Mechanism of coadsorption of two organic substances on electrodes at strong attractive interaction between their molecules in the adsorption layer

Based on the model of three parallel capacitors, the differential capacitance and the surface concentration of two organic compounds coadsorbed on an electrode are calculated as a function of the potential. It is shown that for the strong attractive interaction of two different adsorbed molecules that occupy equal areas on the surface and for different combinations of the other adsorption parameters is well described by the model of two parallel capacitors with a simple Frumkin isotherm. However, in this case, the effective attraction constant in this isotherm should depend on the electrode potential. The obtained results show that the good agreement of experimental data with the calculations based on the model of two parallel capacitors is insufficient for assuming that the orientation of adsorbed molecules of a given organic compound is potential-independent. On the other hand, if the adsorbate molecule in two different orientations occupies different areas on the electrode surface, then the model of two parallel capacitors does not allow one to describe the dependence of the total surface concentration on the electrode potential even under the conditions where this model adequately describes the differential capacitance curves.     

Some algorithms for equivalent transformation of nondeterministic finite automata

In this paper we consider algorithms which allow one to combine several states of a nondeterministic finite automaton into one state. Along with the algorithms for combining states, we adduce one more algorithm for the equivalent transformation of a non-deterministic finite automaton, namely, an algorithm for adding cycles. Problems under consideration imply the development of robust computer programs.     

FAE战斗部毁伤威力评价的试验研究

利用基于靶板毁伤效应和超压-冲量准则的FAE战斗部毁伤威力评价方法,分别对三种不同起爆方式和燃料配方的FAE战斗部进行了毁伤威力评价的试验,并计算得到了相应的TNT威力当量值。结果表明,1#云爆弹在炸距3.8 m之后靶板的变形挠度大于同药量的RDX/TNT装药,在炸距3.8～4.2 m之间的TNT当量约为2.0;在炸距13～18 m之间,采用新型固液混合燃料的2#云爆弹的靶板变形挠度约为传统环氧丙烷燃料的3#云爆弹的1.4倍,TNT当量分别为3.75和2.96。     

卫星夹层结构夹芯层力学性能分析与数值模拟

由于高强、质轻的特点,夹层结构材料在工程领域得到了广泛的应用.本文对卫星夹层结构所采用的蜂窝夹芯进行力学性能分析,推导出六边形蜂窝夹芯结构的等效弹性常数;并选取某型号卫星蜂窝夹芯结构,对其进行数值模拟研究.通过对比理论计算和数值模拟结果,验证了等效弹性参数公式的正确性,可作为卫星蜂窝夹芯结构的优化设计的理论依据.     

CVC轧辊辊形参数的确定

对CVC轧辊的辊形曲线进行数学解析,研究轧辊的轴向移动量与轧辊有效凸度的关系,推导辊形参数的理论计算公式,得到从工艺角度出发计算辊形系数A1的公式,并对某CSP厂CVC轧辊技术参数进行计算,提出其辊形参数的修正建议。     

对两道未定式解法的分析与探讨

以一道未定式的求解为例,通过对使用洛必达法则求解时求导过程比较复杂的原因分析,提出在求导前对函数进行预处理的思想,并指出等价无穷小替换是有效的处理方法.而针对另一道未定式问题,指出相关文献为论证一种错误的解法而使用的反例是错的,给出该解法存在错误的具体说明.     

一个Hilbert型不等式及其等价形式的加强推广

本文研究了Hilbert型级数不等式.利用改进的Euler-Maclaurin求和公式及权系数的方法,并引进两对共轭指数,获得一个具有最佳常数系数的Hilbert型不等式,该不等式是联系若干Hilbert型不等式的加强推广式.作为应用,给出该不等式的等价形式及若干有意义的特殊结果.     

基于遗传算法的岩体参数辨识研究

目前,对于岩体流固耦合分析研究已经很多,而耦合分析常常受困于计算参数的取值,因此对两场耦合模型中的计算参数反演分析是非常必要的.根据实测的水头、位移资料,利用遗传算法,建立了等效连续岩体渗流场与应力场耦合计算参数辨识模型.并对某算例在库水位下降情况下,以渗流场与应力场耦合正分析计算结果作为"实测值",进行两场耦合参数辨识分析.从参数辨识的结果来看,验证了所提出的思路、方法以及程序的正确性和可行性.两场耦合计算参数进行反演分.析,对于两场耦合模型的建立和计算结果的可靠性是非常有意义的.     

基于PS021的电容式冰层厚度检测系统的设计

根据空气、冰和水的电容特性差异,本文设计了一种新型的电容式冰层厚度检测系统.该检测系统应用了德国acam公司的电容数字转换器PS021,可以把电容式传感器采集到的电容信号转换成数字信号输出.黄河的现场实验数据分析结果表明,系统结构简单,可靠性高,可以应用于冬季河道冰层厚度及冰下水位的定点、连续自动测量.     

一个有限区间逆向的Hilbert型积分不等式

引入多参数,应用分析的方法以估算权函数,在有限区间(a,b)(0相似文献