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41.
Masuhiro Tsukada Giuliano Freddi Nobutami Kasai 《Journal of Polymer Science.Polymer Physics》1994,32(7):1175-1182
The physical structure and compatibility of solution-cast Antheraea pernyi/Bombyx mori silk fibroin blend films were stuided by differential scanning calorimetry (DSC), thermomechanical (TMA) and thermogravimetric (TGA) analysis, dynamic viscoelastic measurement, infrared spectroscopy, and x-ray diffractometry. The DSC curves of the blend films showed independent endotherms at 280 and 358°C, corresponding to the thermal decomposition of B. mori and A. pernyi silk fibroins with random coil conformation. The intensity was roughly proportionate to the amount of each component in the blend. The thermal behavior corresponding to the conformational transitions induced by heating on A. pernyi and B. mori silk fibroins overlapped in the temperature range 190–230°C. Thermal expansion and contraction properties, as well as weight retention behavior of the blend films were intermediate between the pure components, as shown by the TMA and TGA curves. The onset temperature of the storage modulus curve decreased markedly, approaching that of B. mori silk fibroin film when the amount of this component in the blend increased. The loss modulus curve of the blend films showed two peaks at ca. 190 and 210°C, the former corresponding to B. mori, and the latter to A. pernyi silk fibroin. Infrared spectra of the blends exhibited absorption bands characteristic of the pure components overlapping in the spectral region 2000–400 cm?1. The x-ray diffraction peaks at 23 and 21.5°, attributed to the crystalline spacings of A. pernyi and B. mori fibroins, respectively, overlapped in the diffraction curves of the blends, while the peak at 11.4°, of A. pernyi, increased as the content of this fibroin in the blend increased. The degree of crystallinity, calculated from the x-ray diffraction curves, diminished as the amount of B. mori silk fibroin decreased. A low degree of compatibility exists between the two fibroins when they are cast from aqueous solution in the experimental conditions adopted in this work. © 1994 John Wiley & Sons, Inc. 相似文献
42.
将系统理论引入数字图书馆研究中 ,介绍了数字图书馆的人员结构系统以及各个子系统的特点 .阐述了各个子系统和系统环境与用户服务之间的相互关系以及如何利用这种关系来提高数字图书馆的服务 相似文献
43.
李学敏 《山东师范大学学报(自然科学版)》1994,9(1):6-10
讨论了第一临界情形下的平面三次系统高次奇点的局部拓朴结构,并给出利用多项式系数的判断准则。 相似文献
44.
45.
以砌体结构为例,阐明在工程量计算中应正确应用统筹法,并得出了砌体工程量计算的统筹公式。 相似文献
46.
工程设计单位小型局域网的组建与管理 总被引:1,自引:0,他引:1
介绍了小型局域网的特点,结构类型的选择,布线方法,操作系统的选择、安装与配置,安装防火墙和即时杀毒软件,并介绍了小型局域网的有效管理。 相似文献
47.
Xia Yin Weiguang Zhang Qijiao Zhang Jun Fan Chian Sing Lai Edward R. T. Tiekink 《应用有机金属化学》2004,18(3):139-140
The centrosymmetric structure of {Cd[S2CN(CH2Ph)2]2}2 features both bridging and chelating dithiocarbamate ligands so that a square pyramidal S5 coordination geometry results. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献
48.
The centrosymmetric title compound, [Cd2{CH3OC6H4P(OC5H9)S2}4], features an eight‐membered [? Cd? S? P? S? ]2 ring owing to the presence of bridging dithiolate ligands. Tetrahedral coordination geometries for cadmium are completed by chelating ligands. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献
49.
路振华 《贵州工业大学学报(自然科学版)》2007,36(2):15-19
运用理想点法来构造评价函数,将求解多目标规划问题转化为求解单目标规划问题得出最优解,以毕节地区1997年到2005年土地利用结构变化为实例。研究结果表明:“理想点法”能反映出历年土地利用结构变化间的细微差别,为使土地利用寓于社会经济发展和维持生态系统平衡之中,最终谋求社会、经济、生态三效益的统一提供有价值的参考。 相似文献
50.
《科学通报(英文版)》2008,(11)
Based on density functional theory (DFT) of the first-principle for the cathode materials of lithium ion battery, the electronic structures of Li(Fe1-xMex)PO4 (Me = Ag/Mn, x = 0―0.40) are calculated by plane wave pseudo-potential method using Cambridge serial total energy package (CASTEP) program. The calculated results show that the Fermi level of mixed atoms Fe1-xAgx moves into its conduction bands (CBs) due to the Ag doping. The Li(Fe1-xAgx)PO4 system displays the periodic direct semiconductor characteristic with the increase of Ag-doped concentration. However, for Fe1-xMnx mixed atoms, the Fermi level is pined at the bottom of conduction bands (CBs), which is ascribed to the interaction be-tween Mn(3d) electrons and Fe(4s) electrons. The intensity of the partial density of states (PDOS) near the bottom of CBs becomes stronger with the increase of Mn-doped concentration. The Fermi energy of the Li(Fe1-xMnx)PO4 reaches maximum at x = 0.25, which is consistent with the experimental value of x = 0.20. The whole conduction property of Mn-doped LiFePO4 is superior to that of Ag-doped LiFePO4 cathode material, but the structural stability is reverse. 相似文献