基于均匀设计的海峡两岸高层建筑顺风向风荷载多因素分析

为明确海峡两岸高层建筑顺风向风荷载的异同,对两岸建筑风荷载标准进行了对标分析,并采用均匀设计方法进行了高层建筑顺风向风荷载多因素分析。研究表明:两岸风荷载标准中基本风速取样方法和极值分布参数取值方法存在明显区别,风压高度变化系数分布和不同重现期的设计风速转换系数大致相同,台湾标准给出的湍流强度建议值明显大于大陆标准;台湾标准分类计算建筑物主体和围护结构的设计风压,大陆标准采用统一表达式,两者给出的设计风荷载组合方式区别明显;以基底剪力和基底弯矩作为评价指标,H/(BL)(1/2)(高宽比)、α地面粗糙度指数)、C_g(脉动效应系数)、C_p(风荷载体型系数)和I_z(湍流强度),对高层建筑顺风向风荷载的影响程度依次减小,H/(BL)(1/2)和α为主要影响因素;随H/(BL)(1/2)的增大,C_g对顺风向风荷载的影响逐渐增强,当H/(BL)(1/2)增大到一定程度时,C_g成为主导因素。     

Equivalent nonlinear beam model for the 3-D analysis of shear-type buildings: Application to aeroelastic instability

Tower buildings can be very sensitive to dynamic actions and their dynamic analysis is usually carried out numerically through sophisticated finite element models. In this paper, an equivalent nonlinear one-dimensional shear–shear–torsional beam model immersed in a three-dimensional space is introduced to reproduce, in an approximate way, the dynamic behavior of tower buildings. It represents an extension of a linear beam model recently introduced by the authors, accounting for nonlinearities generated by the stretching of the columns. The constitutive law of the beam is identified from a discrete model of a 3D-frame, via a homogenization process, which accounts for the rotation of the floors around the tower axis. The macroscopic shear strain in the equivalent beam is produced by the bending of columns, accompanied by negligible rotation of the floors. A coupled nonlinear shear–torsional mechanical model is thus obtained. The coupling between shear and torsion is related to a non-symmetric layout of the columns, while mechanical nonlinearities are proportional to the slenderness of the columns. The model can be used for the analysis of the response of tower buildings to any kind of dynamic and static excitation. A first application is here presented to investigate the effect of mechanical and aerodynamic coupling on the critical galloping conditions and on the postcritical behavior of tower buildings, based on a quasi-steady model of aerodynamic forces.     

The First Catalytic Synthesis of an Acrylate from CO2 and an Alkene—A Rational Approach

For more than three decades the catalytic synthesis of acrylates from the cheap and abundantly available C₁ building block carbon dioxide and alkenes has been an unsolved problem in catalysis research, both in academia and industry. Herein, we describe a homogeneous catalyst based on nickel that permits the catalytic synthesis of the industrially highly relevant acrylate sodium acrylate from CO₂, ethylene, and a base, as demonstrated, at this stage, by a turnover number of greater than 10 with respect to the metal.     

论坚持社会主义先进文化前进方向

社会主义先进文化是马克思主义政党思想精神上的旗帜。中国共产党是中国特色社会主义事业的领导核心,是推进文化改革发展的根本保证。坚持社会主义先进文化前进方向,就是要加强党对文化事业的领导,以马克思主义指导文化工作发展,以文化阵地为壁垒引领文化方向,以提升全民族素质为文化建设着力点;就是要加强和改进党的自身文化建设,提升全党政治理论水平,完善党员思想道德情操,培育党内科学文化素养,积极探索党的自身文化建设与党建理论研究相结合的新路子。     

绿色建筑发展关键主体动态博弈——基于供给侧结构性改革视角

 中国绿色建筑市场正处于稳步发展阶段，但仍然存在供需结构不合理、各方利益关系协调不均衡等问题。基于供给侧结构性改革视角，分析了绿色建筑发展过程中“供应侧”和“需求侧”两端正外部经济性特征，构建了政府与供、需两端关键主体动态博弈模型，提出了基于政府、房地产开发商和消费者的对策建议。通过研究，表明绿色建筑发展前期阶段存在正外部经济效应和市场失灵共生现象，供、需两端并不能满足帕累托效率的平衡量要求，只通过市场自身资源配置功能调节绿色建筑市场结构和各主体利益关系存在局限性，政府的适度干预有利于实现供、需两端最优利益组合和利益均衡，有助于加快实现传统建筑市场转型升级。     

Thiadiazolo-Azaacenes

This work reports the synthesis and characterization of bis- and tetrakis(thiadiazolo)-appended di- and tetraazaacenes, displaying up to seven catenated benzene/pyrazine rings. The targets are obtained by condensation of benzo-bis(thiadiazole)-4,5-dione with aromatic di- and tetraamines. The condensation products—up to a heptacene-like species—are stable but can be insoluble. Soluble derivatives are readily processible, but do not show enhanced electron affinities, as the two or four attached benzothiadiazole units are effectively resonance-separated from the acene body, maximizing the number of Clar-sextets.     

建筑结构设计软件动力时程分析功能比较

利用SATWE、MIDAS/Building和ETABS软件分别对结构地震作用进行计算以获得其在地震作用下的反应,来判断结构整体的安全性和可靠性.对3种软件在前处理、分析过程中、后处理3方面进行对比,得出在前处理中MIDAS/Building在建模、选波和调波方面具有一定的优势,并且在后处理方面提供了丰富的后处理功能,便于操作人员快速查询结果.     

Crystal structures of functional building blocks derived from bis(benzo[b]thiophen‐2‐yl)methane

The syntheses of three bis(benzo[b]thiophen‐2‐yl)methane derivatives, namely bis(benzo[b]thiophen‐2‐yl)methanone, C₁₇H₁₀OS₂, (I), 1,1‐bis(benzo[b]thiophen‐2‐yl)‐3‐(trimethylsilyl)prop‐2‐yn‐1‐ol, C₂₂H₂₀OS₂Si, (II), and 1,1‐bis(benzo[b]thiophen‐2‐yl)prop‐2‐yn‐1‐ol, C₁₉H₁₂OS₂, (III), are described and their crystal structures discussed comparatively. The conformation of ketone (I) and the respective analogues are rather similar for most of the compounds compared. This is true for the interplanar angles, the C_aryl—C_bridge—C_aryl angles and the dihedral angles. The best resemblance is found for a bioisotere of (I), viz. 2,2′‐dinaphthyl ketone, (VII). By way of interest, the crystal packings also reveal similarities between (I) and (VII). In (I), the edge‐to‐face interactions seen between two napthyl residues in (VII) are substituted by S…π contacts between the benzo[b]thiophen‐2‐yl units in (I). In the structures of the bis(benzo[b]thiophen‐2‐yl)methanols, i.e. (II) and (III), the interplanar angles are also quite similar compared with analogues and related active pharmaceutical ingredients (APIs) containing the dithiophen‐2‐ylmethane scaffold, though the dihedral angles show a larger variability and produce unsymmetrical molecules.     

卷泥片雕塑：当代钧窑造型艺术的新高度

1990年代中后期,卷泥片成型技艺引进钧窑造型艺术。钧窑卷泥片陶艺造型从理念上讲,需要创作者对泥性的深刻理解与把握,需要基本认知泥片成型工艺要求,需要熟知卷泥片肌理及其应用;从创作艺术素养和思想上讲,需要创作者从传统文化资源里汲取养素,在日常生活中寻求创作灵感。卷泥片造型技法进入钧窑成型艺术无疑将给当代中国钧窑带来极大的艺术提升潜力和张力。     

浅谈建筑节能改造的防火问题

既有建筑节能改造是当前我国建筑节能工作的重点,但由于材料、施工、法规监管等多方面的原因,给我国建筑防火安全造成了许多重大隐患和事故。就如何在建筑节能改造中通过多种手段处理好防火安全问题进行了讨论,提出一些可供借鉴的方法。