全文获取类型
收费全文 | 3096篇 |
免费 | 375篇 |
国内免费 | 248篇 |
专业分类
化学 | 645篇 |
晶体学 | 9篇 |
力学 | 106篇 |
综合类 | 33篇 |
数学 | 394篇 |
物理学 | 707篇 |
综合类 | 1825篇 |
出版年
2024年 | 7篇 |
2023年 | 31篇 |
2022年 | 57篇 |
2021年 | 61篇 |
2020年 | 87篇 |
2019年 | 83篇 |
2018年 | 82篇 |
2017年 | 104篇 |
2016年 | 116篇 |
2015年 | 122篇 |
2014年 | 189篇 |
2013年 | 224篇 |
2012年 | 190篇 |
2011年 | 198篇 |
2010年 | 159篇 |
2009年 | 156篇 |
2008年 | 167篇 |
2007年 | 196篇 |
2006年 | 185篇 |
2005年 | 175篇 |
2004年 | 143篇 |
2003年 | 145篇 |
2002年 | 109篇 |
2001年 | 97篇 |
2000年 | 77篇 |
1999年 | 84篇 |
1998年 | 59篇 |
1997年 | 59篇 |
1996年 | 51篇 |
1995年 | 44篇 |
1994年 | 42篇 |
1993年 | 41篇 |
1992年 | 35篇 |
1991年 | 30篇 |
1990年 | 23篇 |
1989年 | 22篇 |
1988年 | 13篇 |
1987年 | 17篇 |
1986年 | 8篇 |
1985年 | 9篇 |
1984年 | 6篇 |
1983年 | 2篇 |
1981年 | 3篇 |
1980年 | 3篇 |
1979年 | 2篇 |
1978年 | 3篇 |
1977年 | 3篇 |
排序方式: 共有3719条查询结果,搜索用时 15 毫秒
51.
Pérez Pavón JL Guerrero Peña A García Pinto C Moreno Cordero B 《Journal of chromatography. A》2004,1047(1):101-109
The direct coupling of a headspace sampler with a mass spectrometer is proposed as a screening tool for the rapid detection of soil pollution by hydrocarbons from petroleum and derivatives. The samples are subjected to the headspace generation process, with no prior treatment, and the volatiles generated are introduced directly into the mass spectrometer, thereby obtaining a fingerprint of the sample analysed. Suitable treatment of the signal by chemometric techniques allows unequivocal characterisation of the different types of sample. The use of fast gas chromatography with a mass spectrometer detector coupled to the headspace sampler allows identification of the major hydrocarbons present in the mineral and organic polluted samples, interpretation of the results obtained, and demonstrates the analytical potential of headspace-mass spectrometry coupling. 相似文献
52.
53.
54.
55.
Min-zhi Chen Xiao-liang Wang Fang-fang Tao Qi Xue Ping-chuan 《高分子科学》2007,(1):107-111
The concept of entanglement provides the basis of our current understanding of the flow behavior of polymer melts, Current techniques developed to investigate the degree of interpenetration of polymer chains only provide indirectly the information of the degree of entanglement in a relatively large scale (several to tens of nanometer). In this article, we report ^1H-NMR spectroscopy with dipolar filters under fast magic angle spinning for probing chain interpenetration of polymer glasses at the molecular level. 相似文献
56.
T. V. Gryaznova Yu. G. Budnikova O. G. Sinyashin 《Russian Journal of Electrochemistry》2007,43(10):1151-1155
An alternative approach to synthesis of electrophilic terminal phosphinidene complexes of tungsten pentacarbonyl with various substituents at the phosphorus atom has been developed. The approach is based on the reaction of the electrochemically generated tungsten pentacarbonyl ion with trivalent phosphorus acyl chlorides. Electrochemical reduction of ethyldichlorophosphines in the presence of α-diimines is a one-step process that forms 1,3,2-diazaphospholenes containing an exocyclic P-C bond. 相似文献
57.
Shinya Hamasaki Chie Sawauchi Masami Kamigaito Mitsuo Sawamoto 《Journal of polymer science. Part A, Polymer chemistry》2002,40(4):617-623
A fast living radical polymerization of methyl methacrylate (MMA) proceeded with the (MMA)2? Cl/Ru(Ind)Cl(PPh3)2 initiating system in the presence of n‐Bu2NH as an additive [where (MMA)2? Cl is dimethyl 2‐chloro‐2,4,4‐trimethyl glutarate]. The polymerization reached 94% conversion in 5 h to give polymers with controlled number‐average molecular weights (Mn's) in direct proportion to the monomer conversion and narrow molecular weight distributions [MWDs; weight‐average molecular weight/number‐average molecular weight (Mw/Mn) ≤ 1.2]. A poly(methyl methacrylate) with a high molecular weight (Mn ~ 105) and narrow MWD (Mw/Mn ≤ 1.2) was obtained with the system within 10 h. A similarly fast but slightly slower living radical polymerization was possible with n‐Bu3N, whereas n‐BuNH2 resulted in a very fast (93% conversion in 2.5 h) and uncontrolled polymerization. These added amines increased the catalytic activity through some interaction such as coordination to the ruthenium center. © 2002 John Wiley & Sons, Inc. J Polym Sci Part A: Polym Chem 40: 617–623, 2002; DOI 10.1002/pola.10148 相似文献
58.
结合Thin—Client/Server架构在图书馆信息系统的实际应用情况,分析图书馆应用自动化的技术要求及Thin—Client/Server架构的优缺点.针对该架构的优缺点搞好终端服务器运行、客户端设备使用以及网络连接的管理,有利于进一步提高Thin—Client/Server架构在图书馆的功用. 相似文献
59.
非稳态等离子体射流在液体中的膨胀特性 总被引:3,自引:0,他引:3
该文采用数字高速摄影测试技术对电弧等离子体射流在液体中膨胀特性、泰勒空腔发展过程进行了实验研究。通过对录像图片的分析,初步获得了放电能量及喷嘴结构对等离子体射流结构特征和泰勒空腔在轴向和径向的发展过程的影响。测得的泰勒空腔头部发展速度与前人的实验结果相同,但在射流结构上有新的发现,相间界面存在明显的冷却暗区,泰勒空腔有时出现间断。 相似文献
60.
Isotopic evolution of the terminal Neoproterozoic and early Cambrian carbon cycle on the northern Yangtze Platform, South China 总被引:2,自引:0,他引:2
Profound geotectonic, climatic and biological changes occur during the terminal Neoproterozoic and its transition into the early Cambrian. These are reflected in temporal variations of the chemical and isotopic composition of seawater. We are studying a sequence of sedimentary rocks at the Shatan section, northern Yangtze Platform, Sichuan Province of China. This succession comprises, in ascending stratigraphic order, predominantly calcareous sediments of the Sinian upper Dengying Formation and black shales of the lower Cambrian Guojiaba Formation (time equivalent of Niutitang Fm.). Paleoenvironmental setting represents shallow-water shelf deposits. The objective of our study is to provide temporal records for the isotopic compositions of organic and carbonate carbon throughout this time interval. Organic carbon isotope values display a range between -35.8‰ and -30.1‰ with clear stratigraphic variations. Carbonate carbon isotope data vary between -3.5‰ and +0.5‰. These secular variations are interpreted to reflect perturbations of the global carbon cycle, specifically changes in the fractional burial of organic carbon. However, local conditions have further affected the isotopic signals. 相似文献