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51.
Rooha Khurram Zaib Un Nisa Aroosa Javed Zhan Wang Mostafa A. Hussien 《Molecules (Basel, Switzerland)》2022,27(4)
This study describes the preparation of graphitic carbon nitride (g-C3N4), hematite (α-Fe2O3), and their g-C3N4/α-Fe2O3 heterostructure for the photocatalytic removal of methyl orange (MO) under visible light illumination. The facile hydrothermal approach was utilized for the preparation of the nanomaterials. Powder X-ray diffraction (XRD), Scanning electron microscopy (SEM), Energy dispersive X-ray (EDX), and Brunauer–Emmett–Teller (BET) were carried out to study the physiochemical and optoelectronic properties of all the synthesized photocatalysts. Based on the X-ray photoelectron spectroscopy (XPS) and UV-visible diffuse reflectance (DRS) results, an energy level diagram vs. SHE was established. The acquired results indicated that the nanocomposite exhibited a type-II heterojunction and degraded the MO dye by 97%. The degradation ability of the nanocomposite was higher than that of pristine g-C3N4 (41%) and α-Fe2O3 (30%) photocatalysts under 300 min of light irradiation. The formation of a type-II heterostructure with desirable band alignment and band edge positions for efficient interfacial charge carrier separation along with a larger specific surface area was collectively responsible for the higher photocatalytic efficiency of the g-C3N4/α-Fe2O3 nanocomposite. The mechanism of the nanocomposite was also studied through results obtained from UV-vis and XPS analyses. A reactive species trapping experiment confirmed the involvement of the superoxide radical anion (O2•−) as the key reactive oxygen species for MO removal. The degradation kinetics were also monitored, and the reaction was observed to be pseudo-first order. Moreover, the sustainability of the photocatalyst was also investigated. 相似文献
52.
《Physics letters. A》2020,384(26):126662
We study the dynamic of magneto-polaron condensate in monolayer two dimensional (2D) transition metal dichalcogenides (TMDs) materials of 2H types in triangular quantum well potential. Within both the quantum mechanical Schrödinger approach (QMSA) and the improved Wigner-Brillouin theory (IWBT), Landau energies levels (LELs) are derived. We have shown that the magneto-polaron condensation is enhanced in monolayer MoSe2 compared to MoS2, WS2 and WSe2. We derive various levels by increasing a magnetic field and laser parameter. We show that the quantum confinement lifts the degeneracy of the Landau levels (LLs) resulting in an anticrossing and crossing. The dephasing effect due to the quantum well potential's parameter plays an important role in the magneto-polaron energy corrections, which are also affected by the amplitude of the laser field. The system presents Stückelberg oscillations which is important for practical applications. 相似文献
53.
用相对论HartreeFock方法对YⅦ—AgⅩⅤ离子4s24p3和4s24p25s组态的能级结构进行了系统的理论计算.通过分析能级结构的Slater径向积分参数沿等电子序列的变化规律,运用参数拟合外推(或内插)的方法计算了上述离子组态的能级结构参数.在此基础上,计算了Rh,Pd和AgⅩⅤ离子4s24p3(4S32,2P12,32,2D12,32)和4s24p25s(4P12,32,52,2P12,32,2D32,52,2S12)组态的精细结构能级以及这两个组态之间电偶极允许跃迁的全部35条谱线波长与相应的振子强度,其中Pd和AgⅩⅤ离子的所有数据纯属目前的预测计算值. 相似文献
54.
利用半经典量子化理论和量子理论,分别采用Lennard-Jones势和Morse势,对双原子分子的振动能级给予了较为详细的数值计算。并将所得结果与部分实验数据进行比较,峄双原子分子的振动能级作了较为详细的 讨论。 相似文献
55.
陈少寅 《浙江万里学院学报》2010,23(3):105-107
《孙子兵法》蕴含的“和谐”艺术深刻、睿智地阐发了许多认识论和方法论原则。文章以《孙子兵法》中的“经之五事”:“道、天、地、将、法”为切入点,结合高校学生党员管理的团队精神培养、校园环境建设、用人选拔、制度建设五方面展开阐述,力求将《孙子兵法》中最具普遍理论意义的“和谐”艺术应用到高校学生党员管理中去。以“古为今用”为原则为高校学生党员管理研究提供新的阐释视角,进而探索富有时代特色的高校学生党员管理之路。 相似文献
56.
武器装备的供给应着力于构建"寡头主导、大中小企业分层竞争"的产业组织结构。采办方应设计最优的主承包招标机制,以促进各寡头企业之间的投标竞争,从而实现最佳采办效益。武器装备采办的分层次竞争不完全取决于采办方的竞争意愿,其还要受到武器装备供给企业的产权安排、军民融合程度、纵向一体化及采办代理人制度等多种因素的影响。 相似文献
57.
Attila G. Császár Tamás Szidarovszky Nikolai F. Zobov Oleg L. Polyansky Jonathan Tennyson 《Journal of Quantitative Spectroscopy & Radiative Transfer》2010,111(9):1043-1106
A new, accurate, global, mass-independent, first-principles potential energy surface (PES) is presented for the ground electronic state of the water molecule. The PES is based on 2200 energy points computed at the all-electron aug-cc-pCV6Z IC-MRCI(8,2) level of electronic structure theory and includes the relativistic one-electron mass-velocity and Darwin corrections. For H216O, the PES has a dissociation energy of D0 = 41 109 cm−1 and supports 1150 vibrational energy levels up to 41 083 cm−1. The deviation between the computed and the experimentally measured energy levels is below 15 cm−1 for all the states with energies less than 39 000 cm−1. Characterization of approximate vibrational quantum numbers is performed using several techniques: energy decomposition, wave function plots, normal mode distribution, expectation values of the squares of internal coordinates, and perturbing the bending part of the PES. Vibrational normal mode labels, though often not physically meaningful, have been assigned to all the states below 26 500 cm−1 and to many more above it, including some highly excited stretching states all the way to dissociation. Issues to do with calculating vibrational band intensities for the higher-lying states are discussed. 相似文献
58.
S. Gandolfi F. Pederiva S. a Beccara 《The European Physical Journal A - Hadrons and Nuclei》2008,35(2):207-211
We computed ground-state energies of calcium isotopes from 42Ca to 48Ca by means of the Auxiliary Field Diffusion Monte Carlo (AFDMC) method. Calculations were performed by replacing the 40Ca core with a mean-field self-consistent potential computed using the Skyrme interaction. The energy of the external neutrons
is calculated by projecting the ground state from a wave function built with the single-particle orbitals computed in the
self-consistent external potential. The shells considered were the 1F
7/2 and the 1F
5/2 . The Hamiltonian employed is semi-realistic and includes tensor, spin-orbit and three-body forces. While absolute binding
energies are too deep if compared with experimental data, the differences between the energies for nearly all isotopes are
in very good agreement with the experimental data. 相似文献
59.
A. E. Kochetov A. S. Mikhaylushkin 《The European Physical Journal B - Condensed Matter and Complex Systems》2008,61(4):441-444
We report the results of our first-principles studies
of the interaction between an infinite monoatomic gold nanowire and
a carbon-monoxide molecule. We show that the gold
monoatomic nanowire is capable of absorbing the CO molecule at the
distances of about 1.8 ? and forms a bond with the carbon atom.
Further, we find that dissociation of the
CO molecule as the source of gold nanowire contamination with carbon, which is
widely discussed in literature as the possible reason for
the striking stability of gold nanowires under stretching, is thermodynamically
unfavored. 相似文献
60.
Neji Khelifi 《Journal of Russian Laser Research》2008,29(3):274-287
Adiabatic and diabatic study for all the states dissociating below the ionic limit [i.e., Na (3s, 3p, 4s, 3d, 4p, 5s, 4d,
and 4f) + H (1s)] in 1Σ+ and 3Σ+ symmetries are presented. Adiabatic results are also reported for 1,3Π and 1,3Δ symmetries. Pseudo-potential, operatorial core-valence correlation, and full valence CI approaches combined with an efficient
diabatization procedure are used in these ab initio calculations. Our vibrational-level spacings and spectroscopic constants
are in good agreement with the available experimental data for the low-lying states. Diabatic potentials and dipole moments
are analyzed, revealing the strong imprint of the ionic state in the 1Σ+ adiabatic states. The hydrogen electron affinity correction was taken into account by the use of the efficient diabatization
method. This leads to a better agreement with the available experimental data. Experimental suggestions are also given for
the higher excited states based on their unusual behavior. 相似文献