理想气体吸热和放热的讨论

根据热力学第一定律和理想气体状态方程推导了理想气体的热容量公式,并对理想气体在p-V图上的直线过程和循环过程的温度变化及吸热和放热进行了讨论.     

气体放电等离子体特性测量I-V曲线不对称性的研究

利用气体放电双探针法研究了等离子体的I-V曲线中的电流I相对于电压V轴交点的不对称性,并提出2种可能的解释:一认为是由于两探针表面积不同引起的;二认为是由于探针所在处等离子体电位不等引起的.本文利用仪器的工艺误差和调换放电管电压的方法,对提出的2种可能原因分别进行验证,并指出第二种解释的合理性,并对其进行了理论分析.     

Atomistic packing models for experimentally investigated swelling states induced by CO2 in glassy polysulfone and poly(ether sulfone)

Atomistic packing models have been created, which help to better understand the experimentally observed swelling behavior of glassy polysulfone and poly (ether sulfone), under CO₂ gas pressures up to 50 bar at 308 K. The experimental characterization includes the measurement of the time‐dependent volume dilation of the polymer samples after a pressure step and the determination of the corresponding gas concentrations by gravimetric gas‐sorption measurements. The models obtained by force‐field‐based molecular mechanics and molecular dynamics methods allow a detailed atomistic analysis of representative swelling states of polymer/gas systems, with respect to the dilation of the matrix. Also, changes of free volume distribution and backbone mobility are accessible. The behavior of gas molecules in unswollen and swollen polymer matrices is characterized in terms of sorption, diffusion, and plasticization. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 1874–1897, 2006     

双电极对双脉冲激光器结构分析

本文对双电极对双脉冲激光器的谐振腔结构进行了分析,结果表明采用双非稳腔和增大反射镜的曲率半径可分别获得单纵模和基横模输出。为使输出能量稳定,则双电极对的间距有一最小值的限制。     

低温二维电子气体的比热容

运用闭路格林函数方法，得到了二维电子气体热力学势的表达式，同时还得到了新的交换项，这个交换项可以化为已知的由虚时方法得到的表达式，但在低温下它没有奇异性，这表明，虽然闭路格林函数方法和虚时方法在总体上是等价的，但在一些技术细节上前者优于后者，此外，从导出的热力学势出发计算了二维电子气体在低温下的比热容。     

Analysis of Pyrolysates for Phenol Formaldehyde Resin by Py-GC/MS

Pyrolysis of phenol formaldehyde resin has been investigated by Pyrolysis Gas Chromatography-Mass Spectroscopy at the different temperatures from 500℃ to 750℃. Its composition of pyrclysates has been analyzed. Several compounds, especially benzene, toluene, p-xylene could only be formed above 500-550℃. Howerver, peak intensities for some pbend derivatives were decreased at the higher temperature. During pyrolysis, for thermo-setting phenol formaldehyde resins, polymeric chain scissions take place as a successive removal of the monomer units from the polymeric chain. The chain scissions are followed by secondary reactions, which leads to a variety of compounds. Addition reactions can also take place among the double-bond compounds during pyrolysis.     

沉积盆地侵入岩区的异常“温度场、压力场和地球化学场”与油气的关系——以东营凹陷纯西辉长岩为例

通过岩石学、有机地球化学等分析 ,发现纯西辉长岩周围烃源岩具有有机质含量极低、高熟和裂缝发育以及油气比较丰富等特征 .研究表明 ,其根源是辉长岩形成的特殊温度场、压力场和地球化学场 ;辉长岩形成的异常高温大大促进了烃源岩热演化 ,并提高了生烃量 ;高压产生的大量裂缝为烃源岩排烃和油气聚集提供了通道和储集空间 ;而辉长岩带来的深源氢对烃源岩起到加氢作用 ,扩大了生烃量     

Vortices in Bose-Einstein condensates: A review of the experimental results

Rotating dilute Bose-Einstein condensates (BEC) of alkali atoms offer a testing ground for theories of vortices in weakly interacting superfluids. In a rotating super-fluid, quantised vortices, with a vorticity h/m, form above a critical velocity. Such vortices have been generated in BEC of alkali atoms by different techniques such as (a) wave function engineering of a two-component BEC, (b) decay of solitons, (c) rotation of a thermal cloud before cooling it below the condensation temperature, (d) stirring with an ‘optical’ spoon, (e) rotating a deformation in the anisotropic trap in which the condensate is trapped and (f) by creating Berry phase by adiabatically reversing the axial magnetic field. Since the core of a vortex is a fraction of a micrometer in diameter, it cannot be directly imaged optically. The condensate with vortices is allowed to ballistically expand till the size increases by one order before the vortices are imaged. Surface wave spectroscopy and the change in aspect ratio of a rotating cloud are the other techniques used. Studies have been made on the creation and dynamics of single vortex and on systems with more than a hundred vortices. Results have been obtained on vortex nucleation, stability of vortex structures, nature of the vortex lattice and defects in such a lattice. Important results are: (a) evidence exists that vortex nucleation takes place by a surface mode instability; but this is not the only mechanism; (b) the vortex lattice is perfectly triangular right up to the edge; (c) in the initial stages of rotation of the cloud a tangled web of vortices is seen; it takes a few hundred milliseconds before the vortices arrange themselves in a lattice; this time appears to be independent of temperature; (d) the decay of vortices appears to arise from the transfer of energy to the rotating thermal component and is dependent on temperature; (e) defects in the lattices such as dislocations and grain boundaries are seen; (f) transverse oscillations (Tkachenko modes) of the vortex lattice have been observed; and (g) giant vortices have been produced. These will be discussed.     

Flaked capillary columns with crown ether complexes for gas-liquid chromatography

Flaked capillary columns with an OV-101/CE-Na{in3}PO{in4} hydrophobic-hydrophilic sorbent have been suggested. This sorbent provides for the analysis of polar and nonpolar substances, including amines and aminoalcohols, in aqueous and organic solvents. The efficiency of new columns was demonstrated for the analysis of 25 organic substances of various classes.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2169–2173, December, 1994.The work was financially supported by the Russian Foundation for Basic Research, Project No. 93-03-4969.     

Enantioselective separations by capillary GC on derivatized cyclodextrins. Part 2: Determination of enantiomeric excess of some racemic 2,3-isopropylidene-1,2,3-cyclohexanetriol derivatives on permethyl α-, β-, and γ-cyclodextrins

Capillary GC on permethyl α-, β-, and γ-cyclodextrins has been applied to separate and quantify the enantiomers of some 2,3-iso-propylidene-1,2,3-cyclohexanetriol derivatives. Quantitative CGC data are compared to those obtained with chiral shift ¹H NMR.