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61.
Anna Doppler Leo D.M. Nicholls Christopher Golz Manuel Alcarazo Michael John 《Magnetic resonance in chemistry : MRC》2019,57(11):961-967
Two functionalized [6]carbohelicenes, one of which was also available in its two enantiomeric pure forms, were oriented in stretched polystyrene in CDCl3, and in a recently introduced chiral thermoresponsive lyotropic polyaspartate (poly(benzyl)0.5(phenethyl)0.5-L-aspartate) in C2D2Cl4. From the resulting 1H,13C residual dipolar couplings, the helical pitch of a methylated [6]carbohelicene was determined and found to be in agreement with theoretical predictions and existing crystal structures (d(C2,C2′) ≈ 4.3 Å). For a second [6]carbohelicene with para-methoxyphenyl substituents, a clear conformational preference of the substituents was observed. The orientational properties of the two helicene enantiomers in the chiral polyaspartate are very similar, but both drastically change around 306 K. We suggest this behavior is due to an unusual phase transition in the liquid crystal. 相似文献
62.
Dawei Xu Li Zheng Xinhong Cheng Gang Wang Qian Wang Wenbo Xin Peiyi Ye Lingyan Shen Yuehui Yu 《Physics letters. A》2019,383(25):3134-3137
The efficient passivation of in situ NH3-plasma pre-treatment and its regulation of the band alignment between HfO2 and 4H-SiC have been investigated by XPS. With in situ NH3-plasma passivation by PEALD, a VBO of 0.72 eV and a CBO of 1.54 eV can be obtained across the HfO2/4H-SiC interface. The Si-O bonds components reduction in the passivated interface layers will lead to band bending or band shift at the interface and regulate the band alignments between HfO2 and 4H-SiC. The physical mechanism investigation of band alignments can be a cornerstone for the application of HfO2/4H-SiC heterojunctions in the high-power devices. 相似文献
63.
64.
Marian Apostol Victor Barsan Constantin Nantea 《Molecular Crystals and Liquid Crystals》2013,570(1):453-456
Jordan's boson representation and cut-off repolarization for the one-dimensional two-fermion model (TFT) is used to get the equivalence of the model with the two-dimensional Coulomb gas and sine-Gordon model. The scaling equations for the coupling constants are thereby obtained up to the third order. 相似文献
65.
The liquid‐crystalline polymorphism of the homologous series of 4‐hexyloxybenzylidene‐4′‐alkyloxyanilines is investigated. Basing on the polarization microscopy (POM, TOA), the DSC calorimetry and miscibility studies the following mesophases were detected: nematic, smectic A, smectic C and smectic I. The phase diagrams of the compounds of these series with 4‐hexyloxybenylidene‐4′‐pentylaniline (as the standard of mesophases) show induction of the smectic F mesophases. Their dependence on the alkyl chain length and mole fraction is shown. 相似文献
66.
Junya Uchida 《Liquid crystals》2017,44(12-13):1816-1829
ABSTRACTDendritic molecules having several rigid-rod moieties can be applied to induce liquid crystallinity for a variety of non-mesomorphic functional molecules such as metal complexes, nanoparticles, fullerenes and π-conjugated molecules when these dendritic molecules are covalently bonded to those non-mesomorphic molecules. These complex molecules are called supermolecular liquid crystals. Due to the cooperation of several mesogenic moieties, these dendritic molecules exhibit very stable liquid-crystalline (LC) phases. We have used fork-shaped LC dendrons having two or three rigid-rod moieties to induce liquid crystallinity for functional molecules such as interlocked molecules and π-conjugated molecules. In these fork-like molecules, the rigid-rod cores are attached to the 3,4,5-position of the phenyl moieties through flexible spacer, and these molecules are bonded to functional molecules through the 1-position. They basically form smectic LC phases, which induce the layered arrangement of functional moieties. Here we report on a new family of fork-like mesogens containing a hydrogen bonding moiety or an ionic group. They are designed to build supramolecular materials. 相似文献
67.
Biological network alignment is an important research topic in the field of bioinformatics. Nowadays almost every existing alignment method is designed to solve the deterministic biological network alignment problem.However, it is worth noting that interactions in biological networks, like many other processes in the biological realm,are probabilistic events. Therefore, more accurate and better results can be obtained if biological networks are characterized by probabilistic graphs. This probabilistic information, however, increases difficulties in analyzing networks and only few methods can handle the probabilistic information. Therefore, in this paper, an improved Probabilistic Biological Network Alignment(PBNA) is proposed. Based on Iso Rank, PBNA is able to use the probabilistic information. Furthermore, PBNA takes advantages of Contributor and Probability Generating Function(PGF) to improve the accuracy of node similarity value and reduce the computational complexity of random variables in similarity matrix. Experimental results on dataset of the Protein-Protein Interaction(PPI) networks provided by Todor demonstrate that PBNA can produce some alignment results that ignored by the deterministic methods, and produce more biologically meaningful alignment results than Iso Rank does in most of the cases based on the Gene Ontology Consistency(GOC) measure. Compared with Prob method, which is designed exactly to solve the probabilistic alignment problem, PBNA can obtain more biologically meaningful mappings in less time. 相似文献
68.
Ernesta M. Meintjes Sandra W. Jacobson Christopher D. Molteno J. Christopher Gatenby Christopher Warton Christopher J. Cannistraci John C. Gore Joseph L. Jacobson 《Magnetic resonance imaging》2010
By contrast to the adult literature, in which a consistent parietofrontal network for number processing has been identified, the data from studies of number processing in children have been less consistent, probably due to differences in study design and control conditions. Number processing was examined using functional magnetic resonance imaging in 18 right-handed children (8–12 years) from the Cape Coloured community in Cape Town, South Africa, using Proximity Judgment and Exact Addition (EA) tasks. The findings were consistent with the hypothesis that, as in adults, the anterior horizontal intraparietal sulcus (HIPS) plays a major role in the representation and manipulation of quantity in children. The posterior medial frontal cortex, believed to be involved in performance monitoring in more complex arithmetic manipulations in adults, was extensively activated even for relatively simple symbolic number processing in the children. Other areas activated to a greater degree in the children included the left precentral sulcus, which may mediate number knowledge and, for EA, the head of the caudate nucleus, which is part of a fronto-subcortical circuit involved in the behavioral execution of sequences. Two regions that have been linked to number processing in adults — the angular gyrus and posterior superior parietal lobule — were not activated in the children. The data are consistent with the inference that although the functional specialization of the anterior HIPS may increase as symbolic number processing becomes increasingly automatic, this region and other elements of the parietofrontal network identified in adults are already reliably and robustly activated by middle childhood. 相似文献
69.
国产60—70年代的T611型卧式镗床大多因原结构性能和多年使用的原因,有必要进行精化改造。本文分析了T611型卧式镗床存在的一些弊端,并从数显改造等方面有针对性的介绍了一些精化改造的措施和方法,同时分析了改造后所具有的性能特点。 相似文献
70.
陈建平 《数学建模及其应用》2015,4(3):72-74
高通量测序技术的飞速发展让生物信息领域迎来了大数据时代。新技术在提供海量生物遗传信息的同时,也给分析这些数据带来了新的挑战。DNA序列比对是信息分析流程中的关键步骤,为后续的变异检测提供序列比对信息。2015“深圳杯”数学建模夏令营B题以DNA序列比对为研究课题,希望参赛学生给出序列快速比对的最佳方案。本文简要点评了各参赛队伍的解答情况,然后介绍了现有DNA序列比对软件中用到的算法和数据结构。 相似文献