Barrier-free intermolecular proton transfer in the uracil-glycine complex induced by excess electron attachment

The photoelectron spectra (PES) of anions of uracil-glycine and uracil-phenylalanine complexes reveal broad features with maxima at 1.8 and 2.0 eV. The results of ab initio density functional B3LYP and second order M?ller-Plesset theory calculations indicate that the excess electron occupies a π^* orbital localized on uracil. The excess electron attachment to the complex can induce a barrier-free proton transfer (BFPT) from the carboxylic group of glycine to the O8 atom of uracil. As a result, the four most stable structures of the anion of uracil-glycine complex can be characterized as the neutral radical of hydrogenated uracil solvated by the anion of deprotonated glycine. The similarity between the PES spectra for the uracil complexes with glycine and phenylalanine suggests that the BFPT is also operative in the case of the latter anionic species. The BFPT to the O8 atom of uracil may be related to the damage of nucleic acid bases by low energy electrons because the O8 atom is involved in a hydrogen bond with adenine in the standard Watson-Crick pairing scheme. Received 6 April 2002 Published online 13 September 2002     

10kw热管—散热器的研制

本文介绍应用热管原理,设计用于冷却10kW速调管的热管—散热器。采用径向热管和紧凑散热器,并利用计算机对紧凑散热器进行了优化设计。为了考验热管的性能和寿命,除了进行一般的性能试验外,还在5kW左右条件下进行1154小时的寿命试验,结果表明热管—散热器性能可靠。计算结果和实测数据具有良好的一致性。     

电子文件对中国档案事业生态环境的影响*

中国档案事业生态环境主要包括政治、经济、法律、科技、人文等档案事业生存和发展的现实社会环境要素。以电子文件为基本单元的信息技术的飞速发展和普及,大大改善了中国档案事业的生态环境,同时也带来了新的挑战。     

Web-Based Information Extraction Technology

Information extraction techniques on the Web are the current research hotspot. Now many information extraction techniques based on different principles have appeared and have different capabilities. We classify the existing information extraction techniques by the principle of information extraction and analyze the methods and principles of semantic information adding, schema defining,rule expression, semantic items locating and object locating in the approaches. Based on the above survey and analysis,several open problems are discussed.     

一种信息审计系统中的多关键字匹配算法

针对审计系统中搜索大量审计数据的需要,设计了一种基于哈希表机制的多关键字匹配算法.该算法把关键字集合储存到哈希表中,并为关键字集合建立了两个过滤表和一个关键字长度类型表.在查找过程中,对未经过滤表验证的字符串不再进行匹配查找,同时,关键字长度类型表的使用减少了循环的次数.测试结果表明,该算法在速度和精度上都优于BM和mgrep算法.     

Canonical correlation analysis based on information theory

In this article, we propose a new canonical correlation method based on information theory. This method examines potential nonlinear relationships between p×1 vector Y-set and q×1 vector X-set. It finds canonical coefficient vectors a and b by maximizing a more general measure, the mutual information, between a^TX and b^TY. We use a permutation test to determine the pairs of the new canonical correlation variates, which requires no specific distributions for X and Y as long as one can estimate the densities of a^TX and b^TY nonparametrically. Examples illustrating the new method are presented.     

网络环境下会计信息系统的创新

从我国会计软件的发展历程及网络环境方面，对会计信息系统软件功能的创新、会计信息系统基本结构的创新作了分析和探讨，提出了会计软件未来发展与创新的基本思路和设想．     

A microspectroscopic study of the electronic homogeneity of ordered and disordered Sr2FeMoO6

Disordered Sr₂FeMoO₆ shows a drastic reduction in saturation magnetization compared to highly ordered samples, moreover magnetization as a function of the temperature for different disordered samples shows qualitatively different behaviours. We investigate the origin of such diversity by performing spatially resolved photoemission spectroscopy on various disordered samples. Our results establish that e_xtensive electronic inhomogeneity, arising most probably from an underlying chemical inhomogeneity in disordered samples, is responsible for the observed magnetic inhomogeneity. It is further pointed out that these inhomogeneities are connected with composition fluctuations of the type Sr₂Fe_1+x Mo_1-x O₆ with Fe-rich (x > 0) and Mo-rich (x < 0) regions. Dedicated to Prof J Gopalakrishnan on his 62nd birthday.     

中国加入WTO对图书馆的影响与对策

分析了中国加入世界贸易组织(VETO)后会给图书馆带来的冲击和影响。指出入世后我国图书馆界挑战与机遇并存，并提出入世后图书馆应采取的应对措施。     

浅谈对高校新教师的备课指导

对高校新教师应进行备课指导,要求他们层层了解课程的背景材料,懂得备课的几种形式和基本规范,注意收集教学反馈情况,逐步提高教学艺术水平。