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11.
稀土复合变质对新型铸造热锻模具钢组织与性能的影响 总被引:8,自引:1,他引:8
研究了稀土复合变质对新型铸造热锻模具钢(CHD钢)组织与性能的组织。结果表明,稀土复合变质能细化晶粒,并且随着稀土量的增加。细化效果明显;加入适量的稀土复合变质后,夹杂物数量明显减少,夹杂物趋于球化并均匀地分布在钢中,形态和分布得以了改善,向钢中加入稀土进行复合变质,能促进贝氏体、奥氏体和位错亚结构的形成,细化马氏体板条。当残留稀土含量为0.02%时,CHD钢的硬度、强度变化不大,断裂韧性(KIC)和疲劳裂纹扩展门槛值(△Kth)有所提高,冲击韧性、延伸率、断面收缩率提高了近一倍,抗热疲劳性能也最好。 相似文献
12.
13.
Frost R. L. Weier M. L. Erickson Kristy L. 《Journal of Thermal Analysis and Calorimetry》2004,76(3):1025-1033
Struvite (NH4MgPO4·6H2O) is a mineral often found in urinary tracts and kidneys. Thermal decomposition using slow low heating shows that the 'kidney'
stone can be decomposed at temperatures below 40°C. At this temperature both ammonia and water are evolved. If more rapid
heating is employed the decomposition occurs at around 80°C. The implication of this work rests with the use of low slow heat
for the decomposition of the kidney stones.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
14.
Atsunori Matsuda Tatsuo Matoda Yoshinori Kotani Toshihiro Kogure Masahiro Tatsumisago Tsutomu Minami 《Journal of Sol-Gel Science and Technology》2003,26(1-3):517-521
Anatase nanocrystals were precipitated mainly at the surface of the silica-titania gel films with hot water treatment, whereas the addition of poly(ethylene glycol) (PEG) in the films led to the dispersion of anatase nanocrystals in the whole of the films after the treatment. Both films with and without PEG showed high photocatalytic activities for acetaldehyde, NO
x
and stearic acid in the gas-solid system, and for methylene blue and potassium iodide in the liquid-solid system. The addition of PEG improved the photocatalytic activities of the resultant films due to the smaller anatase crystallites and the porous film structure. The residual silica under-layer of the superficially anatase-precipitated films is expected to act as a protective one for an organic polymer substrate against the photocatalytic degradation. 相似文献
15.
Pressurized hot water extraction (PHWE) using a laboratory made system was applied for the extraction of thermally labile and reasonably polar components such as berberine in coptidis rhizoma, glycyrrhizin in radix glycyrrhizae/liquorice and baicalein in scutellariae radix. PHWE was carried out dynamically at a flow of 1 ml/min, temperature between 95 and 140 °C, an applied pressure of 10-20 bar and extraction time of 40 min. Extraction by PHWE was found to give efficiencies comparable to Soxhlet extraction for baicalein in scutellariae radix and sonication for berberine in coptidis rhizoma, and glycyrrhizin in radix glycyrrhizae. Effects of ethanol added into the water used in PHWE were explored. Pressurized liquid extraction (PLE) with methanol as solvent was used for extraction of baicalein in scutellariae radix. The marker compounds present in the various medicinal plant extracts were determined by gradient elution HPLC. 相似文献
16.
Labeling experiments using several deuterated lipids were pursued to study the biosynthesis of macrocyclic isoprenoidal lipids of thermophilic methanogenic archaea, Methanothermobacter thermautotrophicus. The isopropylidene terminal of geranylgeranyl group of monomeric precursor appeared to be important for the CC bond formation at the hydrophobic end in the macrocyclic lipids. A mechanism involving a radical trigger at the allylic methyl group is proposed for this CC bond formation. 相似文献
17.
H. Moon S. W. Kim J. Lee S. K. Rhee E. S. Choi H. A. Kang I. H. Kim S. I. Hong 《Applied biochemistry and biotechnology》2003,111(2):65-79
As a novel feeding strategy for aptomizing human epidermal growth factor (hEGF) production with a recombinant Hansenula polymorpha DL-1 using the methanol oxidase (MOX) promoter in H. polymorpha DL-1, independent exponential feeding of two substrates was used. A simple kinetic model considering the cell growth on two
substrates was established and used to calculate the respective feeding rates of glycerol and methanol. In the fedbatch culture
with methanol-only feeding, the optimal set point of specific growth rate on methanol was found to be 0.10 h−1. When the fed-batch cultures were conducted by the independent feeding of glycerol and methanol, the actual specific growth
rate on glycerol and methanol was slightly lower than the set point of specific growth rate. By the uncoupled feeding of glycerol
and methanol the volumetric productivity of hEGF increased from 6.4 to 8.0 mg/(L·h), compared with methanol-only feeding. 相似文献
18.
甲烷氧化偶联Na2WO4-Mn/SiO2催化剂热效应的研究 总被引:1,自引:2,他引:1
采用固定床微型反应装置,研究了甲烷氧化偶联反应过程中Na2WO4-Mn/S iO2催化剂床层的热效应和催化性能的关系,考察了反应炉温、CH4/O2比和反应气体空速对催化剂床层热点分布的影响.研究结果表明,甲烷氧化偶联催化剂床层的热效应强烈依赖于反应条件.反应炉温越高,CH4/O2比越低,反应气体空速越大,催化剂床层的热点温度越高.结合催化性能和热效应关系的研究,为优化甲烷氧化偶联的反应操作提供了实验依据. 相似文献
19.
The Modified Barrier Functions (MBF) have elements of both Classical Lagrangians (CL) and Classical Barrier Functions (CBF). The MBF methods find an unconstrained minimizer of some smooth barrier function in primal space and then update the Lagrange multipliers, while the barrier parameter either remains fixed or can be updated at each step. The numerical realization of the MBF method leads to the Newton MBF method, where the primal minimizer is found by using Newton's method. This minimizer is then used to update the Lagrange multipliers. In this paper, we examine the Newton MBF method for the Quadratic Programming (QP) problem. It will be shown that under standard second-order optimality conditions, there is a ball around the primal solution and a cut cone in the dual space such that for a set of Lagrange multipliers in this cut cone, the method converges quadratically to the primal minimizer from any point in the aforementioned ball, and continues, to do so after each Lagrange multiplier update. The Lagrange multipliers remain within the cut cone and converge linearly to their optimal values. Any point in this ball will be called a hot start. Starting at such a hot start, at mostO(In In
-1) Newton steps are sufficient to perform the primal minimization which is necessary for the Lagrange multiplier update. Here, >0 is the desired accuracy. Because of the linear convergence of the Lagrange multipliers, this means that onlyO(In
-1)O(In In
-1) Newton steps are required to reach an -approximation to the solution from any hot start. In order to reach the hot start, one has to perform
Newton steps, wherem characterizes the size of the problem andC>0 is the condition number of the QP problem. This condition number will be characterized explicitly in terms of key parameters of the QP problem, which in turn depend on the input data and the size of the problem.Partially supported by NASA Grant NAG3-1397 and National Science Foundation Grant DMS-9403218. 相似文献
20.
系统地调查研究了16MnR钢在整个生产过程中钢中夹杂物的演变规律和清洁度水平,重点考察了钢锭中大型氧化物夹杂的类型,数量,分布,来源的形成,结果表明:钢锭中夹杂物主要是块状Al2O3,钢锭中大颗粒夹杂物主要来源于复合渣卷渣。 相似文献