可扩展单一映象文件系统的设计、实现及评价

曙光超级服务器是典型的机群系统，COSMOS是为其研制开发的可扩展的单一映象文件系统．文中主要描述了COSMOS原型系统的设计、实现及评价．其中重点介绍了双粒度合作式缓存、分布式元数据管理及网络磁盘存储分组等关键技术，并利用I／O基准程序对原型文件系统进行了性能评价，测试结果表明了谊原型系统在保证系统单一映象的基础上，具备晟好的可扩展性．     

网络环境下高等数学部分内容形象化的实现

通过二维图形、二维动画和三维动画的制作及学生与学习内容的互动,实现网络环境下高等数学部分内容的形象化,其目的是加强学生对高等数学概念和理论的理解,提高学习效率.     

中心裂纹圆盘裂纹形状尺寸对应力强度因子的影响

采用有限元数值分析方法 ,分析了由脆性材料制成的中心裂纹圆盘试件 ,在复合模式加载条件下裂纹形状尺寸 ,尤其是裂纹宽度和中心小孔半径对应力强度因子的影响 .结果表明 :槽式和槽孔组合式裂纹圆盘试件 ,其I型无量纲应力强度因子FⅠ均比按理想裂纹推出的解析解大 ,而Ⅱ型无量纲应力强度因子FⅡ 均比解析解小 ;随着加载角度增加 ,FⅠ 的数值解与解析解的差值逐渐变小 ,而FⅡ 的差值逐渐变大 ;同时 ,随着裂纹槽宽度或中心小孔半径的增加 ,应力强度因子数值解与解析解之差逐步增加 .依据数值分析的结果 ,给出了这两类试件相对于理想中心裂纹圆盘试件应力强度因子解析解的修正公式 .     

FTO客体3m闪光照相的Monte Carlo研究

 研究了客体模型FTO的闪光照相系统X光输运过程，给出了直穿照射量、散射照射量、直散比、直穿照射量能谱、散射照射量能谱、直穿X光通量能谱和散射X光通量能谱在记录平面的空间分布。结果表明：后锥是照射量散射成分的主要来源，后锥照射量占总散射量97%；后锥也是造成散射的空间分布不均匀的主要器件，这一不均匀性高达58%。照相系统的最小直散比非常小，表明锥造成的散射已经严重地淹没了直穿（轫致辐射）信号。计算中使用高空间分辨率记录法进行分点，合成图像对吸收系数的复原结果与国外报道的结果相符。     

Esters flash point prediction using artificial neural networks

In this article, an artificial neural network to predict the flash point of 95 esters was implemented. Four variables were used for its development. A neural network with 4‐5‐8‐5‐1 topology was encountered to gain the best agreement of the experimental results with those predicted (square correlation coefficient (R²) and root mean square error were 0.99 and 5.46 K for the training phase and 0.96 and 13.02 K for the testing set). © 2012 Wiley Periodicals, Inc.     

Hydrophobic cryogels for DNA adsorption: Effect of embedding of monosize microbeads into cryogel network on their adsorptive performances

As alternative hydrophobic adsorbent for DNA adsorption, supermacroporous cryogel disks were synthesized via free radical polymerization. In this study, we have prepared two kinds of cryogel disks: (i) poly(2‐hydroxyethyl methacrylate‐N‐methacryloyl‐l ‐tryptophan) [p(HEMA‐MATrp)] cryogel containing specific hydrophobic ligand MATrp; and (ii) monosize p(HEMA‐MATrp) particles synthesized via suspension polymerization embedded into p(HEMA) cryogel structure to obtain p(HEMA‐MATrp)/p(HEMA) composite cryogel disks. These cryogel disks containing hydrophobic functional group were characterized via swelling studies, Fourier transform infrared spectroscopy, elemental analysis, surface area measurements and scanning electron microscopy. DNA adsorption onto both p(HEMA‐MATrp) cryogel and p(HEMA‐MATrp)/p(HEMA) composite cryogels was investigated. Maximum adsorption of DNA on p(HEMA‐MATrp) cryogel was found to be 15 mg/g polymer. Otherwise, p(HEMA‐MATrp)/p(HEMA) composite cryogels significantly increased the DNA adsorption capacity to 38 mg/g polymer. Composite cryogels could be used repeatedly without significant loss on adsorption capacity after 10 repetitive adsorption–desorption cycles. Copyright © 2013 John Wiley & Sons, Ltd.     

Flash Vacuum Pyrolysis: Techniques and Reactions

Flash vacuum pyrolysis (FVP) had its beginnings in the 1940s and 1950s, mainly through mass spectrometric detection of pyrolytically formed free radicals. In the 1960s many organic chemists started performing FVP experiments with the purpose of isolating new and interesting compounds and understanding pyrolysis processes. Meanwhile, many different types of apparatus and techniques have been developed, and it is the purpose of this review to present the most important methods as well as a survey of typical reactions and observations that can be achieved with the various techniques. This includes preparative FVP, chemical trapping reactions, matrix isolation, and low temperature spectroscopy of reactive intermediates and unstable molecules, the use of online mass, photoelectron, microwave, and millimeterwave spectroscopies, gas‐phase laser pyrolysis, pulsed pyrolysis with supersonic jet expansion, very low pressure pyrolysis for kinetic investigations, solution‐spray and falling‐solid FVP for involatile compounds, and pyrolysis over solid supports and reagents. Moreover, the combination of FVP with matrix isolation and photochemistry is a powerful tool for investigations of reaction mechanism.     

Direct UVC photodegradation of imipramine in aqueous solutions: a mechanistic study

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Synthesis by FVT and Characterization of Unhindered Silanethiones

The retro-ene reaction of allylthio- and propargylthiosilanes led, under flash vacuum thermolysis (FVT) conditions, to unhindered silanethiones, characterized by their derivatives, and also directly by coupling of the FVT with gas-phase spectrometries. Monomeric silicon oxysulfide has been generated similarly. The unsubstituted silanethione was not obtained, but dehydrogenated into silicon monosulfide during FVT.