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排序方式: 共有2069条查询结果,搜索用时 218 毫秒
71.
Water splitting has attracted more and more attention as a promising strategy for the production of clean hydrogen fuel. In this work, a new synthesis strategy was proposed, and Co0.85Se was synthesized on nickel foam as the main matrix. The doping of appropriate Cr amount into the target of Co0.85Se and the Cr‐Co0.85Se resulted in an excellent electrochemical performance. The doping of Cr introduces Cr3+ ions which substitute Co2+ and Co3+ ions in Co0.85Se, so that the lattice parameters of the main matrix were changed. It is worth noting that the Cr0.15‐Co0.85Se/NF material exhibits an excellent performance in the oxygen evolution reaction (OER) test. When the current density reaches 50 mA cm?2 for OER, the overpotential is only 240 mV. For the hydrogen evolution reaction (HER) tests, the overpotential is only 117 mV to drive 10 mA cm?2 of current density. Moreover, when the Cr0.15‐Co0.85Se/NF material is used as a two‐electrode device for whole water splitting, the required cell voltage is only 1.43 V to reach a current density of 10 mA cm?2, which is among the lowest values of the published catalysts up to now. In addition, the Cr0.15‐Co0.85Se/NF catalyst also exhibits excellent stability during a long period of water splitting. The experimental result demonstrates that the change of the lattice structure has an obvious influence on the electrocatalytic activity of the material. When an external electric field is applied, it facilitates the rapid electron transfer rate and enhances the electrocatalytic performance and stability of the material. 相似文献
72.
采用真空低压渗流铸造法,制备了泡沫A1-0.146wt.%Ti合金.分析了影响渗流法制备泡沫铝合金的主要因素,得到了制备泡沫合金的最佳条件:NaCl填料粒子预热温度300℃,合金液体浇铸温度760℃,填料粒子尺寸1~3mm.不同孔率泡沫AI-O.146wt.%Ti合金的模拟海水全浸实验结果表明:泡沫合金的耐腐蚀性能随着孔率增加显著下降. 相似文献
73.
74.
P2P资源搜索算法概述 总被引:3,自引:0,他引:3
在介绍P2P的网络体系结构的基础上,分析P2P搜索算法的优缺点,阐述非结构化P2P网络和结构化P2P网络采用的搜索算法,为高性能的P2P搜索算法的提出奠定基础. 相似文献
75.
Chenxi Zhai Yang Yu Yumei Zhu Jing Zhang Ying Zhong Jingjie Yeo Mingchao Wang 《Molecules (Basel, Switzerland)》2022,27(3)
Foaming effect strongly impacts the physical and mechanical properties of foam glass materials, but an understanding of its mechanism especially at the molecular level is still limited. In this study, the foaming effects of dextrin, a mixture of dextrin and carbon, and different carbon allotropes are investigated with respect to surface morphology as well as physical and mechanical properties, in which 1 wt.% carbon black is identified as an optimal choice for a well-balanced material property. More importantly, the different foaming effects are elucidated by all-atomistic molecular dynamics simulations with molecular-level insights into the structure–property relationships. The results show that smaller pores and more uniform pore structure benefit the mechanical properties of the foam glass samples. The foam glass samples show excellent chemical and thermal stability with 1 wt.% carbon as the foaming agent. Furthermore, the foaming effects of CaSO4 and Na2HPO4 are investigated, which both create more uniform pore structures. This work may inspire more systematic approaches to control foaming effect for customized engineering needs by establishing molecular-level structure–property–process relationships, thereby, leading to efficient production of foam glass materials with desired foaming effects. 相似文献
76.
77.
超临界水驱超稠油提高采收率热物理特性研究 总被引:2,自引:0,他引:2
超稠油资源的高效开发对于提高石油供给和保障我国石油安全意义重大。针对深层超稠油资源由于原始地层压力高、原油黏度大导致常规蒸汽驱无法有效开发的问题,本文提出超临界水驱开发深层超稠油的新思路。本文首先研制了超临界水驱油提高采收率实验平台,研发的管式填砂岩心模型能够模拟岩心升温和驱替的同步过程,然后开展了超临界水驱、蒸汽驱和热水驱对比实验研究,实验结果表明,相对于蒸汽驱,超临界水驱能显著提高采收率并具有更高的热效率,25MPa、400℃超临界水驱鲁克沁超稠油的采收率达到97.07%;获得了超临界水驱过程的温度场和驱替压差变化规律,发现了超临界水超覆现象,与蒸汽超覆相比,超临界水超覆发生晚且持续短,可扩大波及范围,提高采收率。 相似文献
78.
常温下为液态的镓铟锡合金以其优异的导热性能在具有特殊要求的传热领域有着重要的应用价值,与传统流动介质相比较大的表面张力使得其产生的流动现象必有所区别.本文研究镓铟锡所形成的液滴撞击泡沫金属表面后所产生的铺展、回缩及回弹现象.采用高速相机拍摄液滴投影轮廓随液滴运动的变化过程,并通过图像处理获得不同撞击速度、底板表面孔径下的液滴铺展系数、中心位置轮廓高度以及液滴回弹后在空中的振动特性.研究结果表明:具有较高表面张力的镓铟锡液滴的铺展系数随无量纲时间的变化在铺展初始阶段仍满足常规流体的1/2次幂关系,只在铺展后期与底板的无量纲孔径有关系;液滴的最大铺展系数在较小无量纲孔径底板大于在光滑镍板,且随底板无量纲孔径增大而逐渐减小;在回弹过程,由于底板孔隙结构的存在使得液滴回弹后在空中的振动呈现3种形态:规则的横向和纵向振动、带旋转的横向和纵向振动以及旋转振动;最后,通过对振动频率的拟合和分析,进一步拓展了传统振动频率理论公式在非规则振动过程预测中的应用. 相似文献
79.
为研究多孔吸能材料泡沫铝板对工程结构的抗爆防护作用,开展室外爆炸破坏实验,分别对设置不同泡沫铝防护层的钢筋混凝土(reinforced concrete,RC)板在爆炸荷载下的动态响应及破坏模式进行了研究,并运用LS-DYNA软件建立了有限元模型。通过与实验对照,验证了模型的可行性,对比分析了有、无泡沫铝防护层钢筋混凝土板的损伤破坏规律,并讨论了泡沫铝密度梯度分布和纵筋配筋率的影响。结果表明:有限元模型能够有效分析含泡沫铝防护层RC板的动态响应及其破坏形态;泡沫铝防护层能够有效减小钢筋混凝土板的挠度变形,降低试件的破坏程度;泡沫铝密度由下到上递增情况对RC板的减爆效果最好;增大配筋率可以提升泡沫铝防护RC板整体抗爆性能。 相似文献
80.
In this study, nineteen unmodified lignins from various sources (hardwood, softwood, wheat straw, and corn stover) and isolation processes (kraft, soda, organosolv, sulfite, and enzymatic hydrolysis) were used to replace 30 wt.% of petroleum-based polyol in rigid polyurethane/polyisocyanurate (PUR/PIR) foam formulations. Lignin samples were characterized by measuring their ash content, hydroxyl content (Phosphorus Nuclear Magnetic Resonance Spectroscopy), impurities (Inductively Coupled Plasma), and pH. After foam formulation, properties of lignin-based foams were evaluated and compared with a control foam (with no lignin) via cell morphology, closed-cell content, compression strength, apparent density, thermal conductivity, and color analysis. Lignin-based foams passed all measured standard specifications required by ASTM International C1029-15 for type 1 rigid insulation foams, except for three foams. These three foams had poor compressive strengths, significantly larger cell sizes, darker color, lower closed-cell contents, and slower foaming times. The foam made with corn stover enzymatic hydrolysis lignin showed no significant difference from the control foam in terms of compressive strength and outperformed all other lignin-based foams due to its higher aliphatic and p-hydroxyphenyl hydroxyl contents. Lignin-based foams that passed all required performance testing were made with lignins having higher pH, potassium, sodium, calcium, magnesium, and aliphatic/p-hydroxyphenyl hydroxyl group contents than those that failed. 相似文献