新型薄壁柴油机缸体铸件的研制与应用

采用低合金化、合锑多元复合孕育剂、扫描电镜、200h台架试验、以及l000h耐久试验等方法对新型薄壁柴油机缸体铸件进行了研制与应用试验．试验结果表明：碳当量控制在3．9％--4．1％时(与菲亚特缸体的碳当量大体相当)，采用低合金化及合锑复合孕育剂，可稳定获得高强度铸件，抗拉强度σb＞270MPa，硬度HB＞210，白口倾向小，硬度差小于35HB，其性能均达到菲亚特缸体的性能要求．对无缸套缸体的缸壁表面进行激光处理，比传统缸套的耐磨性提高一倍以上．由于采用了无缸套缸体生产技术，简化了柴油机的结构，降低了柴油机的生产成本，提高了柴油机使用性能和技术含量．     

CoCl（CNPh）2（pph3）2的制备,结构和性质

由ＣｏＣｌ（ＰＰｈ３）３与过量ＰｈＮＣＳ在苯溶液中的反应制备出一种流的Ｃｏ（Ｉ）的五配位配合物．根据红外，１Ｈ核磁共振、快原子轰击质谱、ｘ电子能谱及元素分析结果确定其分子式为ＣｏＣｌ（ＣＮＰｈ）２（ＰＰｈ３）２与类似的配合物比较，推断该配合物具有三角双锥结构，其中两个大体积的叔膦基成轴间配位．从ｄ－ｐ户反馈π键度讨论了ＩＲ及１ＨＮＭＲ．此外，也对该回合物的溶解性、热稳定性以及对Ｏ２的稳定性加以了描述．     

太行山长城岭南山东北坡植被的研究

本文研究了太行山长城岭南山东北坡的植被分布及其特征。结果表明,从山麓至山顶,由于气候条件随海拨的逐渐升高而产生了明显的垂直变化,从而导致了植被分布的垂直变化。从山麓至山顶依次分布有落叶阔叶林、针阔混交林、针叶林和落叶阔叶灌丛等四个植被型、并因人为干扰落叶阔叶林正向针阔叶混交林和针叶林方向演替。     

重庆主城区社区体育的现状调查

采用问卷调查、文献资料、数理统计等研究方法，对重庆市主城区社区体育现状进行调查，分析了社区居民参加体育活动的内容、时间、地点、形式、规模，以及社区体育的服务管理、设施管理、体育人才管理、体育经营管理系统，并提出了符合实情，可体现地理、环境特点的重庆主城区社区体育发展对策。     

Azine bridged silver coordination polymers: Powder X-ray diffraction route to crystal structure determination of silver benzotriazole

In continuation of our interest in solid-state structures of silver complexes of photographic importance, the structure for silver benzotriazole (AgBZT), has now been obtained. The preferred method for solving crystal structures is via single-crystal X-ray diffraction (XRD). However, for some materials, growing single crystals of appropriate size and quality is often difficult or even impossible. AgBZT is an example of such a silver complex with poor solubility. The usual routes to preparing single crystals using recrystallization from a cooperating solvent resulted in polycrystalline powder samples. We propose a crystal structure for AgBZT, solved from synchrotron X-ray powder diffraction data, using a direct-space Monte Carlo simulated annealing approach. AgBZT crystals are monoclinic, (P2₁/c), with unit cell dimensions, a=14.8052(3) Å, b=3.7498(4) Å, c=12.3495(12) Å, and β=114.200(6)°. The AgBZT complex is constructed from all three of the Benzotriazole (BZT) nitrogens bonding to a separate silver atom. As a consequence of this bonding mode, the structure is a highly cross-linked, coordination polymer.     

Assembly and Photophysics of Ternary Luminescent Lanthanide Molecular Complex Systems

In this paper, according to the molecular fragment principle, a series of eight ternary luminescent lanthanide complex systems were assembled, and whose compositions were determined with elemental analysis and infrared spectrum: Ln(MA)₃(L)·H₂O, where Ln = Sm, Eu, Tb, Dy; HMA = α‐methylacrylic acid; L = 1,10‐phenanthroline (phen), 2,2′‐bipyridine (bipy). The photophysical properties of these functional molecular systems were studied with ultraviolet‐visible absorption spectrum, and fluorescence excitation and emission spectrum. It was found that the heterocylic compounds (phen and bipy) act as the main energy donor and luminescence sensitizer for their suitable energy match and effective energy transfer to the emission energy level of Ln³⁺ ions. MMA ligand was only used as the terminal structural ligand to influence the luminescence. Especially terbium complex systems show the strongest luminescence for the optimum energy match and transfer between phen (bipy) and Tb³⁺ ion.     

萃取浮选光度法测定微量钼的研究及应用

研究了用甲苯萃取浮选Mo(Ⅴ)—SCN~-—Kφ三元络合物的各种条件。在硫酸介质中,紫红色络合物最大吸收波长位于585nm,摩尔吸光系数为2.8×10~5l·mol~(-1)·cm~(-1),钼量在0—10μg/25ml范围内符合比耳定律。大量常见元素均不干扰,40倍的钨(Ⅵ)亦不干扰钼的测定,方法已应用于钨矿中微量钼的测定,其结果令人满意。     

一维连通复合形的实现

定理1:一维连通无有闭道复形K,在E~2内实现. 定理2:存在一个一维连通复形,有九个一维单形,不能在E~2内实现. 定理3:一维连通复形,有八个一维单形,可在E~2内实现. 定理2,定理3是最好的定理.问题是:n维连通复形(n≥2),相应的定理2定理3是如何表示?     

Mechanism of Interaction of γ-Halogenated Salts of Pyrylium and Benzopyrylium with Aromatic Amines

Stoichiometry and kinetics of reactions of 2,6-diphenyl-4-chloropyrylium, 4-chloroflavylium, 4-bromoflavylium, and 4-iodoflavylium perchlorates with nucleophiles N,N-dimethylaniline and n-phenylenediamine are studied using cyclic voltammetry and spectroscopy. Nucleophilic substitution in these compounds proceeds via the formation of a charge-transfer complex, which converts into a radical ion pair as a result of the electron transfer. Heterolytic clevage of the C–Hal bond occurs at the stage of pyranyl (flavanyl) radical.