核心型钢混凝土柱抗震性能试验及数值模拟

在低周反复荷载作用下,对1个钢筋混凝土柱和8个核心型钢混凝土柱进行试验,研究核心型钢配钢率和轴压比对试件抗震性能的影响.研究结果表明,试件抗震性能随着核心型钢配钢率的增加得到显著改善.采用有限元软件ADINA对试件进行非线性有限元全过程分析,计算得到的试件骨架曲线、应力应变分布和裂缝发展情况与试验结果吻合良好.     

水溶性SalenMn(Ⅱ)的合成及其对氨基酸的分子识别研究

本文合成并表征了手性席夫碱配体(Salen H2)及其水溶性的锰配合物[Salen Mn(Ⅱ)].用紫外-可见光谱滴定技术测定了主体Salen Mn(Ⅱ)与客体氨基酸(苯丙氨酸和苏氨酸)对映异构体分子间进行识别作用的缔合常数.结果表明:SalenMn(Ⅱ)与系列客体氨基酸作用的配位比均为1∶2,主客体反应均为放热、熵减...     

基于电容层析法糖浆气液两相流识别

针对目前常规两相流流型识别方法在糖厂煮糖罐糖浆识别中精度低的缺点,提出基于电容层析法(ECT)的气液两相流流型判别软测量模型.首先对由ECT传感器采集的检测数据优化处理并提取特征参数作为BP神经网络的辅助变量,气液两相流相应实际流型作为BP网络的主导变量,通过神经网络结构参数的优化训练,构建出二级并行的自组织竞争神经网...     

基于物联网的产品质量监管系统

针对当前产品质量监管的现状,为了实现产品质量的动态监管,设计了一种基于物联网技术的产品质量监管系统。该系统综合运用射频识别技术、条码技术、GIS空间信息处理技术等,实现了对产品实施全程监管和质量追溯。     

利用Laplace小波和粒子群算法实现阻尼和频率精确计算

提出一种利用Laplace小波求自由衰减信号阻尼和频率的新方法.该方法利用Laplace小波实部的衰减特性来识别信号中的自由衰减波形,从而实现阻尼、频率的正确识别.同时为了提高识别效率,引入了粒子群算法来实现Laplace小波的参数寻优.仿真试验表明:这一方法具有较高的计算精度,且计算精度不受相邻模态耦合的影响.     

基于优化肌电特征的无声语音信号识别

提出了一种基于遗传算法(GA)和fisher投影的最佳可鉴别基的求解方法.将原始特征向量向着最佳可鉴别基投影可得到具有最佳可分性的新的特征向量.从颧肌和二腹肌前腹的皮肤表面检测无声发出6个汉语元音的表面肌电信号(SEMG),以该肌电信号的AR模型系数、倒谱系数和美尔倒谱系数作为原始特征向量.使用遗传算法找出了原始特征的次优组合,并组成新的特征向量.将GA找出的次优特征向量向着fisher最佳可鉴别基投影可得到最佳鉴别特征向量.最后用改进的BP神经网络作为分类器得到了较好的识别效果.     

Characterization of the molecular deformation behavior of glassy epoxy resins by rheo-optical FTIR spectroscopy

Rheo-optical FTIR spectroscopy was used for the first time to monitor molecular orientation phenomena in highly crosslinked epoxies. After studying the orientation behavior of epoxy/amine networks during uniaxial deformation above their glass transition temperature in a preceding article, this article deals with the rheo-optical characterization of the deformation process of those epoxy systems below T_g. The orientation behavior is influenced by the different molecular structure of the constituents and the free volume entrapped in the resins. Yield strain and tensile modulus are correlated with the slope of the orientation function. The orientation function was found to show an abrupt change of its slope in the yield point region. This phenomenon is discussed with respect to the mechanism of plastic deformation. © 1996 John Wiley & Sons, Inc.     

Dynamic mechanical behavior of a side-chain liquid crystalline polyacrylate

The phenomenology of the α- and β-relaxation processes in an amorphous and a crystallized specimen of a side-chain LC polyacrylate, based on the azobenzene mesogenic unit, was investigated by thermal and dynamic mechanical methods. The activation energy of the β relaxation of the crystallized sample is equal to that of the amorphous sample. The α-transition process of the amorphous sample was described by the WLF equation. In contrast, the α-relaxation behavior of the amorphous part of the semicrystalline sample was described by a double Arrhenius law broken at T = T_g. This peculiar behavior has been tentatively related to the decrease of the motion characteristic length of the macromolecules confined in the multidomain structure of the semicrystalline state. © 1996 John Wiley & Sons, Inc.     

Synthesis and properties of new poly(ether sulfone)amides

High molecular-weight aromatic polyamides were obtained from 1,5- and 2,6-bis-(4′-carboxy-4-phenylenoxy-sulfonyl)naphthalene by direct polycondensation reaction in N-methyl-2-pyrrolidone with various aromatic diamines, using triphenyl phosphite and pyridine as condensing agents. The polymers were characterized by elemental analysis, thermogravimetric analysis, differential scanning calorimetry, and infrared analysis. The polyamides, obtained in quantitative yield, possessed inherent viscosities in the range 0.42–1.70 dL/g, glass transition temperatures between 245–310°C, and 10% weight loss temperatures in nitrogen and air above 435 and 424°C, respectively. Most of the polymers were soluble in aprotic solvents. The effect of the structure on properties, such as solubility, T_g, and thermal behavior, were also studied. © 1996 John Wiley & Sons, Inc.     

Discotic Liquid Crystals of Transition Metal Complexes, 19: Discotic Mesomorphism and Double Clearing Behavior of Octakis(dialkoxyphenyl)phthalocyanine Derivatives

Eight novel octakis(3,4-dialkoxyphenyl)- phthalocyanine derivatives, Cn-M (2, M=2H; 3, M=Ni; 4, M=Cu; a, decyloxy; b, undecyloxy; c, dodecyloxy), have been synthesized and characterized. It was found that each of the derivatives exhibits discotic liquid crystalline properties, and that each of the Cn–Cu (4) derivatives has two kinds of D_rd2( P 2₁/ a ) mesophases. These Cn–Cu (4a,b,c) and C₁₂–2H (2c) derivatives exhibit a unique double clearing behavior.