲-疏水性平衡、软段深度层次分布及表面电位是影响血液相容性的重要因素。     

Supramolecular assemblies from single-chain hydrocarbon fluorocarbon hybrid bolaamphiphiles

Three types of single-chain hydrocarbon fluorocarbon hybrid bolaamphiphiles were synthesized.They readily formed different kinds of organized supramolecular assemblies,including vesicles,tapes,and micellar fibers,in aqueous solution.The aggregates morphology was characterized by transmission electron microscopy (TEM) after negative staining.The superstructures of these aggregates seemed to be determined by the geometry and the head group's properties of the corresponding amphiphiles.     

The discovery of polymer‐clay hybrids

The first successful example of a polymer‐clay hybrid was nylon‐clay hybrid (NCH), which is a nano‐meter‐sized composite of nylon‐6 and 1‐nm‐thick exfoliated aluminosilicate layers of the clay mineral. NCH was found and developed at Toyota Central Research and Development Laboratories over 17 years ago. The NCH containing a few weight percentages of clay exhibits superior properties such as high modulus, high strength, and good gas‐barrier properties. The key for the discovery of NCH was the polymerization of a nylon monomer in the interlayer space of the clay. This highlight presents the development of NCH from its discovery to its commercialization. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 819–824, 2004     

Composition and thermal stability of SiO2-based hybrid materials TEOS-MTEOS system

Hybrid materials with different amounts of organics permanently bound on the inorganic network obtained in the TEOS-MTEOS (tetraethoxysilan-methyltriethoxysilan) system are used for obtaining coatings with different optical and mechanical properties. To study the thermal stability of the mentioned materials, compositions with different molar ratios of the precursors were prepared. The influence of the solvent and water amounts on the gelation process was also investigated. The gels obtained were characterised by IR spectrometry and their decomposition temperatures were determined by DTA/TG. Thermal stability of the gels is rather influenced by their composition than the conditions of the gelation process. This revised version was published online in July 2006 with corrections to the Cover Date.     

Immobilization of copper in organic-inorganic hybrid materials: a highly efficient and reusable catalyst for the Ullmann diaryl etherification

The immobilization of copper in organic-inorganic hybrid materials catalyzing the Ullmann reaction has been described. Phenols reacted with aryl iodides, aryl bromides and aryl chlorides smoothly in the presence of a 3-(2-aminoethylamino)propyl functionalized silica gel immobilized copper catalyst. The protocol involved the use of DMSO as the solvent, and potassium fluoride as the base. The reactions generated the corresponding cross-coupling products in good to excellent yields. Furthermore, the silica-supported copper could be recovered and recycled by a simple filtration of the reaction solution and used for 10 consecutive trials without loss of its reactivity.     

微量元素锌在治疗Bell麻痹中的作用

为探讨急性早期应用补锌和综合疗法治疗Bell麻痹 ,将 1 5 8例Bell麻痹患者 ,随机分成两组 :(1 )补锌组 (补锌 +综合疗法 ) ;(2 )对照组 (单纯综合疗法 )。对其进行了观察对比治疗 ,同时检测了所有患者治疗前后自身对照发锌值 ,还对所有患者进行了定位诊断、面神经电反应测试、并对面肌功能进行评分。结果表明 ,对定位诊断其病变在D段、面肌功能评分在 1 1分以下、面神经无电反应患者 ,即使给予早期综合治疗 ,效果仍较差 ,而早期给予补锌加综合治疗效果优于对照组 ,其它段内患者治疗次数和治愈天数也均优于对照组。可见微量元素锌在发挥免疫应答、免疫调控中的重要作用     

覆冰地区分裂与扩径导线表面电场特性

输电线路覆冰对电力系统安全运行具有严重威胁,目前已经发展了多种防冰除冰方法,但每种方法都有其局限性,对于一些具有微气象、微地形特征的重覆冰地区尚未有较好的解决方法。文中考虑到扩径导线的特点和分裂导线输电线路的局限性,根据波阻抗和自然功率将分裂导线等效为单导线,并考虑电流的集肤效应,得到了等效的单根扩径导线,进而分析比较覆冰地区的分裂导线及其等效的单根扩径导线的表面电场特性。研究表明：等效前后导线截面面积相同且波阻抗一致时,扩径导线与分裂导线相比,不仅显著降低了子导线根数和输电线路的覆冰荷载,而且在扩径导线的半径等于分裂导线的等效单导线半径时,扩径导线的表面最大电场强度小于分裂导线。因此,在严重覆冰地区,采用分裂导线等效半径的扩径导线具有非常好的表面电场特性,且可显著降低冰风荷载,提高抗冰强度。     

基于预训练模型和多视角循环神经网络的电力文本匹配模型

针对传统方法未能考虑词向量的动态性及句子间交互不充分等问题,提出基于BERT预训练模型及多视角循环神经网络的文本匹配模型。通过BERT-whitening方法对BERT输出的句向量进行线性变换优化,并利用多视角循环神经网络将两句子不同位置的BERT动态词向量进行双向交互计算;将句向量与词粒度交互向量进行融合后计算结果。实验结果表明,提出的模型相较于对比模型有明显性能提升,实用性良好。