Supramolecular framework adducts constructed of hexamethylenetetramine,aquated alkali metal cationic clusters,and hexacyanoferrates(II/III)

The reaction of alkali metal hexacyanoferrate(II/III) with (CH₂)₆N₄ (hexamethylenetetramine, abbreviated HMT) in an acidic medium yielded crystalline compounds of stoichiometries HK₂[Fe¹¹¹(CN)₆]·2HMT·4H₂O, H₂K₂[Fe¹¹(CN)₆]·2HMT·4H₂O, and HNa₂[Fe¹¹¹(CN)₆]· 2HMT·5H₂O. Their crystal structures are based on a packing of three molecular components: neutral and/orprotonated HMT, hexacyanoferrate, and an alkali metal ion-water cluster. The resulting three-dimensional supramolecular framework is constructed from the coordination of the alkali metal ion by aqua ligands as well as [Fe(CN)₆]{n–} and HMT units, and further stabilization is achieved by hydrogen bonding between water molecules and the noncoordinated nitrogen atoms of HMT and hexacyanoferrate.     

Synthesis and structural characterization of a coordination polymer of silver(I) with saccharinate and nicotinamide

A silver(I)-saccharinato (sac) complex with nicotinamide (nia), [Ag(sac)(nia)] _n has been synthesized and characterized by elemental analysis, IR spectroscopy, DTA-TG analyses and single crystal X-ray diffractometry. The complex crystallizes in monoclinic space group P2₁/n with unit cell parameters of a=7.0258(4) Å, b=24.3784(10) Å, c=8.4301(5) Å, β=109.407(5)°, V=1361.85(13) ų and Z=4. [Ag(sac)(nia)] _n contains [Ag(sac)(nia)] units, which are doubly bridged by both nia and sac ligands, leading to a linear one-dimensional polymeric chains running along the a axis. The silver(I) ion has a highly distorted AgN₂O₂ tetrahedral geometry and the coordination polymer exhibits relatively short intra-chain ligand supported Ag···Ag separations of 3.1593(4) Å. The one-dimensional chains are crosslinked by N–H···O hydrogen bonds and aromatic π(sac)···π(nia) stacking interactions to generate a two-dimensional layer structure. IR spectra and thermal analysis data are in agreement with the crystal structure.     

具有双螺旋链的新型二维无机-有机骨架晶体材料Ni(PDC)(H2O)2的合成与结构

本文报道由H2PDC合成的新型维层状无机-有机骨架晶体Ni(PDC)(H2O)2(H2PDC=吡啶-2,5-二羧酸), 该化合物的一层是由右手螺旋Ni—O—C链与左手螺旋Ni-pdc链组成, 而邻近的一层则是由左手螺旋Ni—O—C链与右手螺旋Ni-pdc链组成, 层与层之间通过氢键作用形成了三维超分子结构. 用ICP、TG、IR和X射线单晶衍射分析等手段对其结构进行表征.     

Synthesis, crystal structure and magnetic property of a new nickel selenite chloride: Ni5(SeO3)4Cl2

The new nickel selenite chloride, Ni₅(SeO₃)₄Cl₂, was obtained by high-temperature solid state reaction of NiCl₂, Ni₂O₃ and SeO₂ in a 1:2:4 molar ratio at 700 °C in an evacuated quartz tube. Its structure was established by single-crystal X-ray diffraction. Ni₅(SeO₃)₄Cl₂ crystallizes in the triclinic system, space group P-1 (No. 2) with cell parameters of a=8.076(2), b=9.288(2), c=9.376(2) Å, α=101.97(3), β=105.60(3), γ=91.83(3)° and Z=2. All nickel(II) ions in Ni₅(SeO₃)₄Cl₂ are octahedrally coordinated by selenite oxygens or/and chloride anions (([Ni(1)O₅Cl], [Ni(2)O₄Cl₂], [Ni(3)O₅Cl], [Ni(4)O₆] and [Ni(5)O₄Cl]). The structure of the title compound features a condensed three-dimensional (3D) network built by Ni(II) ions interconnected by SeO₃²⁻ anions as well as Cl⁻ anions. Magnetic property measurements show strong antiferromagnetic interaction between nickel(II) ions.     

基于协同过程的产品开发链框架研究

从内涵、概念模型以及协同过程控制等方面建立了产品开发链的理论框架,提出了产品开发链的组织、过程及环境多视图模型;从成员选择的角度研究了开发链的构建原理;介绍了开发链的5大组成要素,即开发目标、组织结构、开发活动及任务、产品数据、协同控制机制等,而协同过程是产品开发链的核心元素,最后提出了基于协同过程的产品开发链系统层次框架.     

摔跤训练器主体与模拟人连接机构的分析与改进

阐述了摔跤训练器的基本机构,利用齐次坐标变换建立了摔跤训练器主体机构与模拟人连结部分的运动关系;根据理论推导的结果,分析了此机构的特点,提出了改进方案。该方案克服了训练器在滚桥动作中的一些不足之处。     

基于网络分布式入侵检测系统的设计与实现

对现有的入侵检测技术进行了阐述。在结合通用入侵检测系统框架模型的基础上，提出和实现基于网络分布式入侵检测系统，该系统具备良好扩展性。     

用ASP.net制作动态网页

随着互联网的发展，网页的制作由静态转向动态，即网页已具备交互性与自动更新的功能，分析了微软的新战略，NET，以及基于．Net framework sdk的ASP．net和ADO．net，利用ASP．net制作了一个实用的动态网页．     

Dynamical framework with blocking topography coordinates for atmospheric GCM and its validation

The dynamical framework with Blocking Topography Coordinates (hereafter, BTC), which is suited to handle the steep topography for the atmospheric general circulation models, is presented in this paper, together with its validation results. The integral properties of both the differential and finite-difference equations for the BTC dynamical core are: gross mass conservation, quadratic conservation for advection terms, Coriolis force does not change the kinetic energy, conservation of total available energy. The improved nonlinear iteration scheme is utilized for the time-integration. The energy conservation for BTC dynamical core is validated by using the integration results from 9-layer and 21-layer version respectively. Comparison results show that, the changes of the kinetic energy and total available potential energy during the integration are quite close for both the BTC dynamical framework and the dynamical framework of IAP 9-level and IAP 21-level AGCM, and this may suggest that the BTC dynamical core can be used for long-term integration with good computational stability. Furthermore, the BTC dynamical core has the advantage over the terrain following (sigma) coordinates in its better representation of the influence of the large-scale topography on the atmospheric general circulation. Finally, the correctness and reasonableness of the BTC dynamical core has been further proved by the numerical simulation of the topography influence on the quasi-stationary planetary wave with 21-layer version of BTC dynamical framework.     

基于Struts体系结构的企业级应用系统

Struts是一个MVC框架,它提供了对开发MVC系统的底层支持,采用的主要技术有Servlet,JSP和自定义标签库.本文在介绍MVC模式的基础上,介绍了Struts体系结构,以远程教育应用系统为例,用Struts体系结构构建企业级应用系统,分析该应用系统的企业级实体Bean的数据关系,最后给出了远程教育应用系统的部署.