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951.
952.
Urlic L.E. Florusse L.J. Straver E.J.M. Degrange S. Peters C.J. 《Transport in Porous Media》2003,52(2):141-157
This contribution reports on the phase and interfacial tension behavior of some model high-temperature–high-pressure gas condensates. On the one hand these types of gas condensate are becoming a subject of major interest for the oil industry, while on the other their phase and interfacial tension behavior have not been very well studied. For two different model gas condensates, both composed of the three n-alkanes, methane, butane, and decane, experimental results on their fluid phase behavior have been obtained in the temperature region 270 < T (K) < 490 and up to pressures as high as 24 MPa. Also, critical points of the two mixtures have been determined experimentally. Both mixtures show an extended retrograde region. Using the Peng–Robinson equation of state, the phase behavior of the two mixtures was modeled. In addition, the interfacial tension behavior of the model gas condensates was modeled. For that purpose, the Cahn–Hilliard theory was applied in combination with the Peng–Robinson equation of state. Satisfactory results were obtained. 相似文献
953.
The quasi-parallel regime of a Darcy–Boussinesq boundary-layer flow over a permeable vertical flat plate adjacent to a fluid saturated porous medium is considered. Quasi-parallel means here a plane flow with a constant transversal velocity v=–v
0 directed perpendicularly towards the vertical surface, where a lateral suction with the same velocity –v
0 is applied. The plate is held at a constant temperature T
w which coincides with the ambient temperature T
of the fluid. The heat released by viscous dissipation induces a density gradient in the fluid. Thus, although T
w=T
, a thermal convection occurs. The steady regime of this self-sustaining buoyant flow has been examined in detail. Wall jet-like profiles with a continuous but finite spectrum of the momentum flow have been found. These self-sustaining buoyant jets show a universal behavior, that is, there exist certain length, velocity and temperature scales such that the flow characteristics become independent of the (constant) material properties of the fluid and the porous medium as well. 相似文献
954.
J.A.W. van Dommelen D.M. Parks W.A.M. Brekelmans 《Journal of the mechanics and physics of solids》2003,51(3):519-541
A micromechanically based constitutive model for the elasto-viscoplastic deformation and texture evolution of semi-crystalline polymers is developed. The model idealizes the microstructure to consist of an aggregate of two-phase layered composite inclusions. A new framework for the composite inclusion model is formulated to facilitate the use of finite deformation elasto-viscoplastic constitutive models for each constituent phase. The crystalline lamellae are modeled as anisotropic elastic with plastic flow occurring via crystallographic slip. The amorphous phase is modeled as isotropic elastic with plastic flow being a rate-dependent process with strain hardening resulting from molecular orientation. The volume-averaged deformation and stress within the inclusions are related to the macroscopic fields by a hybrid interaction model. The uniaxial compression of initially isotropic high density polyethylene (HDPE) is taken as a case study. The ability of the model to capture the elasto-plastic stress-strain behavior of HDPE during monotonic and cyclic loading, the evolution of anisotropy, and the effect of crystallinity on initial modulus, yield stress, post-yield behavior and unloading-reloading cycles are presented. 相似文献
955.
We obtain an asymptotic behavior of the loss probability for the GI/M/1/K queue as K for cases of <1, >1 and =1. 相似文献
956.
We consider the half‐linear boundary value problem where and the weight function q is assumed to change sign. We prove the existence of two sequences , of eigenvalues and derive asymptotic estimates for as . 相似文献
957.
958.
R. Leboda 《Chromatographia》1980,13(9):549-554
Summary The surface properties of complex adsorbents prepared through the pyrolysis of benzyl and n-heptyl alcohols and their mixtures
on the surface of silica gel were investigated. The reactions were carried out in an autoclave at 500°C. A series of adsorbents
having different porous structure, chemical nature of the adsorption centers and their topography were obtained. The best
resolution of different mixtures was obtained by the carbon-silica adsorbent prepared through the pyrolysis of n-heptanol. 相似文献
959.
Summary Synthesis of MBAMT (3-methyl-4-benzylideneamino-5-mercapto-1,2,4-triazole) and its IR and NMR spectral data are reported. The high stability of the characteristically coloured chelates with Cu(II), Co(II), Ni(II), Pd(II), Pt(IV) and Rh(III) has been made the basis for their efficient ascending TLC separations on silica gel G layers, when present together. Results of four different solvent systems are included to assess efficient resolution of the chelates along with their limits of identification and separation. TLC separations, followed by the ring colorimetric determination of the six metal ions (as ternary mixtures) are tabulated.MBAMT=3-methyl-4-benzylideneamino-5-mercapto-1,2,4-triazole. 相似文献
960.
甲基对硫磷的快速测定及电化学性质 总被引:1,自引:2,他引:1
研究了杀虫剂甲基对硫磷的电化学性质。在pH10.38的Bdtton—Robinson缓冲溶液中,采用微分脉冲溶出伏安法在悬汞电极上得到一个还原峰,峰电位为-0.5V(vs.Ag/AgCl),本工作对实验条件进行了深入的研究,结合线性扫描伏安法等手段。研究了体系的电化学行为。实验表明,甲基对硫磷在汞电极上具有吸附性,电极反应具有不可逆性。该法用于水果及水样中甲基对硫磷残余量的测定,结果满意。 相似文献