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61.
Yoshitomo Ono Naoyuki Kawashima Hiroto Kudo Tadatomi Nishikubo Takabumi Nagai 《Journal of polymer science. Part A, Polymer chemistry》2007,45(14):2978-2988
The ring‐opening copolymerization of a glycidyl ester derivative having a benzophenone group and the donor–acceptor norbornadiene (D‐A NBD) dicarboxylic acid, 5‐(4‐methoxyphenyl)‐1,4,6,7,7‐pentamethyl‐2,5‐norbornadiene‐2,3‐dicarboxylic acid, monoglycidyl ester derivatives with D‐A NBD dicarboxylic anhydride using tetraphenylphosphonium bromide as a catalyst proceeded smoothly to give novel self‐photosensitizing NBD polymers in good yields. The molecular weight of these polyesters was about 4,000, and lower than that of analogous NBD polymers having no benzophenone group. All the synthesized NBD polymers isomerized smoothly to the corresponding quadricyclane (QC) polymers upon UV irradiation in tetrahydrofuran (THF) solution and in the film state. The rate of the photoisomerization of the D‐A NBD moieties in these polymers was higher than that of the D‐A NBD moieties in the polymer having no photosensitizing group. Furthermore, the rate of the photoisomerization of the D‐A NBD moieties in these polymers was also higher than that of the NBD polymer with low molecular weight photosensitizer in dilute solution. The photo‐irradiated polymers having QC moieties released thermal energies of 146–180 J/g. The D‐A NBD moieties contained in these NBD polymers possessed fair to good fatigue resistance. The degradation of the NBD moieties in these polymers was 15–30% after 50 repeated cycles of interconversion. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 2978–2988, 2007 相似文献
62.
63.
Guey‐Sheng Liou Hung‐Yi Lin Yu‐Lun Hsieh Yi‐Lung Yang 《Journal of polymer science. Part A, Polymer chemistry》2007,45(21):4921-4932
N‐(4‐nitrophenyl)‐4′,4″‐bisformyl‐diphenylamine was synthesized from N‐(4‐nitrophenyl)‐diphenylamine by the Vilsmeier‐Haack reaction. Soluble aromatic poly(azomethine)s (PAMs) were prepared by the solution polycondensation of N‐(4‐nitrophenyl)‐4′,4″‐bisformyl‐diphenylamine and aromatic diamine in N‐methyl‐2‐pyrrolidone (NMP) at room temperature under reduced pressure. All the PAMs are highly soluble in various organic solvents, such as N,N‐dimethylacetamide (DMAc), chloroform (CHCl3), and tetrahydrofuran (THF). Differential scanning calorimetry (DSC) indicated that these PAMs had glass‐transition temperatures (Tgs) in the range of 170–230 °C, and a 10% weight‐loss temperatures in excess of 490 °C with char yield at 800 °C in nitrogen higher than 60%. These PAMs in NMP solution showed UV‐Vis charge‐transfer (CT) absorption at 405–421 nm and photoluminescence peaks around 462–466 nm with fluorescence quantum efficiency (ΦF) 0.10–0.99%. The highest occupied molecular orbital (HOMO) and lowest unoccupied molecular orbital (LUMO) energy levels of these PAMs can be determined from cyclic voltammograms as 4.86–5.43 and 3.31–3.34 eV, respectively. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 4921–4932, 2007 相似文献
64.
李正平 《科技情报开发与经济》2007,17(20):287-288
指出了电流互感器的测试准确度对电机性能的影响,分析了电流互感器产生误差的原因及其影响因素,提出了几点防范措施。 相似文献
65.
李丽英 《科技情报开发与经济》2007,17(19):234-235
阐述了成本管理的重要性及业绩考核的作用,探讨了完善经济指标考核制度的具体内容,提出了完成业绩指标的措施,指出应进一步加强车间成本管理并完善考核机制。 相似文献
66.
李燕玲 《科技情报开发与经济》2007,17(34):174-176,180
从我国上市公司业绩评价的指标入手,指出由于指标本身存在缺陷,使公司有机可乘,而使舞弊造假时有发生。提出了完善上市公司业绩评价指标的假设,以达到防范证券市场风险、维护投资者利益的目的。 相似文献
67.
以木素为原料制备了两性絮凝剂LSDC,并将其用于污泥的调质处理。实验结果表明LSDC可使污泥沉降速度提高至原始污泥的1.25倍,污泥的过滤比阻则降低至原始污泥的40%左右,泥饼含水率由93%降低至80%。两性木素絮凝剂在污泥调质处理中的应用为木素的高附加值利用提供了新的途径。 相似文献
68.
We study the vessel arrival process in bulk ports handling either cargo containers or minerals. Then we introduce the SHIP/G/1 queue to be able to study the queueing behavior at the port. We present approximations for the asymptotic probabilities of delay and the number of vessels at the port. Numerical examples show the accuracy of the approximations. In appendices, we provide details of the analysis of the number of vessels at the port and the correlation properties of the vessel arrival process. 相似文献
69.
This paper deals with the analysis of an M/M/c queueing system with setup times. This queueing model captures the major characteristics of phenomena occurring in production
when the system consists in a set of machines monitored by a single operator. We carry out an extensive analysis of the system
including limiting distribution of the system state, waiting time analysis, busy period and maximum queue length.
AMS subject classification: 90B22, 60K25 相似文献
70.
根据模糊数学理论,运用模糊意见集中评价和模糊综合评价方法,计算机性能评价和销售预测进行研究,为评价差别不是很明显和含有多种因素的事物,提供了科学有效的方法. 相似文献