Synthesis, crystal structure and magnetic property of a new nickel selenite chloride: Ni5(SeO3)4Cl2

The new nickel selenite chloride, Ni₅(SeO₃)₄Cl₂, was obtained by high-temperature solid state reaction of NiCl₂, Ni₂O₃ and SeO₂ in a 1:2:4 molar ratio at 700 °C in an evacuated quartz tube. Its structure was established by single-crystal X-ray diffraction. Ni₅(SeO₃)₄Cl₂ crystallizes in the triclinic system, space group P-1 (No. 2) with cell parameters of a=8.076(2), b=9.288(2), c=9.376(2) Å, α=101.97(3), β=105.60(3), γ=91.83(3)° and Z=2. All nickel(II) ions in Ni₅(SeO₃)₄Cl₂ are octahedrally coordinated by selenite oxygens or/and chloride anions (([Ni(1)O₅Cl], [Ni(2)O₄Cl₂], [Ni(3)O₅Cl], [Ni(4)O₆] and [Ni(5)O₄Cl]). The structure of the title compound features a condensed three-dimensional (3D) network built by Ni(II) ions interconnected by SeO₃²⁻ anions as well as Cl⁻ anions. Magnetic property measurements show strong antiferromagnetic interaction between nickel(II) ions.     

Syntheses, crystal structures and characterizations of BaZn(SeO3)2 and BaZn(TeO3)Cl2

Two new barium zinc selenite and tellurite, namely, BaZn(SeO₃)₂ and BaZn(TeO₃)Cl₂, have been synthesized by the solid state reaction. The structure of BaZn(SeO₃)₂ features double chains of [Zn(SeO₃)₂]²⁻ anions composed of four- and eight-member rings which are alternatively along a-axis. The double chains of [Zn₂(TeO₃)₂Cl₃]³⁻ anions in BaZn(TeO₃)Cl₂ are formed by Zn₃Te₃ rings in which each tellurite group connects with three ZnO₃Cl tetrahedra. BaZn(SeO₃)₂ and BaZn(TeO₃)Cl₂ are wide bandgap semiconductors based on optical diffuse reflectance spectrum measurements.     

最优套期比率理论及其估计方法的比较

本文首先在均值-方差框架下,对最优套期比率（OHR）的确定进行了分析,分别从静态和动态角度进行了回顾.我们对OHR的估计模型进行了介绍和比较,分别通过移动平均（RW）模型、EWMA模型和基于PE分布的强估计模型进行实证检验.本文对各种模型、方法都是基于最小方差（MV）框架的,在中国期货市场上,这种分析框架比较具有现实意义.     

基于协同过程的产品开发链框架研究

从内涵、概念模型以及协同过程控制等方面建立了产品开发链的理论框架,提出了产品开发链的组织、过程及环境多视图模型;从成员选择的角度研究了开发链的构建原理;介绍了开发链的5大组成要素,即开发目标、组织结构、开发活动及任务、产品数据、协同控制机制等,而协同过程是产品开发链的核心元素,最后提出了基于协同过程的产品开发链系统层次框架.     

摔跤训练器主体与模拟人连接机构的分析与改进

阐述了摔跤训练器的基本机构,利用齐次坐标变换建立了摔跤训练器主体机构与模拟人连结部分的运动关系;根据理论推导的结果,分析了此机构的特点,提出了改进方案。该方案克服了训练器在滚桥动作中的一些不足之处。     

基于模型库的冷连轧过程控制仿真支撑系统

结合当前实际应用对改善仿真建模过程的需求,以简化专业领域仿真过程、提高仿真建模效率为目的,提出了以模型重用技术为基础,基于领域模型库的仿真支撑系统的思想,给出了仿真支撑系统总体结构设计方案,并针对带钢冷连轧过程优化控制系统,就标准仿真流程框架的提取、层次化领域模型库的构建及支撑系统运行机制的实现等关键问题进行了探讨·应用实例说明本文提出的仿真支撑系统总体框架及运行机制是可行的·     

核磁共振法表征磷改性斜发沸石骨架硅铝的变化

用固固相P—Al同晶取代的方法，采用焙烧和微波两种加热方式磷改性斜发沸石。并用^27Al、^29Si和^31P高分辨MASNMR表征磷改性前后斜发沸石骨架上的硅铝变化，结果表明，两种方法都能使沸石骨架Al脱除，形成八面体Al(H2O)^3 6，骨架硅铝比显著增大，微波法对斜发沸石骨架P—Al同晶取代效果比焙烧法好，同时，两种方法对磷改性斜发沸石的骨架结构影响也不同。     

基于网络分布式入侵检测系统的设计与实现

对现有的入侵检测技术进行了阐述。在结合通用入侵检测系统框架模型的基础上，提出和实现基于网络分布式入侵检测系统，该系统具备良好扩展性。     

用ASP.net制作动态网页

随着互联网的发展，网页的制作由静态转向动态，即网页已具备交互性与自动更新的功能，分析了微软的新战略，NET，以及基于．Net framework sdk的ASP．net和ADO．net，利用ASP．net制作了一个实用的动态网页．     

Dynamical framework with blocking topography coordinates for atmospheric GCM and its validation

The dynamical framework with Blocking Topography Coordinates (hereafter, BTC), which is suited to handle the steep topography for the atmospheric general circulation models, is presented in this paper, together with its validation results. The integral properties of both the differential and finite-difference equations for the BTC dynamical core are: gross mass conservation, quadratic conservation for advection terms, Coriolis force does not change the kinetic energy, conservation of total available energy. The improved nonlinear iteration scheme is utilized for the time-integration. The energy conservation for BTC dynamical core is validated by using the integration results from 9-layer and 21-layer version respectively. Comparison results show that, the changes of the kinetic energy and total available potential energy during the integration are quite close for both the BTC dynamical framework and the dynamical framework of IAP 9-level and IAP 21-level AGCM, and this may suggest that the BTC dynamical core can be used for long-term integration with good computational stability. Furthermore, the BTC dynamical core has the advantage over the terrain following (sigma) coordinates in its better representation of the influence of the large-scale topography on the atmospheric general circulation. Finally, the correctness and reasonableness of the BTC dynamical core has been further proved by the numerical simulation of the topography influence on the quasi-stationary planetary wave with 21-layer version of BTC dynamical framework.