气相爆轰波平衡胞格稳定性实验研究

本文详细介绍了研究气体爆轰的烟迹法以及采用所提出的方法得到的爆轰波通过柔性材料壁面前后平衡胞格形成、消失和重新恢复的全过程烟迹照片。实验按初压不同分五组进行。从烟迹照片中各时期的胞格尺寸、横波的变化出发,对上述过程中横波强度变化情况及柔性壁面对横波的作用和影响进行了分析,对平衡胞格恢复的条件进行了讨论。     

气相爆轰波临界直径的实验研究

作者分别用圆形和方形爆轰管,通过改变惰性气体的比例和圆锥管道的锥角,对H2-O2和C2H2-O2系统进行了爆轰临界直径的实验研究,得到了不同稀释浓度下方管中爆轰波熄灭的临界直径,验证了Mitrofanov.V.V.和Soloukhin,R.I.以前得到的结果（dc/=10）,也得到了圆锥管道中不同锥角对临界直径的影响（dc/-）,并用流管理论对实验结果作了初步的分析。     

Size dependence of gaseous cluster reactivity as a mechanistic probe

The determination of the mechanisms of chemical and physical changes is one of the principal occupations of many chemists today. To accomplish this, the dependence of the change being examined on a number of intensive variables such as temperature, pressure, concentration of reactants as well as the pH is usually studied. In this account, we summarize our recent studies on the reactivity and dynamics of niobium gaseous clusters in which their changes with size are used as a new degree of freedom that assists in deducing the mechanism of the change studied.     

Thermal cracking of n-octodecane and its geochemical significance

The mechanism of carbon isotopic fractionation for gaseous hydrocarbons is revealed by investigating the residual liquid hydrocarbons in laboratory pyrolysates of n-octodecane. The results indicate that cracking and polymerization in the relatively low temperatures and dispropor-tionation reactions leading to light hydrocarbons and pol-yaromatic hydrocarbons at high temperatures are probably causes for the carbon isotope reversal of gaseous hydrocarbons that is commonly observed in pyrolysis experiments. This study provides significant insight for quantitative modeling of natural gas δ13C values and aid in the identification and assessment of natural gases derived from oil cracking.     

A biochemical sniffer-chip for convenient analysis of gaseous formaldehyde from timber materials

A biochemical gas-sensor (sniffer-chip) with formaldehyde dehydrogenase (FALDH) was developed for convenient analysis of gaseous formaldehyde with high gas-selectivity. The sniffer-chip for formaldehyde in the gas phase was constructed by immobilizing FALDH to a Pt-electrode coated hydrophilic PTFE membrane. The oxidation current of NADH produced by the enzymatic reactions was measured by amperometric analysis. The calibration range of the sniffer-chip for formaldehyde in the gas phase was from 40 to 2000 ppb, which encountered the maximum permissible concentration of formaldehyde vapor in the residential house (80 ppb) and formaldehyde detection limit for the human sense of smell (410 ppb). As the resident-environmental application, the sniffer-chip was possible to measure the formaldehyde concentration from some timber materials (3 kinds of interior timber and 2 kinds of exterior formwork timber) within 3 min. The calculated concentration value by a regression analysis was consistent with those of a commercially available gas sensor and a gas detector tube for formaldehyde. The FALDH sniffer-tip would be effective and convenient approach to detect and measure gaseous formaldehyde with high gas-selectivity at the residential atmosphere. Correspondence: Kohji Mitsubayashi, Department of Biomedical Devices and Instrumentation, Institute of Biomaterials and Bioengineering, Tokyo Medical and Dental University, 2-3-10 Kanda-Surugadai, Chiyoda-ku, Tokyo 101-0062, Japan     

基于草图理解的数字黑板系统

针对电子教学系统人机交互的自然性和用户适应性不足的问题,研究设计了基于草图的人机交互技术的新型电子教学系统,提出了基于用户信息的草图识别方法.实验表明该方法具有很好的效果.     

储氢合金抗气体杂质毒化的研究进展

本文综述了氢气中的不同杂质气体对储氢合金吸放氢性能的影响。主要评价了LaNi4.7Al0.3、LaNi5、Fe-Ti、ZrCr2-xFex、Ti(Fe,Mn)等合金及它们的氢化物被CO、CO2、H2S等气体毒化的情况,并通过分析目前提升储氢合金抗毒化能力的主要方法及其使用效果,总结了合金抗毒化研究进展,为今后的发展提出了一些新思路。     

Formation of the bisulfite anion (HSO3–, m/z 81) upon collision‐induced dissociation of anions derived from organic sulfonic acids

In the negative‐ion collision‐induced dissociation mass spectra of most organic sulfonates, the base peak is observed at m/z 80 for the sulfur trioxide radical anion (SO₃^–·). In contrast, the product‐ion spectra of a few sulfonates, such as cysteic acid, aminomethanesulfonate, and 2‐phenylethanesulfonate, show the base peak at m/z 81 for the bisulfite anion (HSO₃^–). An investigation with an extensive variety of sulfonates revealed that the presence of a hydrogen atom at the β‐position relative to the sulfur atom is a prerequisite for the formation of the bisulfite anion. The formation of HSO₃^– is highly favored when the atom at the β‐position is nitrogen, or the leaving neutral species is a highly conjugated molecule such as styrene or acrylic acid. Deuterium‐exchange experiments with aminomethanesulfonate demonstrated that the hydrogen for HSO₃^– formation is transferred from the β‐position. The presence of a peak at m/z 80 in the spectrum of 2‐sulfoacetic acid, in contrast to a peak at m/z 81 in that of 3‐sulfopropanoic acid, corroborated the proposed hydrogen transfer mechanism. For diacidic compounds, such as 4‐sulfobutanoic acid and cysteic acid, the m/z 81 ion can be formed by an alternative mechanism, in which the negative charge of the carboxylate moiety attacks the α‐carbon relative to the sulfur atom. Experiments conducted with deuterium‐exchanged and deuterium‐labeled analogs of sulfocarboxylic acids demonstrated that the formation of the bisulfite anion resulted either from a hydrogen transfer from the β‐carbon, or from a direct attack by the carboxylate moiety on the α‐carbon. Copyright © 2012 John Wiley & Sons, Ltd.     

Beyond the Monchick–Mason approximation: the mobility of Li+ Ions in H2

The Monchick–Mason approximation for the calculation of the transport coefficients of atomic ions in diatomic gases is extended in a manner that allows comparison of theoretical and experimental mobilities of gaseous ions to serve as quantitative tests of the accuracy of the ab initio, angle- and position-dependent interaction potentials used in the calculations. The feasibility of this procedure is demonstrated with Li⁺ in H₂.     

气体非稳定爆轰波在具有声学吸收壁的直角三通弯管中传播特性研究

本文实验研究了丙烷、氧气和空气的预混气体非稳定爆轰波在具有声学吸收壁的直角三通弯管中传播特性，分析了声学吸收材料厚度对非稳定爆轰波传播特性的影响．实验结果表明，在直角三通弯管中安装声学吸收材料对气体非稳定爆轰波有明显的衰减作用，在弯管前后非稳定爆轰波的传播速度和压力都有很大程度的减小．而且随着声学吸收材料厚度的增加，气体非稳定爆轰波强度衰减幅度增大．这一实验结论对工业安全具有重要的参考价值．