全文获取类型
收费全文 | 12636篇 |
免费 | 816篇 |
国内免费 | 1834篇 |
专业分类
化学 | 6564篇 |
晶体学 | 115篇 |
力学 | 1082篇 |
综合类 | 95篇 |
数学 | 1568篇 |
物理学 | 1525篇 |
综合类 | 4337篇 |
出版年
2024年 | 39篇 |
2023年 | 125篇 |
2022年 | 211篇 |
2021年 | 261篇 |
2020年 | 339篇 |
2019年 | 309篇 |
2018年 | 296篇 |
2017年 | 360篇 |
2016年 | 451篇 |
2015年 | 414篇 |
2014年 | 566篇 |
2013年 | 939篇 |
2012年 | 714篇 |
2011年 | 775篇 |
2010年 | 620篇 |
2009年 | 849篇 |
2008年 | 792篇 |
2007年 | 895篇 |
2006年 | 737篇 |
2005年 | 795篇 |
2004年 | 721篇 |
2003年 | 590篇 |
2002年 | 535篇 |
2001年 | 458篇 |
2000年 | 365篇 |
1999年 | 335篇 |
1998年 | 283篇 |
1997年 | 226篇 |
1996年 | 183篇 |
1995年 | 183篇 |
1994年 | 168篇 |
1993年 | 145篇 |
1992年 | 104篇 |
1991年 | 83篇 |
1990年 | 86篇 |
1989年 | 60篇 |
1988年 | 51篇 |
1987年 | 46篇 |
1986年 | 30篇 |
1985年 | 25篇 |
1984年 | 24篇 |
1983年 | 11篇 |
1982年 | 27篇 |
1981年 | 10篇 |
1980年 | 14篇 |
1979年 | 13篇 |
1978年 | 7篇 |
1977年 | 4篇 |
1976年 | 4篇 |
1973年 | 4篇 |
排序方式: 共有10000条查询结果,搜索用时 125 毫秒
51.
Whereas glucose oxidase and related proteins are encapsulated readily in silica sol–gels, α-hydroxy enzymes such as lactate
oxidase (LOx), are reported to be damaged by electrostatic interaction with these matrices. Based on a previous report, poly(ethyleneimine),
PEI, was evaluated as a protecting compound under conditions suited to analytical measurements. With LOx and PEI co-encapsulated
in a silica sol–gel, the enzyme retained 62% of its initial activity after 20 days. In the absence of PEI, activity was lost
during the processing. Batch analytical measurements with enzyme-doped sol–gel yielded a linear response over the range 0.5–2.0 mM
lactate and a detection limit of 0.03 mM lactate. Both simple incorporation of LOx in a silica sol–gel and an alternative
protection method, blocking the ion-exchange sites on silica with La(III), failed. These negative results supported the hypothesis
that the efficacy of PEI was related to its formation of a protective sheath around the enzyme.
Author for correspondence. E-mail: coxja@muohio.edu
Received July 29, 2002; accepted December 15, 2002
Published online May 19, 2003 相似文献
52.
53.
54.
T. Beda 《Journal of Polymer Science.Polymer Physics》2007,45(13):1713-1732
A constitutive phenomenological model completing the Gent‐Thomas concept is carried out to formulate laws governing the hyperelastic behavior of incompressible rubber materials. It is shown that the phenomenological Gent‐Thomas model (1958) and the constrained chain model (1992) give similar precise results at small to moderate deformation. On the other hand, comparisons of the outcome of the proposed model with that of the molecular model from the combined concepts of Flory‐Erman and Boyce‐Arruda (2000), and with those of the phenomenological models of Ogden (1982), Yeoh‐Fleming (1997), Pucci‐Saccomandi (2002) and Beda (2005) are made. Residual inconveniences raised by attractive continuum models in rubber elasticity literature have been successfully overcome. Results from both the statistical and phenomenological mechanics concepts are compared with the data of some useful classical materials (rubbers of Treloar, Rivlin‐Saunders, Pak‐Flory and Yeoh‐Fleming). The results permit one to see salient equivalence of the two theories for a more reliable prediction of stress‐stretch response for all states of any mode of deformation. A complete and exhaustive analysis of the Mooney plot that combines small and very large extension‐compression has been quite essential in assessing the validity of models. A method of identification of material parameters is presented and data of the simple tension suffice for the determination of the parameter values. It is shown that the ordinary identification procedures, such as the usual least squares, a very much used numerical method in materials investigation, can be unsuitable in some cases of hyperelastic modeling. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 1713–1732, 2007 相似文献
55.
陶榕 《厦门理工学院学报》2002,10(3):20-23
秘书人员的行为美表现为工作主体的朴实性、规范性、和谐性、创造性 ,其中创造性是秘书行为美的最高层次 ,是秘书工作本质力量的体现 相似文献
56.
Eiji Yanagida 《Journal of Dynamics and Differential Equations》2007,19(4):895-914
This paper is concerned with the irregular behavior of solutions for Fisher’s equation when initial data do not decay in a
regular way at the spatial infinity. In the one-dimensional case, we show the existence of a solution whose profile and average
speed are not convergent. In the higher-dimensional case, we show the existence of expanding fronts with arbitrarily prescribed
profiles. We also show the existence of irregularly expanding fronts whose profile varies in time. Proofs are based on some
estimate of the difference of two distinct solutions and a comparison technique.
Dedicated to Professor Pavol Brunovsky on his 70th birthday. 相似文献
57.
Hydrogels of N‐vinylimidazole (VI) and sodium styrenesulfonate (SSS) were synthesized in aqueous solution by radical crosslinking copolymerization with N,N′‐methylene‐bis(acrylamide) as crosslinker. Swelling in several saline solutions was measured for hydrogel samples synthesized with different comonomer concentrations (CT = 10, 25, or 40%) and with SSS mole fractions covering a broad range (fSSS = 0–0.7), while the crosslinker ratio was 2 wt % in all cases. The degree of swelling in aqueous solution with a specific ionic strength (μ), plotted versus the SSS composition of the feed, shows a minimum for any set of samples synthesized with a fixed CT. The dependence of swelling on μ shows both polyelectrolyte (fSSS beyond the minimum) and antipolyelectrolyte behaviors (in the low fSSS limit). It was found that the nonGaussian factor of the crosslinking density and the polymer‐solvent interaction parameter increase with fSSS for any CT. Moreover, in the low fSSS limit, the osmotic swelling pressure is governed not only by the ionic contribution, but also by the polymer‐solvent mixing and, the concentration of mobile counterions inside the gel is not proportional to the net fixed charge but to the addition of cationic and anionic side groups, what discards the formation of ionic pairs. The antipolyelectrolyte effect is interpreted as due to the increasing protonation of VI as μ goes up. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 1683–1693, 2007 相似文献
58.
J. Feuer 《Journal of Mathematical Analysis and Applications》2007,332(1):564-569
In this paper, we will study two classes of difference equations which are piecewise-linear and of similar forms. We will show that all nontrivial solutions of one equation are eventually periodic with prime period three. We will show this result for one case of the second equation. 相似文献
59.
开放式基金投资者赎回行为的模拟 总被引:6,自引:0,他引:6
应用停止理论(shopping theory)的概念和方法模拟开放式基金投资的赎回行为发现,投资者的赎回行为可用停时(stopping time)来描述,并给出了完全随机型赎回行为的概率分布和其收益现值和期望。 相似文献
60.