精确模型下斜齿轮接触应力的有限元分析

探讨了基于Pro/Engineer的复杂模型的建模方法,介绍了建立斜齿轮精确模型的方法和步骤,将斜齿轮装配后导入已经嵌入到建模系统的有限元环境内,利用有限元软件对已经建立的斜齿轮模型施加约束、划分网格、建立接触对,对接触应力进行精确的计算,并把分析的结果与传统方法计算得到的数据对比,为以斜齿轮为零部件的产品设计提供了可靠的依据和精确的数据,为工程设计中发挥专业软件和计算机的优势提供了新的思路.     

聚[(S)-3-乙烯基-2,2'-二羟基-1,1'-联萘]的钛配合物催化三乙基铝对醛的不对称加成反应

通过维蒂希反应合成了(S)-3-乙烯基-2,2'-甲氧甲氧基-1,1'-联萘.将单体(S)-3-乙烯基-2,2'-甲氧甲氧基-1,1'-联萘用偶氮二异丁腈作引发剂进行自由基聚合得到了聚[(S)-3-乙烯基-2,2'-二甲氧基甲氧基-1,1'-联萘].该聚合物上的MOM保护基通过酸脱除获得手性螺旋聚合物聚[(S)-3-乙烯基-2,2'-二羟基-1,1'-联萘].将手性螺旋聚合物聚[(S)-3-乙烯基-2,2'-二羟基-1,1'-联萘]与Ti(O-i-Pr)4形成的配合物应用于三乙基铝与醛的不对称加成反应中,获得了较好的对映选择性,ee值最高为85%.更重要的是,这种聚合物还可以被回收利用多次且催化活性没有明显降低.     

Spectroscopic and theoretical studies of optically active porphyrin dimers: a system uninterpretable by exciton coupling theory.

The electronic excited states of a meso-meso beta-beta doubly linked bis-porphyrin are comprehensively investigated by measuring its circular dichroism (CD) and magnetic circular dichroism (MCD) spectra. The observed spectroscopic properties are rationalized by DFT calculations. The frontier molecular orbitals (MOs) are constructed by the linear combinations of the constituent monomers' four MOs. Comparison of a theoretical CD spectrum based on time-dependent DFT (TDDFT) with the experimental spectra resulted in the assignment of the helical conformation of the dimer. This assignment is contrary to the previous assignment based on the point-dipole approximation (exciton coupling theory).     

Dynamic behaviors of ferroelectric liquid crystal molecules under an applied electric field

The dynamic changes in ferroelectric liquid crystal (FLC) molecular alignments under an applied electric field are examined by observing the formation of conoscopic figures with a time resolution of 0.1 ms. Close agreements between observed and simulated conoscopic figures under low voltage (30 V) were obtained. Under high voltage (120 V), however, the observed conoscopic figures became blurred between 0.8 ms and 1.1 ms after reversal of the electric field. The light scattering producing the blurriness occurred due to the development of fast transient molecular alignments during the switching transition above the applied voltage 70 V.     

锥形模镦锻极限的研究

本文分析了锥形模镦锻变形的三个阶段,提出了二次稳定镦锻的概念,给出了金属变形过程中几个瞬态的数学模型。在此基础上,提出了不产生空间螺旋弯曲的原始坯料长径比ψ_(nkp),并绘出了ψ_(nkp)-φ临界曲线,进而得出了为设计模具用的三条限制曲线。通过试验分析,提出了在长径比很大时镦锻模膛设计的限制曲线,并在生产中取得了满意的效果。     

含沙水流中水轮机导叶的设计研究

依奇点分布法和前人分析实验得到的含沙水流中固体颗粒的受力分析结果,利用相对阻塞和相对抽吸的观点对含沙水流中水轮机导叶进行设计。经模型试验表明,与传统方法设计的导叶相比,用本文提出的方法设计的导叶在含沙水流中运行时,水力效率高,耐磨蚀。