Targeted Construction of Amorphous MoSx with an Inherent Chain Molecular Structure for Improved Pseudocapacitive Lithium-Ion Response

Owing to low ion/electron conductivity and large volume change, transitional metal dichalcogenides (TMDs) suffer from inferior cycle stability and rate capability when used as the anode of lithium-ion batteries (LIBs). To overcome these disadvantages, amorphous molybdenum sulfide (MoS_x) nanospheres were prepared and coated with an ultrathin carbon layer through a simple one-pot reaction. Combining X-ray photoelectron spectroscopy (XPS) with theoretical calculations, MoS_x was confirmed as having a special chain molecular structure with two forms of S bonding (S²⁻ and S₂²⁻), the optimal adsorption sites of Li⁺ were located at S₂²⁻. As a result, the MoS_x electrode exhibits superior cycle and rate capacities compared with crystalline 2H-MoS₂ (e.g., delivering a high capacity of 612.4 mAh g⁻¹ after 500 cycles at 1 A g⁻¹). This is mainly attributed to more exposed active S₂²⁻ sites for Li storage, more Li⁺ transfer pathways for improved ion conductivity, and suppressed electrode structure pulverization of MoS_x derived from the inherent chain-like molecular structure. Quantitative charge storage analysis further demonstrates the improved pseudocapacitive contribution of amorphous MoS_x induced by fast reaction kinetics. Moreover, the morphology contrast after cycling demonstrates the dispersion of active materials is more uniform for MoS_x than 2H-MoS₂, suggesting the MoS_x can well accommodate the volume stress of the electrode during discharging. Through regulating the molecular structure, this work provides an effective targeted strategy to overcome the intrinsic issues of TMDs for high-performance LIBs.     

HPLC–PDA identification and resolution of rufinamide forced degradation impurities: A congregated chemometric expedite optimization coupled with factorials and desirability

Rufinamide is used presently to treat Lenaux–Gastaut syndrome. A full factorial design and desirability approach was investigated for the optimization of hydrolytic stress via response surface curves (RSCs). The degradation impurities were identified and resolved using reversed-phase high-performance liquid chromatography (RP-HPLC) on the Qualisil® BDS C₈ column. Acetonitrile–water (29:71, v/v) was optimized for the mobile phase and used at a flow rate of 1.0 ml/min with detection at a wavelength of 230 nm. Rufinamide showed appreciable susceptibility to hydrolysis under acidic and alkaline stress, and substantial degradation in the neutral condition. It degraded much less under oxidative stress. Exposure towards thermal and photolytic stress conditions indicated appreciable stability. The developed method was subjected to validation as per the recommendations of the International Conference on Harmonization. The proposed method showed no influence from the excipients and the degradation products. As well as good precision and accuracy in determination, the method showed a linear response between 2 and 12 μg ml⁻¹. The method was extended for determination in a human plasma sample, which resulted in excellent recovery without interference from matrix effects. The combined use of desirability and design for the optimization of acidic and alkaline hydrolytic stress led to simple and rapid analysis.     

文科生大学数学学习情况调查研究

通过对文科大一与大三学生的抽样调查,采用问卷调查、课堂观察和深度访谈这三种方法,对其数学学习情况进行了具体的分析研究,由此发现文科教材中存在的问题:中学与大学的过渡环节较为欠缺以及教材内容的构成成分有待完善.     

三角网格模型五轴加工刀轴矢量调整及优化

为消除全局干涉,提出了一种基于K-D树及刀具离散的高效刀轴矢量调整算法.算法首先以有限个点离散表示刀具,然后利用K-D树快速查找刀具的可能干涉点,并在此基础上计算调整后的刀轴矢量.为避免过大的刀轴矢量突变,提出一种分角度区域方法优化刀轴矢量.实例验证表明:算法能够高效实现全局干涉避免及刀轴矢量优化.     

A novel liquid chromatography Orbitrap mass spectrometry method with full scan for simultaneous determination of multiple bioactive constituents of Shenkang injection in rat tissues: Application to tissue distribution and pharmacokinetic studies

Shenkang injection is a traditional Chinese formula with good curative effect on chronic renal failure. In this paper, a novel, rapid and sensitive ultra‐high‐performance liquid chromatography coupled with Q Exactive hybrid quadrupole Orbitrap high‐resolution accurate mass spectrometry was developed and validated for simultaneous determination of seven bioactive constituents of Shenkang injection in rat plasma and tissues after intravenous administration. Acetonitrile was used as a protein precipitation agent in biological samples disposal with carbamazepine as internal standard. The chromatographic separation was carried out on a C₁₈ column with a gradient mobile phase consisting of acetonitrile and water (containing 0.1% formic acid). The MS analysis was performed in the full‐scan positive and negative ion mode. The lower limits of quantification for the seven analytes in rat plasma and tissues were 0.1–10 ng/mL. The validated method was successfully applied to tissue distribution and pharmacokinetic studies of Shenkang injection after intravenous administration. The results of the tissue distribution study showed that the high concentrations of seven constituents were primarily in the kidney tract. This is the first report of the application of Q‐Orbitrap with full‐scan mass spectrometry in tissue distribution and pharmacokinetic studies of Shenkang injection.     

Semantic image annotation based on GMM and random walk model

Automatic image annotation has been an active topic of research in computer vision and patternrecognition for decades.A two stage automatic image annotation method based on Gaussian mixturemodel (GMM) and random walk model (abbreviated as GMM-RW) is presented.To start with,GMM fitted by the rival penalized expectation maximization (RPEM) algorithm is employed to estimatethe posterior probabilities of each annotation keyword.Subsequently, a random walk processover the constructed label similarity graph is implemented to further mine the potential correlations ofthe candidate annotations so as to capture the refining results, which plays a crucial role in semanticbased image retrieval.The contributions exhibited in this work are multifold.First, GMM is exploitedto capture the initial semantic annotations, especially the RPEM algorithm is utilized to train themodel that can determine the number of components in GMM automatically.Second, a label similaritygraph is constructed by a weighted linear combination of label similarity and visual similarity ofimages associated with the corresponding labels, which is able to avoid the phenomena of polysemyand synonym efficiently during the image annotation process.Third, the random walk is implementedover the constructed label graph to further refine the candidate set of annotations generated byGMM.Conducted experiments on the standard Corel5k demonstrate that GMM-RW is significantlymore effective than several state-of-the-arts regarding their effectiveness and efficiency in the task of automatic image annotation.     

如何应用手机二维码提升图书馆服务水平

在概述手机二维码的概念与特点的基础上，着重介绍了二维码在资源定位、OPAC信息检索、链接门户网站、服务引导、身份认证、信息查询等方面的应用，探讨了手机二维码应用于图书馆的优势及做法。     

Phase retrieval from fringe pattern with 1-D discrete wavelet transform

This paper proposes a novel method to obtain frequency modulation (FM) signals from a single fringe pattern for phase retrieval. First, a 1D discrete Meyer wavelet is employed to decompose the pattern image signal row by row and the soft-thresholding approach is applied to remove noise. The low frequency coefficients of the wavelet decomposition are then set to 0, and the signal is reconstructed. Moreover, the optimal wavelet decomposition level is adaptively determined using a cost function-based method. The reconstructed signal, which no longer contains a background component, is normalized using a nonlinear and piecewise normalization method. The proposed method is faster and more accurate than some other phase retrieval approaches, which is illustrated with two test cases.     

生物工程专业文献检索课探讨

以万方数据知识服务系统和中国知网为检索范围,阐述了生物工程专业文献检索课的研究现状,从教材选用、教师素质、授课内容、授课方式、考核方式、反馈机制6个方面介绍了生物工程专业文献检索课的设计与实施。     

浅议网络新闻文本的优缺点

近年来,国内外传统纸媒业纷纷停刊、合并、倒闭,而网络媒体却大行其道。业界诸多学者认为纸媒行业的衰败已是大势所趋,网络传媒业将前景光明,事实上网络传媒并非十全十美。本文就围绕网络新闻文本的优缺点进行探讨。