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71.
A 368- water molecule structure I gas hydrate, encased by the number of helium (He) molecules ranging from two to twenty-two, are calculated by molecular dynamical simulations. The potential TIP4P (transferable intermolecular potentical with four sites) is used for water interactions and Lennard-Jones for He-He and He-water interactions. He molecules do not affect the water lattice and can stabilize the hydrate when their concentration is small. A trough signature of He encased is found at 80~90 meV in the phonon density of states. He molecules prefer to be more off-center in 51262 cages. Heavier isotope He are energetically favorable to be filled in cages. 相似文献
72.
Thermotropic copolyester fibers of oxynaphthoate and oxybenzoate have been subjected to conditions that promote solid-state polymerization as well as annealing. The annealing process causes the crystals to perfect with a simultaneous increase in heat of fusion and melting temperature. Solid-state polymerization, a reaction rate-controlled process, causes the polymer viscosity average molecular weight to increase by chain extension from about 14,000 g/mole to more than 87,000 g/mole with a simultaneous impressive increase in tenacity from about 10 g/d (1.2 GPa) to almost 30 g/d (3.7 GPa). To understand the changes in mechanical properties, we have modeled the fiber structure as short rod-like molecules poorly bonded to a continuous matrix of parallel molecules. Lengthening of the reinforcing molecules facilitates better transfer of load from matrix to molecules, resulting in higher tenacity fibers. © 1994 John Wiley & Sons, Inc. 相似文献
73.
太行山长城岭南山东北坡植被的研究 总被引:4,自引:1,他引:3
本文研究了太行山长城岭南山东北坡的植被分布及其特征。结果表明,从山麓至山顶,由于气候条件随海拨的逐渐升高而产生了明显的垂直变化,从而导致了植被分布的垂直变化。从山麓至山顶依次分布有落叶阔叶林、针阔混交林、针叶林和落叶阔叶灌丛等四个植被型、并因人为干扰落叶阔叶林正向针阔叶混交林和针叶林方向演替。 相似文献
74.
TAN Shang-wang GUO Ji-ming QI JianDepartment of Applied Mathematics Petroleum University Dongying China 《数学季刊》2004,19(1):57-62
Let T denote a tree with the diameter d(d≥2) and order n. Let P^*d,r,n-d-1denote the tree obtained by identifying the rth vertex of path Pd l and the center of starKl,K1,n-d-1, where r = r(d) is the integer part about d 2/2. Then p(T)≤ p(P^*d,r,n-d-1), andequality holds if and only if T≌P^*d,r,n-d-1 相似文献
75.
76.
We study computable trees with distinguished initial subtree (briefly, I-trees). It is proved that all I-trees of infinite height are computably categorical, and moreover, they all have effectively infinite computable dimension. 相似文献
77.
The symbols in Hawthorne’s masterpiece The Scarlet Letter have the characteristics of indefiniteness and multi-sense. Each character brings out a different side of the forest,however the forest also brings out a different side in each character.The forest reflects multi-dimension. The image of "woods" or "forest" in The Scarlet Letter manifests Horthorne's understanding and exploring of the human nature. The forest may stand for individual freedom,innocence,truth,danger and evil as well. 相似文献
78.
We have studied the temperature dependence of the radiative deactivation of the Pd-porphine triplet states in Shpol’skii matrices
in the temperature range 1.2–210 K. A substantial transformation of the phosphorescence spectra is observed as the temperature
increases and is due to the inclusion of thermally activated Pd-porphine states in the radiative deactivation processes. The
activation energy Ea of these Pd-porphine states is measured in matrices of n-octane and n-nonane. The splitting of the lowest quasidegenerate
triplet state ΔE(T2−T1) is determined for planar and distorted conformations of the Pd-porphine macrocycle in the n-octane matrix as 40 and 57 cm−1, respectively. The ability to use the temperature dependence of the phosphorescence properties of Pd-porphine to fabricate
molecular thermometers for the low-temperature range is analyzed.
__________
Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 74, No. 4, pp. 460–464, July–August, 2007. 相似文献
79.
基于决策树方法的银行客户信用评估 总被引:1,自引:0,他引:1
分析了传统银行客户信用评估方法存在的问题,针对ID3算法存在的不足,提出了一种改进的ID3算法.实验结果表明,改进后的ID3算法分类正确率有所提高,所生成的决策树较为健壮、简洁,可以减少计算代价,提高计算效率. 相似文献
80.
S. F. Chekmarev R. Mitri V. Bonaci-Koutecký 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2003,24(1-3):45-48
The ab initio molecular
dynamics (AIMD) [1] is combined with the heuristic, successive
confinement method of surveying a potential energy surface (PES)
[2], thereby offering a framework for the simulation study of
kinetics and equilibrium properties of metallic clusters. This
approach is applied to the study of Au4,
a cluster possessing a simple but specific PES, which consists
of very shallow and deep basins and due to this presents a
challenge to the conventional AIMD methods. Among other things,
the probabilities of the transitions between isomers have been
found, and on this basis, both the time-dependent and
equilibrium populations of the isomers have been calculated for
the conditions typical of the NeNePo experiments [3] in the
femtosecond pump-probe spectroscopy. 相似文献