The concentration quenching characteristics of ~5D_3-~7F_J and ~5D_4-~7F_J (J=0―6) transitions of Tb~(3 ) in YBO_3:Tb~(3 ) phosphor

The photoluminescence quenching behaviors of 5D3-7FJ and 5D4-7FJ (J = 0―6) transitions of Tb3 in YBO3:Tb under 130―290 nm excitation were systematically investigated. The results revealed that the quenching concentrations of both 5D3-7FJ and 5D4-7FJ transitions of Tb3 in YBO3:Tb were mainly de-pendent on excitation wavelength. Particularly,the quenching concentrations of 5D4-7FJ transitions of Tb3 under 130―290 nm excitation were correlated with excitation bands of YBO3:Tb. The quenching concentrations of 5D3-7FJ transitions remained at low concentration (2%) under 186―290 nm excitation and then increased gradually with energy of incoming excitation photon when excited at 130―186 nm. This dependence should be involved in their excitation mechanisms and quenching pathway in particular excitation region.     

基于模糊数学的计算机性能评价和销售预测的研究

根据模糊数学理论,运用模糊意见集中评价和模糊综合评价方法,计算机性能评价和销售预测进行研究,为评价差别不是很明显和含有多种因素的事物,提供了科学有效的方法.     

线弹性有限元的自适应加密与多重网格法求解

基于Ｚｉｅｎｋｉｅｗｉｃｚ－Ｚｈｕ误差估计方法，自适应策略以及分子表结构，研制出功能强大的自适应多重网格有限元程序。该程序可对任意曲线组成的计算区域进行全局与局部加密。以应力集中问题为例，展示了自适应多重网格有限元的主要特征。研究结果表明：本文采用的误差枯计方法，自适应策略对线弹性问题的有效的，自适应多重网格有限元求解应力集中问题具有精度高，收敛速度快的优点。     

Thermodynamic and surface properties of Sb-Sn and In-Sn liquid alloys

The thermodynamic properties of Sb-Sn and In-Sn liquid alloys have been studied using the quasi-chemical model for compound forming binary alloys and that for simple regular alloys. The concentration fluctuation S _cc(0) and the Warren-Cowley short-range order parameter (α ₁) were determined for the whole concentration range at a temperature of 770 K. The surface tensions of these liquid alloys were determined for the whole concentration range by using energetics determined from thermodynamic calculations. In all calculations, In-Sn manifested properties very close to alloys of ideal mixing, while Sb-Sn showed properties that are asymmetric about equiatomic composition. Our results suggest that a weak complex of the form SbSn₂ could be present in the Sb-Sn alloy at a temperature of about 770 K.     

横向爆炸载荷下开孔弹性板的应力集中

基于ANSYS 7.0/LS-DYNA程序,对3 m×3 m四边简支、厚度为0.025 m、中心开有0.3 m×0.3 m方孔的弹性板,在下三角爆炸载荷作用下的应力响应进行了分析;利用能量密度时间分布函数(TDFED)确定了动应力集中因子,重点讨论了时间步长和采样时间间隔对计算结果的影响。     

管流与环缝入流的管内合流特性──等温浓度场与紊流特性实验研究

在对管流与环缝入流的管内合流特性完成等温速度场实验研究的基础上，以对应一致的实验条件，实测了时均浓度分布，紊流正应力和紊流切应力分布．结果证明：浓度分布有与速度分布相一致的变化趋势和规律，但合流后截面上浓度均匀化比速度均匀化慢；合流动量相交产生附加雷诺应力，并决定合流后速度分布和浓度分布的均匀化进程．为建立系统的化学反应流动规律提供基础．     

能耗率极值原理和重力理论交互作用下粗质颗粒的浓度垂线分布

本文同时运用能耗率极值原理和重力理论研究了固液两相流在粗质颗粒时固相浓度的垂线分布,通过探讨能耗率极值原理对“非单向性”作用问题,进一步揭示了两相流运动的机理。计算结果与实测数据有较好的吻合。其研究方法、原理、步骤也极易推广到其它各种粒径的固相。     

Synthesis of Polyacrylaminothiourea Chelating Fiber and Properties of Concentration and Separation of Trace Noble Metal Ions from Samples

A novel polyacrylaminothiourea chelating fiber was synthesized simply and rapidly from nitrilon (an acrylonitrile-based synthetic fiber), which was applied to preconcentrate and separate of trace amount of Au(Ⅲ）,Pt(Ⅳ）,Pd(Ⅳ） and Ir (Ⅳ） ions from solution of samples.The analyzed ions can be quantitatively concentrated by the fiber up to a flow rate of 20.0mL/min at pH2, and can also be desorbed with 15 mL of 4mol/L HCl 3% thiourea from the fiber column with recoveries of 96.5%-100%.The chelating fiber can be reused for ten times,the recoveries of these ions are still over 92%,and hundred to thousand times of excess of Fe(Ⅲ）,Al（Ⅲ）,Ca(Ⅱ），Mg（Ⅱ）,Ni(Ⅱ）,Mn（Ⅱ),Cu(Ⅱ），Zn(Ⅱ），and Cd(Ⅱ） cause no interference on the determination of the analyzed ions by inductively-coupled plasma atomic emission spectrometry (ICP-AES).The static saturation adsorption capacities of the fiber for the analytes are in the range of 1.15-2.80mmol/g.The relative standard deviations for the determination of 20.0ng/mL each of Au(Ⅲ）,Pt(Ⅳ）,Pd(Ⅳ）and Ir(Ⅳ） are in the range of 0.7%-3.0%.The recoveries for test from standard additions to real solution samples are between 96% and 100%.The concentration of each ion in powder sample detected by the method is in good agreement with the certified value.     

两亲嵌段共聚物聚乙二醇-聚谷氨酸苄酯纳米粒药物载体的合成研究

用磺酸酯法制备单端氨基聚乙二醇引发剂,引发谷氨酸苄酯羧酸酐开环聚合,生成可生物降解的两亲嵌段共聚物聚乙二醇﹣聚谷氨酸苄酯(PEG-PBLG),用IR,NMR和GPC表征了共聚物。用超微透析法制备PEG-PBLG聚合物纳米粒,荧光芘探针法测定纳米粒的临界聚集浓度(cac)。紫外分光光度计考察纳米粒对疏水性药物的增溶作用,PEG-PBLG可作为亚微粒药物输送系统的载体。