Fiber-Optic Chemical Sensor for Detection of NO2 Using Poly (3-Octylthiophene)

A fiber-optic chemical sensor (FOCS) for detection of nitrogen dioxide (NO₂) molecules is reported. The FOCS presents an optropode structure because of the transmission properties of the sensitive material. The NO₂ FOCS is activated by using the semiconductor polymer: regioregular head-to-tail poly(3-octylthiophene-2,5-diyl). The operation wavelength of the sensor is 543.5 nm such that a simple LED and detector can be used for the design of this device. The sensor response decreases after each exposure, demonstrating the reduction in sensitivity as well as irreversibility lower than 5%. However, its properties such as rapid response, high selectivity, high sensitivity (0.43 ± 0.01 muW/ppm), hygroscopic properties, and its operation at room temperature make this kind of FOCS a good alternative for NO₂ toxic gas detection.     

Polymerization behaviors of racemic and chiral amphiphilic monomers in organized bilayer membranes of lamellar liquid crystalline phase

A racemic amphiphilic monomer, n‐dodecyl glyceryl itaconate (DGI), forms bilayer membranes in water in the presence of small amount of ionic cosurfactant and shows iridescent color. A chiral DGI, S‐DGI, also shows an iridescent property, but with a rather red shift in the color, which can be ascribed to the increased packing density of the monomer in the bilayer membranes. Chrial DGI has a more compact packing density than racemic one owing to closer distance between the monomer molecules; the conversion rate, however, is slower than that of racemic one when H₂O₂ is used as an initiator. When the initiator is changed to an amphiphilic one, 4‐(2‐hydroxyethoxy) phenyl‐(2‐hydroxy‐2‐propyl) ketone (Irgacure 2959), the chiral DGI shows even a little faster conversion rate than that of racemic one. The NMR chemical shift results of protons in benzene ring show that the molecules of Irgacure 2959 insert into the bilayer membranes. The molecular weights of the corresponding polymers prove that the initiation by H₂O₂ is restricted compared to that by Irgacure 2959. It is concluded that the decelerated polymerization behavior of chiral DGI initiated by H₂O₂ is a result of limited diffusion of the initiator into the lamellar bilayer structures. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 4891–4900, 2007     

新型纳米纤维膜对地下水中重金属的过滤去除研究

采用扫描电镜表征了氯化聚氯乙烯静电纺丝纳米纤维膜的微观结构特征,并进行了去除地下水中铜、铅、镉等重金属阳离子的过滤试验,包括直接过滤、加土壤过滤、加硅藻土过滤和胶束强化过滤。结果表明,最佳的过滤工艺是胶束强化过滤,其最佳试验条件是10层膜过滤和5mmol/L的SDBS浓度,对铜、铅、镉的去除率分别超过73%,82%和91%。     

具有可调紫外滤光性能的富勒烯胺/壳聚糖共混膜的研究

通过溶液共混及流涎成膜法制备了一系列不同C60乙醇胺含量的壳聚糖共混膜。以及含Cu（Ⅱ）的C60乙醇胺/壳聚糖共混膜。研究表明，C60乙醇胺/壳聚糖共混膜具有优异的可调紫外滤光性能，随着C60乙醇胺含量的增加，其紫外滤光波长从200nm红移至400nm左右。在该复合体系中引入Cu（Ⅱ）能有效改善膜的紫外光学性能，同时还初步探讨了这类复合材料的紫外滤光机制。     

全光纤脉冲压缩器的理论及实验研究

对色散位移光纤＋普通单模光纤构成的全光纤脉冲压缩器进行了理论分析，分析了压 缩效果与光纤参数及输入脉冲参数的关系；对不同中心波长和脉宽的主动锁模光纤激光器的 输出脉冲进行了压缩实验，均得到了近变换限Sech的压缩脉冲，实验结果与理论分析一致. 关键词： 全光纤脉冲压缩器 压缩因子 基座能量 主动谐波锁模光纤 激光器     

Preparation and Selectivity of Molecularly Imprinted Polymer Coating on the Micro Pore Membrane of Polytetrafluoroethylene

In order to obtain mechanically stable membrane for practical application, the imprinted polymer was synthesized in the pores of polyfluoromembrane, the binding and transport ability of the membrane were studied.     

Two-Frequency Brillouin Fiber Laser Based on Bragg Grating Fabry-Perot Cavity

A novel and simple two-frequency Brillouin fiber laser is presented. It is based on a fiber Fabry-Perot cavity with fiber Bragg gratings as reflectors. The model of stimulated Brillouin scattering in fiber grating-based Fabry-Perot resonator is investigated. The laser allows conversion efficiency of close to 100% and suppresses the higher-order Stokes waves. The theoretical prediction is presented and the experimental demonstration is realized.     

高能、超短脉冲、可调谐激光器用掺镱氟磷酸盐玻璃研究进展

Yb^3 与其它稀土离子相比有最简单的能级结构，这使它具有一些独特的性质，如避免激发态吸收，消除上转换和浓度猝灭等，因此它是高能输出激光器介质的理想掺杂离子。氟磷玻璃综合了氟化物玻璃和磷酸盐玻璃的优点，可降低磷酸盐的声子能量，改善其易吸湿性；提高氟化物玻璃的物理化学性能等，这使它成为稀土掺杂可调谐光纤激光器的很好的掺杂介质。众多研究表明，Yb^3 掺杂氟磷玻璃是一种很有前途的激光工作物质。本文总结了Yb^3 掺杂氟磷玻璃的特点，性质，结构及存在的问题。     

二次阳极氧化方法制备有序多孔氧化铝膜

通过二次阳极氧化方法制备多孔氧化铝膜与一次阳极氧化方法制备多孔氧化铝膜孔排布规律性的对比 ,结果发现 ,二次阳极氧化方法制取的多孔氧化铝膜孔排布规律性明显好于一次阳极氧化法制取的多孔膜 .在几个微米范围内 ,孔呈理想的六角排布 .去除一次阳极氧化膜后 ,二次阳极氧化得以在更良好的表面进行 ,制取的氧化铝膜孔规律性和有序度更高 .有序区域的尺寸与晶粒内的亚晶大小有一定关系     

光纤传感振动检测系统及其实验研究

实际工程结构中的振动检测是十分重要的，也是十分复杂的，常用的结构振动检测传感器易受工程现场恶劣环境的影响．而光纤传感器具有小巧、抗电磁干扰、灵敏度高、适合长期监测等优点。本文建立了基于马赫—曾德(Mech-Zehnder)干涉原理的光纤传感振动检测系统．研制了运用先进的数字信号处理技术采集和处理数据的专用软件，并在典型结构件——钢制悬臂梁结构上进行了外加信号作用下的强迫振动检测和冲击载荷作用下的自由衰减振动检测，测量了该结构件的频率及振幅，其结果与同时进行的成熟的电测结果相近，说明光纤传感器用于结构件的振动测量是可靠的。本文为光纤传感器应用于实际工程的振动检测提供了新的技术装置，具有工程应用前景。