Keggin结构钨钼磷混配杂多酸盐的合成和性质研究

用复分解法首次合成了５种Ｋｅｇｇｉｎ结构钨钼磷混配杂多酸盐ＭｘＰＷ４Ｍｏ８Ｏ４０．ｎＨ２Ｏ（Ｍ＝Ｅｔ４Ｎ,Ｂｕ４Ｎ,Ｋ,Ｂａ,Ｚｎ）,通过ＩＲ,ＵＶ,ＤＴ－ＴＧＡ,极谱及循环伏安对它们进行了表征。     

甘薯（Ipomoea batatas（L.）lam）不定根根尖细微结构的初步研究

顶端分生组织细胞有高的核质比,胸质中可见前质体和其它细胞,器。分化的组织原细胞中,皮层原细胞较中柱原和根冠表皮原细胞内前质体增多明显。     

NUMERICAL ANALYSIS OF HYDRODYNAMICS IN AIRLIFT LOOP REACTOR (IALR) ECOSYSTEM(I)——THE FIELDS OF FLOW,PRESSURE AND SHEAR STRESSES

气升内环流反应器是在生物工程中有较广泛应用、在环境工程中有重要应用前景的反应器．采用时间分裂法和有限元法对ＩＡＬＲ生态系统下降段的流体动力学Ｎ＿Ｓ方程进行求解,获得了发酵液为牛顿液体时,锥角θ＝｛７０°,７５°｝和Ｒｅ＝｛１００,２００｝情形下的二维速度场、压力场和剪切应力场．结果表明锥结构对ＩＡＬＲ的性能有重要影响．     

高层筒中筒结构的整体稳定简化分析

按照常规的方法,将筒中筒结构的外框筒连续化为具有弯曲变形和剪切变形,同时考虑其剪力滞后影响的等效实腹筒体．内筒只考虑其弯曲变形,内外筒的变形是协调的．然后用虚拟水平分布荷载来模拟由竖向荷载产生的Ｐ＿Δ效应,推导出结构的整体稳定微分方程,用Ｇａｌｅｒｋｉｎ法求解方程并获得整体结构的最小临界荷载．     

广义分布参数变结构系统的不变性条件

首次研究了广义分布参数系统的不变性条件,利用特征向量函数法将广义分布参数系统化为一广义系统,证明了它们的不变性条件是等价的,同时也指正了某些文献个别结论和证明．     

Spectrochemical Properties of Noncubical Transition Metal Complexes in Solutions. IX. The Mixed Tetragonal Distorted Bis(Salicylato)Cobalt(II) Complex in Various Solvents

Mixed cobalt(II) complexes with the monodentate ligands: 2-hydroxybenzoic acid deprotonated (sal^–, the salicylate ion) and water, have been investigated. The combined results of the spectrophotometric and conductance measurements, as well as known the X-ray structure for solids, were used to determine the structure of the studied complexes in solution. The electronic absorption spectra in aqueous acid (0.01M HClO₄), ethylene glycol (glycol), formamide (FM), N,N-dimethylformamide (DMF), and dimethyl sulfoxide (DMSO) solutions have been recorded. The d-d electronic spectra have been treated by the crystal-field model (CFM) and angular overlap model (AOM). Low-symmetry splittings of the broad asymmetric bands in the experimental spectra (solutions at room temperature) were found by Gaussian analysis. The effect of the and bonding of the monodentate ligands (with oxygen-donor ligators) on the central metal ion was described in the ligand–field framework. A comparison of the stereochemistry of the complex species in various solutions was made.     

桥梁初步设计专家系统

完成的系统包括上部结构形式和施工方法的选择、墩台类型选择及工程量估算,采用作者提出了双重加权多目标决策方法,对可行的方案进行优化,得出最佳方案,采用多层模糊识别方法对工程量进行估算,系统采用多路线推理、数据驱动和目标驱动相结合的推理策略,运用策略解释法解释推理结论,大量的汉语选择菜单为用户提供了友善的人机界面。     

Crystal and molecular structure of 6-0-acetylgrayanotoxin III

The crystal and molecular structure of a grayanotoxin III derivative, 6-0-acetylgrayanotoxin III is presented. The crystal is orthorhombic, space group P2₁2₁2₁, witha=15.582(3),b=21.304(3),c=6.339(3)Å,V=2104(1) ų Z=4. The structure was solved by direct methods and refined by full matrix least-squares methods to a finalR=0.047 for 1763 independent reflections withF ₀>3 (F ₀) The molecule is based on a tetracyclic structure consisting of two five-membered, one six-membered, and one seven-membered ring with various conformations.     

Synthesis and X-ray analysis of 1-((1S)-phenylethyl)-azetidine-(2R)-piperidinamide

The crystal and molecular structure of a new azetidine-2-carboxylic amide derivative is described. The structure was solved by direct methods and refined by least squares methods toR1=0.0393 for 4264 reflections (withI>2(I)) The structure consists of two independent molecules which are chemically the same with slight differences in geometry. Crystal data: C₁₇H₂₄N₂O, monoclinic, space groupP2₁,a=8.3782(4),b=20.0342(13),c=9.7769(8) Å, =109.687(6)°,V=1545.1(2)ų,Z=4.     

Estimation of Multinomial Probabilities under a Model Constraint

In this paper estimation of the probabilities of a multinomial distribution has been studied. The five estimators considered are: unrestricted estimator (UE), restricted estimator (RE) (under model ), preliminary test estimator (PTE) based on a test of the model , shrinkage estimator (SE) and the positive-rule shrinkage estimator (PRSE). Asymptotic distributions of these estimators are given under Pitman alternatives and the asymptotic risk under a quadratic loss has been evaluated. The relative performance of the five estimators is then studied with respect to their asymptotic distributional risks (ADR). It is seen that neither of the preliminary test and shrinkage estimators dominates the other, though each fares well relative to the other estimators. However, the positive rule estimator is recommended for use for dimension 3 or more while the PTE is recommended for dimension less than 3.